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Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by 1H NMR

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Abstract

Aqueous solutions of surfactant at various concentrations with 0.2% poly(vinylpyrrolidone) (PVP) were studied by 1H NMR methods, including relaxation time and self-diffusion coefficient measurements and two-dimensional nuclear Overhauser enhancement spectroscopy. Two surfactants were concerned: cationic cetyltrimethylammonium bromide (CTAB) and nonionic Triton X-100 (TX-100). In the presence of 0.2% PVP, the variation of the T 2 values of CTAB protons is similar to that in the absence of PVP. Relaxation times of PVP protons are not significantly affected by the increasing concentration of CTAB. This indicates that no interaction between PVP and CTAB could be detected. However, in the presence of 0.2% PVP, TX-100 micelles are formed at a concentration lower than its normal critical micellization concentration. According to the results of relaxation time measurement of water protons, the presence of 0.2% PVP also induces the contraction of the hydrophilic layer of the TX-100 micelle. This indicates some interaction between PVP and TX-100, but the mechanism of this interaction needs further investigation.

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Acknowledgement

Financial support by the National Key Basic Development Program "Fundamental Studies of the Extensively Enhanced Petroleum Recovery" (project grant no. G19990225) is gratefully acknowledged.

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Authors and Affiliations

  1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, The Chinese Academy of Sciences, P.O. Box 71010, 430071, Wuhan , China

    Yang Feng, Xiao-Wen Fang, Shi-Zhen Mao, Han-Zhen Yuan & You-Ru Du

  2. Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, 100101, Beijing, China

    Sui Zhao & Jia-Yong Yu

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  1. Yang Feng
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  2. Xiao-Wen Fang
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  3. Shi-Zhen Mao
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  4. Sui Zhao
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  5. Han-Zhen Yuan
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  6. Jia-Yong Yu
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  7. You-Ru Du
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Correspondence to You-Ru Du.

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Feng, Y., Fang, XW., Mao, SZ. et al. Interaction of poly(vinylpyrrolidone) with cationic and nonionic surfactants in aqueous solution studied by 1H NMR. Colloid Polym Sci 281, 902–906 (2003). https://doi.org/10.1007/s00396-002-0855-0

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  • DOI: https://doi.org/10.1007/s00396-002-0855-0

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