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Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion

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Abstract

The structures of cesium and tetraphenylphosphonium polyborates obtained in the course of mild oxidation of the closo-decaborate anion [B10H10]2– in water with a cerium(IV) salt to form Cs2[trans-B20H18] as the main product and in the course of long-term isomerization of the [trans-B20H18]2– anion under the action of UV irradiation to form (Ph4P)2[iso-B20H18] as the main product have been studied. The compounds have been isolated as solvates Cs[B5O6(OH)4]·2H2O and PPh4[B5O6(OH)4]·2DMF·H2O from the filtrates obtained after removing the target compounds from the reaction solutions. The formation of polyborates is explained by the processes of degradation of boron cluster anions in reaction solutions over time.

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ACKNOWLEDGMENTS

Analytical studies were carried out at the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute RAS within the framework of the State Assignment of the Kurnakov Institute RAS.

Funding

The work was carried out within the framework of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental scientific research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Kubasov, V. V. Avdeeva, K. Yu. Zhizhin & N. T. Kuznetsov

  2. MIREA – Russian Technological University, 119571, Moscow, Russia

    I. V. Novikov & K. Yu. Zhizhin

  3. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    P. A. Starodubets

Authors
  1. A. S. Kubasov
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  2. I. V. Novikov
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  3. P. A. Starodubets
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  4. V. V. Avdeeva
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  5. K. Yu. Zhizhin
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  6. N. T. Kuznetsov
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Correspondence to V. V. Avdeeva.

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Translated by V. Avdeeva

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Kubasov, A.S., Novikov, I.V., Starodubets, P.A. et al. Formation of Polyborates during Dimerization of the closo-Decaborate Anion and Isomerization of the Octadecahydroeicosaborate Anion. Russ. J. Inorg. Chem. 67, 984–991 (2022). https://doi.org/10.1134/S0036023622070130

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  • DOI: https://doi.org/10.1134/S0036023622070130

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