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Synthesis, thermal behavior and the temperature-dependent fluorescence property of a new organic amine borate of [(CH3)4N][B5O6(OH)4]·1/2H2O

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Abstract

A new organic amine borate [(CH3)4N][B5O6(OH)4]·1/2H2O has been synthesized under solvothermal conditions, which was characterized by elemental analysis, FTIR spectrum, thermal analysis and X-ray powder diffraction. Its crystal structure was determined by single X-ray crystal diffraction, in which there exists a isolated [B5O6(OH)4]− cluster. The [B5O6(OH)4]− units are connected to one another through hydrogen bonds forming a three-dimensional framework with large channel along the a axis, in which the templating organic amine cations are located. According to the thermal analysis result, the effects of different temperatures on the fluorescence properties of [(CH3)4N][B5O6(OH)4]·1/2H2O were also studied, and the result shows that the fluorescence color changes with the increase of temperatures.

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Acknowledgements

Project supported by National Natural Science Foundation of China (No. 20871078).

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xi’an, 710100, China

    Sa-Ying Li

  2. Key Laboratory for Macromolecular Science of Shaanxi Province, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an, 710062, China

    Zhi-Hong Liu

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  1. Sa-Ying Li
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  2. Zhi-Hong Liu
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Correspondence to Sa-Ying Li.

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Li, SY., Liu, ZH. Synthesis, thermal behavior and the temperature-dependent fluorescence property of a new organic amine borate of [(CH3)4N][B5O6(OH)4]·1/2H2O. J Therm Anal Calorim 126, 913–918 (2016). https://doi.org/10.1007/s10973-016-5577-5

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  • DOI: https://doi.org/10.1007/s10973-016-5577-5

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