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Oxidation of Porous HfB2–SiC Ultra-High-Temperature Ceramic Materials Rich in Silicon Carbide (65 vol %) by a Supersonic Air Flow

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Porous HfB2–65 vol % SiC samples (porosity 34.5%) were produced by reactive hot pressing of HfB2–(SiO2–C) composite powder at 1800°C (heating rate 10 deg/min, holding duration 15 min) and 30 MPa. Using a high-temperature induction plasmatron, their resistance to oxidation by a supersonic dissociated air flow was studied (the heat fluxes in the course of the experiment were varied from 363 to 779 W/cm2). The observation of the temperature distribution over the surface of the sample during the experiment showed that a sharp increase in temperature from ~1770–1850 to ∼2600°C in the samples under investigation occurred at lower heat fluxes and shorter treatment times than that in denser HfB2–30 vol % SiC samples (porosity 9–11%). This indicated that increasing the density of the HfB2–SiC material and also increasing the silicon carbide content reduced the oxidation resistance. However, the fact that the studied sample withstood 37-min exposure to a high-enthalpy dissociated air flow (including 27 min at a surface temperature of 2560–2620°C) without destruction or complete oxidation makes it possible to assign it to ultra-high-temperature materials.

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Notes

  1. Because of the evaporation of the silicate glass layer and the appearance of porous, highly catalytically active, and low thermally conductive HfO2 on the surface [8, 15, 16, 73–76, 83].

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This work was supported by the Russian Science Foundation (grant no. 17-23-20181).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. P. Simonenko, N. P. Simonenko, I. A. Nagornov, V. G. Sevast’yanov & N. T. Kuznetsov

  2. Ishlinskii Institute of Problems of Mechanics, Russian Academy of Sciences, 119526, Moscow, Russia

    A. N. Gordeev & A. F. Kolesnikov

  3. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119991, Moscow, Russia

    A. S. Lysenkov

  4. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    I. A. Nagornov

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Simonenko, E.P., Simonenko, N.P., Gordeev, A.N. et al. Oxidation of Porous HfB2–SiC Ultra-High-Temperature Ceramic Materials Rich in Silicon Carbide (65 vol %) by a Supersonic Air Flow. Russ. J. Inorg. Chem. 65, 606–615 (2020). https://doi.org/10.1134/S0036023620040191

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