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Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG)

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Abstract

A sample of palladium nanoparticles with an average size of ~5 nm on the surface of highly oriented pyrolytic graphite (HOPG) was prepared by vacuum deposition. With the use of X-ray photoelectron spectroscopy (XPS), it was found that the interaction of the resulting Pd/HOPG sample with nitrogen dioxide at room temperature and a pressure of 10–6 mbar led to the oxidation of graphite. In this case, palladium particles retained their metallic state. A comparison with the behavior of a palladium sample supported onto HOPG activated by ion etching under similar conditions showed that structural defects on the graphite surface did not play a decisive role in the oxidation of graphene layers. A comparison with the results obtained upon the interaction of NO2 with Pt nanoparticles supported on the HOPG surface was made.

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REFERENCES

  1. Smirnov, M.Yu., Kalinkin, A.V., Sorokin, A.M., and Bukhtiyarov, V.I., Kinet. Catal., 2020, vol. 61, no. 4, p. 637.

    Article  CAS  Google Scholar 

  2. Parker, D.H. and Koel, B.E., J. Vac. Sci. Technol., A, 1990, vol. 8, p. 2585.

    Article  CAS  Google Scholar 

  3. Zheng, G. and Altman, E.I., Surf. Sci., 2000, vol. 462, p. 151.

    Article  CAS  Google Scholar 

  4. Kalinkin, A.V., Sorokin, A.M., Smirnov, M.Yu., and Bukhtiyarov, V.I., Kinet. Catal., 2014, vol. 55, p. 354.

    Article  CAS  Google Scholar 

  5. Kalinkin, A.V., Smirnov, M.Yu., Bukhtiyarov, A.V., and Bukhtiyarov, V.I., Kinet. Catal., 2015, vol. 56, p. 796.

    Article  CAS  Google Scholar 

  6. Smirnov, M.Yu., Vovk, E.I., Nartova, A.V., Kalinkin, A.V., and Bukhtiyarov, V.I., Kinet. Catal., 2018, vol. 59, p. 653.

    Article  CAS  Google Scholar 

  7. Kalinkin, A.V., Smirnov, M.Y., Sorokin, A.M., Gladky, A.Yu., Bukhtiyarov, V.I., and Klembovskii, I.O., J. Struct. Chem., 2018, vol. 59, p. 1726.

    Article  CAS  Google Scholar 

  8. Smirnov M.Yu., Kalinkin A.V., Bukhtiyarov A.V., Prosvirin I.P., Bukhtiyarov V.I., J. Phys. Chem. C, 2016, vol. 120, p. 10419.

    Article  CAS  Google Scholar 

  9. Afanas’ev, V.P., Bocharov, G.S., Eletskii, A.V., Ridzel, O.Yu., Kaplya, P.S., and Koppen, M., J. Vac. Sci. Technol., B, 2017, vol. 35, p. 041804.

    Article  Google Scholar 

  10. Zhu, C., Hao, X., Liu, Y., Wu, Y., and Wang, J., Appl. Surf. Sci., 2018, vol. 427, p. 1137.

    Article  CAS  Google Scholar 

  11. Rousseau, B., Estrade-Szwarckopf, H., Thomann, A.-L., and Brault, P., Appl. Phys. A, 2003, vol. 77, p. 591.

    Article  CAS  Google Scholar 

  12. Paredes, J.I., Martınez-Alonso, A., and Tascon, J.M.D., Langmuir, 2007, vol. 23, p. 8932.

    Article  CAS  Google Scholar 

  13. Utsumi, S., Honda, H., Hattori, Y., Kanoh, H., Takahashi, K., Sakai, H., Abe, M., Yudasaka, M., Iijima, S., and Kaneko, K., J. Phys. Chem. C, 2007, vol. 111, p. 5572.

    Article  CAS  Google Scholar 

  14. Figueiredo, J.L. and Pereira, M.F.R., Catal. Today, 2010, vol. 150, p. 2.

    Article  CAS  Google Scholar 

  15. Blume, R., Rosenthal, D., Tessonnier, J.-P., Li, H., Knop-Gericke, A., and Schlogl, R., ChemCatChem, 2015, vol. 7, p. 2871.

    Article  CAS  Google Scholar 

  16. Favaro, M., Agnoli, S., Perini, L., Durante, C., Gennaro, A., and Granozzi, G., Phys. Chem. Chem. Phys., 2013, vol. 15, p. 2923.

    Article  CAS  Google Scholar 

  17. Nosova, L.V., Stenin, M.V., Nogin, Yu.N., and Ryndin, Yu.A., Appl. Surf. Sci., 1992, vol. 55, p. 43.

    Article  CAS  Google Scholar 

  18. Aiyer, H.N., Vijayakrishnan, V., Subbanna, G.N., and Rao, C.N.R., Surf. Sci., 1994, vol. 313, p. 392.

    Article  CAS  Google Scholar 

  19. Oktar, N., Mitome, J., Holmgreen, E.M., and Ozkan, U.S., J. Mol. Catal. A: Chem., 2006, vol. 259 P. 171.

    Article  CAS  Google Scholar 

  20. Fiordaliso, E.M., Murphy, S., Nielsen, R.M., Dahl, S., and Chorkendorff, I., Surf. Sci., 2012, vol. 606, p. 263.

    Article  CAS  Google Scholar 

  21. Gao, J. and Guo, Q., Appl. Surf. Sci., 2012, vol. 258, p. 5412.

    Article  CAS  Google Scholar 

  22. Porsgaard, S., Ono, L.K., Zeuthen, H., Knudsen, J., Schnadt, J., Merte, L.R., Chevallier, J., Helveg, S., Salmeron, M., Wendt, S., and Besenbacher, F., ChemPhysChem, 2013, vol. 14, p. 1553.

    Article  CAS  Google Scholar 

  23. Kettner, M., Stumm, C., Schwarz, M., Schuschke, C., and Libuda, J., Surf. Sci., 2019, vol. 679, p. 64.

    Article  CAS  Google Scholar 

  24. Morales, C., Díaz-Fernández, D., Mossanek, R.J.O., Abbate, M., Méndez, J., Pérez-Dieste, V., Escudero, C., Rubio-Zuazo, J., Prieto, P., and Soriano, L., Appl. Surf. Sci., 2020, vol. 509, p. 145118.

    Article  CAS  Google Scholar 

  25. Conrad, H., Ertl, G., Kuppers, J., and Latta, E., Surf. Sci. 1977, vol. 65, p. 245.

    Article  CAS  Google Scholar 

  26. Zemlyanov, D., Azalos-Kiss, B., Kleimenov, E., Teschner, D., Zafeiratos, S., Havecker, M., Knop-Gericke, A., Schlogl, R., Gabasch, H., Unterberger, W., Hayek, K., and Klotzer, B., Surf. Sci., 2006, vol. 600, p. 983.

    Article  CAS  Google Scholar 

  27. Gabasch, H., Unterberger, W., Hayek, K., Klotzer, B., Kleimenov, E., Teschner, D., Zafeiratos, S., Havecker, M., Knop-Gericke, A., Schlogl, R., Han, J., Ribeiro, F.H., Aszalos-Kiss, B., Curtin, T., and Zemlyanov, D., Surf. Sci., 2006, vol. 600, p. 2980.

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The studies are conducted using the equipment of the Center of collective use “National Center of Catalyst Research”.

Funding

This work was carried out at the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences within the framework of a state contract (project no. AAAA-A17-117041710078-1).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. Yu. Smirnov, A. V. Kalinkin, A. M. Sorokin & V. I. Bukhtiyarov

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  1. M. Yu. Smirnov
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  2. A. V. Kalinkin
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  3. A. M. Sorokin
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  4. V. I. Bukhtiyarov
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Correspondence to M. Yu. Smirnov.

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Additional information

Translated by V. Makhlyarchuk

Abbreviations and notation: HOPG, highly oriented pyrolytic graphite; XPS, X-ray photoelectron spectroscopy; STM, scanning tunneling microscopy; Eb, binding energy.

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Smirnov, M.Y., Kalinkin, A.V., Sorokin, A.M. et al. Room Temperature Interaction of NO2 with Palladium Nanoparticles Supported on a Nonactivated Surface of Highly Oriented Pyrolytic Graphite (HOPG). Kinet Catal 61, 907–911 (2020). https://doi.org/10.1134/S0023158420060142

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  • DOI: https://doi.org/10.1134/S0023158420060142

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