Skip to main content
SpringerLink
Log in

Catalytic syntheses of polycyclic compounds based on norbornadiene in the presence of nickel complexes: VI. Heterogenized catalyst for isomerization reactions of norbornene derivatives

  • Mechanisms of Catalytic Reactions
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The kinetics and mechanism of the thermal izomerization of 5-exo-methyl-tricyclo[3.2.1.05,7]octene-2 into 2-methyl-tetracyclo[3.2.1.02,7.04,6]octane are reported. The use of catalysts based on nickel compounds is demonstrated. As compared to the other catalytic systems, the heterogenized nickel catalyst obtained by thermal treatment of nickel norbornadiene complexes shows much better performance characteristics (selectivity, specific activity, and service life).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Bren, V.A., Dubonosov, A.D., Minkin, V.I., and Chernoivanov, V.A., Usp. Khim., 1991, vol. 60, no. 5, p. 913.

    CAS  Google Scholar 

  2. Nishino, H., Nakamura, A., Terada, M., Kosaka, A., Fukui, M., Aoki, N., and Inone, J., J. Photochem. Photobiol., A, 2002, vol. 147, p. 1.

    Article  CAS  Google Scholar 

  3. Laikov, D.N., Chem. Phys. Lett., 1997, vol. 281, p. 151.

    Article  CAS  Google Scholar 

  4. Organikum: Organisch-chemisches Grundpraktikum, Berlin: Wissenschaften, 1976.

  5. Leont’eva, S.V., Dmitriev, D.V., Katsman, E.A., and Flid, V.R., Kinet. Katal., 2006, vol. 47, no. 4, p. 597 [Kinet. Catal. (Engl. Transl.), vol. 47, no. 4, p. 580].

    Google Scholar 

  6. Hartley, F.R., Supported Metal Complexes: A New Generation of Catalysts, Dordrecht: Reidel, 1985.

    Google Scholar 

  7. Ermakov, Yu.I., Zakharov, V.A., and Kuznetsov, B.N., Zakreplennye kompleksy na okisnykh nositelyakh v katalize (Oxide-Supported Complexes in Catalysis), Moscow: Mir, 1980.

    Google Scholar 

  8. Colquhoun, H.M., Holton, J., Thomson, D.J., and Twigg, M.V., New Pathways for Organic Synthesis: Practical Applications of Transition Metals, New York: Plenum, 1985.

    Google Scholar 

  9. Lisichkin, G.V. and Yuffa, A.Ya., Geterogennye metallokompleksnye katalizatory (Heterogeneous Metal Complex Catalysts), Moscow: Khimiya, 1981.

    Google Scholar 

  10. Ivanov, A.V., Manulik, O.S., Flid, V.R., and Belov, A.P., Kinet. Katal., 1994, vol. 35, no. 5, p. 774.

    CAS  Google Scholar 

  11. Vetrova, O.B., Katsman, E.A., Zhavoronkov, I.P., Karasev, Yu.Z., and Dolgii, I.E., Zh. Org. Khim., 1991, vol. 27, p. 2624.

    CAS  Google Scholar 

  12. USSR Inventor’s Certificate 1532069, Byull. Izobret., 1989, no. 48.

Download references

Author information

Authors and Affiliations

  1. Lomonosov State Academy of Fine Chemical Technology, Moscow, 119571, Russia

    S. V. Leont’eva & V. R. Flid

Authors
  1. S. V. Leont’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. R. Flid
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Leont’eva.

Additional information

Original Russian Text © S.V. Leont’eva, V.R. Flid, 2007, published in Kinetika i Kataliz, 2007, Vol. 48, No. 6, pp. 876–880.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Leont’eva, S.V., Flid, V.R. Catalytic syntheses of polycyclic compounds based on norbornadiene in the presence of nickel complexes: VI. Heterogenized catalyst for isomerization reactions of norbornene derivatives. Kinet Catal 48, 818–822 (2007). https://doi.org/10.1134/S0023158407060092

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158407060092

Keywords

Search

Navigation