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A review on copper-based nanoparticles as a catalyst: synthesis and applications in coupling reactions

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Abstract

The ever-increasing demand for efficient and sustainable catalytic systems has prompted a surge in the exploration of transition metal nanoparticles as catalysts for various chemical reactions. Among these, copper-based nanoparticles have emerged as promising contenders, offering a viable alternative to the traditionally employed palladium catalysts. This review provides a comprehensive overview of the catalytic application of copper-based nanoparticles in coupling reactions, with a focus on their synthesis methods, structural characterization, and catalytic performance. The synthesis of copper-based nanoparticles is discussed in detail, encompassing a range of techniques including wet chemical technique, reverse micelle, biosynthesis, microwave and solgel methods. Emphasis is placed on tailoring the size, shape, and surface properties of these synthesized nanoparticles. Furthermore, the catalytic activity is detailed and summarized by focusing on the coupling reactions. The comprehensive insights provided herein serve as a valuable resource for researchers engaged in the development of efficient and eco-friendly catalytic processes.

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Adapted with permission from ref [67] under CC-BY license Copyright Royal Society of Chemistry. 2023.

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Adapted with permission from ref [50], Copyright 2023. Elsevier.

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Adapted with permission from [116] Copyright @ 2019. Royal Society of Chemistry.

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Adapted from Ref [118]. Copyright, 2022. Springer Nature

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Adapted with permission from ref [129].

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Adapted from ref [130].

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Acknowledgements

The authors are very grateful to the Vice Chancellor, PP Savani University, for knowledge support, guidance and financial assistance.

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  1. 2D Materials and LASER Actuation Laboratory, Centre of Excellence for Research, PP Savani University, NH-8, Surat, Gujarat, 394125, India

    Rakshit Pathak, Vinay Deep Punetha, Shalini Bhatt & Mayank Punetha

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RP and VP contributed to study conceptualization and review and editing; RP contributed to literature review and original draft writing and supervised the study; MP and RP contributed to graphical illustration and software; and RP, SB and VP contributed to final draft. All authors reviewed and approved the final version of the manuscript.

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Pathak, R., Punetha, V.D., Bhatt, S. et al. A review on copper-based nanoparticles as a catalyst: synthesis and applications in coupling reactions. J Mater Sci 59, 6169–6205 (2024). https://doi.org/10.1007/s10853-024-09546-z

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