Abstract
The kinetics of phenol degradation in aqueous solution in an atmospheric-pressure dielectric-barrier discharge in oxygen at different power inputs to the discharge has been investigated. On the basis of these data, the energy yields of degradation and their dependence on the discharge parameters and initial concentration have been determined. The problem of comparing the energy efficiencies of different types of discharges has been discussed. The decomposition of phenol has been shown to result in the formation of carboxylic acids and aldehydes in the solution and carbon dioxide in the gas phase.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Yang, Y., Cho, Y.I., and Friedman, A., Plasma Discharge in Liquid: Water Treatment and Applications Boca Raton: CRC, 2012.
Bobkova, E.S., Grinevich, V.I., Isakina, A.A., and Rybkin, V.V., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2011, vol. 54, no. 6, p. 3.
Zhang, J., Chen, J., and Li, X., J. Water Resour. Prot., 2009, vol. 2, no. 2, p. 99.
Lukes, P. and Locke, B.R., J. Phys. D: Appl. Phys, 2005, vol. 38, no. 22, p. 4074.
Yan, J.H., Du, Ch.M., Li, X.D., Cheron, B.G., Ni, M.J., and Cen, K.F., Plasma Chem. Plasma Process., 2006, vol. 26, p. 31.
Gao, J., Plasma Sources Sci. Technol., 2003, vol. 12, no. 4, p. 533.
Ognier, S., Iya-sou, D., Fourmond, C., and Cavadias, S., Plasma Chem. Plasma Process., 2009, vol. 29, no. 4, p. 261.
Grabowski, L.R., Veldhusen, E.M., Pemen, A.J.M., and Rutgers, W.R., Plasma Chem. Plasma Process., 2006, vol. 26, no. 1, p. 3.
Malik, M.A., Plasma Chem. Plasma Process., 2010, vol. 30, no. 1, p. 21.
Wang, L., Plasma Chem. Plasma Process., 2009, vol. 29, p. 241.
Janca, S., Kuzmin, A., Maximov, A., Titova, Yu., and Czernichowski, A., Plasma Chem. Plasma Process., 1999, vol. 19, p. 53.
Bruggeman, P., Liu, J., Degroote, J., Kong, M.G., Vierendeels, J., and Leys, C., J. Phys. D: Appl. Phys, 2008, vol. 41, p. 215201.
Shutov, D.A., Isakina, A.A., Konovalov, A.S., and Bobkova, E.S., High Energy Chem., 2013, vol. 47, no. 4, p. 203.
Even-Ezra, I., Mizraki, A., Gerrity, D., Snyder, S., Salveson, A., and Lanav, O., Desalin. Water Treat., 2009, vol. 11, p. 236.
Liu, Y. and Jiang, X., Plasma Chem. Plasma Process., 2008, vol. 28, no. 1, p. 15.
Lukes, P. and Locke, B.R., J. Phys. D: Appl. Phys, 2005, vol. 38, no. 22, p. 4074.
Jiang, B., Zheng, J., Qui, Sh., Wu, M., Zhang, Q., Yan, Y., and Xue, Q., Chem. Eng. J., 2014, vol. 236, no. 1, p. 348.
Bobkova, E.S., Grinevich, V.I., Ivantsova, N.A., and Rybkin, V.V., Plasma Chem. Plasma Process., 2012, vol. 32, no. 4, p. 703.
Simonov, V.A., Nekhorosheva, E.V., and Zavorovskaya, N.A., Analiz vozdushnoi sredy pri pererabotke polimernykh materialov (Air Analysis upon Reprocessing of Polymer Materials), Leningrad: Khimiya, 1988.
Reid, R.C. and Sherwood, T.K. The Properties of Gases and Liquids. Their Estimation and Correlation, New York: McGraw-Hill, 1966.
Bobkova, E.S. and Rybkin, V.V., Teplofiz. Vys. Temp., 2014, vol. 53, no. 3, p. 25.
Tomizawa, S. and Tezuka, M., Plasma Chem. Plasma Process., 2007, vol. 27, no. 4, p. 486.
Locke, B.R. and Shih, K.Ya., Plasma Sources Sci. Technol., 2011, vol. 20, no. 3, p. 034006.
Mansergas, A. and Anglada, M., J. Phys. Chem. A, 2006, vol. 110, no. 11, p. 4001.
Eiteneer, B., Yu, C.L., Goldenberg, M., and Frenklash, M., J. Phys. Chem. A, 1998, vol. 102, no. 27, p. 5196.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.S. Bobkova, A.A. Isakina, A.I. Shishkin, N.N. Kuznets, A.M. Morev, 2015, published in Khimiya Vysokikh Energii, 2015, Vol. 49, No. 1, pp. 71–75.
Rights and permissions
About this article
Cite this article
Bobkova, E.S., Isakina, A.A., Shishkin, A.I. et al. Features of phenol degradation in aqueous solution in dielectric-barrier discharge in oxygen. High Energy Chem 49, 68–71 (2015). https://doi.org/10.1134/S0018143915010038
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143915010038