Abstract
Reduction of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane with a sub-stoichiometric amount of SnCl2 afforded a mixture of isomeric 2,4,6,8,10- and 2,4,6,8,12-pentanitro-2,4,6,8,10,12-hexaazaisowurtzitanes, their ratio depending on the solvent used. Treatment of these compounds with NOBF4 gave rise to isomeric pentanitronitroso-2,4,6,8,10,12-hexaazaisowurtzitanes, which can be transformed into the starting NH products by treating with HCl.
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References
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Luk"yanov, O.A., Shlykova, N.I. Pentanitro- and pentanitronitroso-2,4,6,8,10,12-hexaazaisowurtzitanes. Russian Chemical Bulletin 53, 566–568 (2004). https://doi.org/10.1023/B:RUCB.0000035638.09600.0e
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DOI: https://doi.org/10.1023/B:RUCB.0000035638.09600.0e
- 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
- 2,4,6,8,10-pentanitro-2,4,6,8,10,12-hexaazaisowurtzitane
- 2,4,6,8,12-pentanitro-2,4,6,8,10,12-hexaazaisowurtzitane
- 2,4,6,8,10-pentanitro-12-nitroso-2,4,6,8,10,12-hexaazaisowurtzitane
- 2,4,6,8,12-pentanitro-10-nitroso-2,4,6,8,10,12-hexaazaisowurtzitane
- N-nitro compounds
- N-nitroso compounds
- tin chloride
- reduction
- N-nitrosation
- N-NO-denitrosation
- N-nitration