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Thermal decomposition of complexes

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Abstract

The iron(II) complex of the Schiff bases trans-N,N'-bis(salicylidene)-1,2-cyclohexanediamine (Salcn), manganese(II) and vanadyl complexes of the Schiff bases cis- andtrans-N,N'-bis(salicylidene)-1,2-cyclohexanediamine (Salcn) were prepared and characterized by IR spectroscopy, and elemental analysis. These new complexes were submitted to thermal analysis (TG and DSC) under dynamic air atmosphere. The differences in the decomposition profiles were related to the structure of isomers and decomposition intermediates were characterized according to their X-ray diffraction pattern and by their infrared spectrum.

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Authors and Affiliations

  1. Departamento de Química -, Universidade Federal de Săo Carlos, Via Washington Luís km 235, Caixa Postal 676, CEP 13565-905, Săo Carlos, Săo Paulo, Brazil

    F. C. D. Lemos, M. Muraro, J. Zukerman-Schpector, É. T. G. Cavalheiro & E. R. Dockal

Authors
  1. F. C. D. Lemos
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  2. M. Muraro
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  3. J. Zukerman-Schpector
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  4. É. T. G. Cavalheiro
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  5. E. R. Dockal
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Correspondence to E. R. Dockal.

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Lemos, F.C.D., Muraro, M., Zukerman-Schpector, J. et al. Thermal decomposition of complexes. Journal of Thermal Analysis and Calorimetry 75, 599–606 (2004). https://doi.org/10.1023/B:JTAN.0000027151.56337.a2

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  • DOI: https://doi.org/10.1023/B:JTAN.0000027151.56337.a2

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