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Synthesis, structure, and catalytic properties of iron complexes with mono- and bisformazans in sulfide oxidation and ethylene oligomerization reactions

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Abstract

Metal complexes with different numbers of iron atoms in a predominantly nitrogen-containing coordination environment have been synthesized on basis of benzothiazole mono- and bisformazans. The composition and structures of the resulting iron coordination compounds have been characterized by electronic absorption spectroscopy, elemental analysis, mass spectrometry, electron spin resonance, and magnetochemistry. The catalytic behavior of these metal chelates in the liquid-phase oxidation of sulfides and the oligomerization of ethylene has been studied.

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Authors and Affiliations

  1. Ural State Forest Engineering University, Sibirskii trakt 37, Yekaterinburg, Sverdlovsk oblast, 620100, Russia

    I. S. Maksakova, I. G. Pervova & I. N. Lipunov

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    G. P. Belov & I. I. Khasbiullin

  3. Kazan National Research Technological University, ul. Karla Marksa 68, Kazan, Tatarstan, 420015, Russia

    I. I. Khasbiullin

  4. Zavoiskii Physicotechnical Institute, Kazan Scientific Center, Russian Academy of Sciences, Sibirskii trakt 10/7, Kazan, Tatarstan, 420029, Russia

    N. A. Ivanova & E. N. Frolova

Authors
  1. I. S. Maksakova
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  2. I. G. Pervova
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  3. G. P. Belov
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  4. I. I. Khasbiullin
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  5. N. A. Ivanova
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  6. E. N. Frolova
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  7. I. N. Lipunov
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Corresponding author

Correspondence to I. S. Maksakova.

Additional information

Original Russian Text © I.S. Maksakova, I.G. Pervova, G.P. Belov, I.I. Khasbiullin, N.A. Ivanova, E.N. Frolova, I.N. Lipunov, 2015, published in Neftekhimiya, 2015, Vol. 55, No. 3, pp. 228–235.

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Maksakova, I.S., Pervova, I.G., Belov, G.P. et al. Synthesis, structure, and catalytic properties of iron complexes with mono- and bisformazans in sulfide oxidation and ethylene oligomerization reactions. Pet. Chem. 55, 217–223 (2015). https://doi.org/10.1134/S0965544115030068

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  • DOI: https://doi.org/10.1134/S0965544115030068

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