Skip to main content
SpringerLink
Log in

Tetradentate Schiff base oxovanadium(IV) complexes

  • Full Papers
  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Summary

Eleven oxovanadium(IV) complexes of tetradentate Schiff bases, obtained by condensating two moles of an o-hydroxycarbonyl compound with a diamine, have been prepared and characterized by elemental analysis, m.p., and i.r. and electronic spectra. The i.r. and electronic spectra of the free ligand and the complexes are compared and discussed. The Gaussian analysis of the vis. spectra of the complexes, normally C1 or Cs, in MeCN yielded four peaks at ca. 12000, 15000, 17700 and 20000–23000cm−1, assigned to the four d-d transitions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Butler and C. J. Carrano, Coord. Chem. Rev., 109, 61 (1991).

    Google Scholar 

  2. D. Rehder, Angew. Chem. Int. Edit. Engl., 30, 148 (1991).

    Google Scholar 

  3. N. D. Chasteen (Ed.), Vanadium in Biological Systems, Kluwer Academic Publishers, Boston, 1990.

    Google Scholar 

  4. Y. Shecter and S. J. D. Karlish, Nature, 284, 556 (1980).

    Google Scholar 

  5. C. E. Heyliger, A. G. Tahiliani and J. H. McNiell, Science, 227, 1474 (1985).

    Google Scholar 

  6. S. C. Stenson, Chem. Eng. News, 69, 35 (1991).

    Google Scholar 

  7. A. Shaver, J. B. Ng, D. A. Hall, B. S. Lum and B. I. Posner, Inorg. Chem., 32, 3109 (1993).

    Google Scholar 

  8. O. M. Rosen, Science, 237, 1452 (1987).

    Google Scholar 

  9. X. Li, M. S. Lash and V. L. Pecoraro, Inorg. Chem., 27, 4657 (1988).

    Google Scholar 

  10. J. A. Bonadies, V. L. Pecoraro and C. J. Carrano, J. Chem. Soc., Chem. Commun., 1218 (1986).

  11. P. E. Riley, V. L. Pecoraro, C. J. Carrano, J. A. Bonadies and K. N. Raymond, Inorg. Chem., 25, 154 (1986).

    Google Scholar 

  12. J. A. Bonadies and C. J. Carraro, J. Am. Chem. Soc., 108, 4088 (1986).

    Google Scholar 

  13. C. J. Carraro, Inorg. Chem., 30, 1231 (1991).

    Google Scholar 

  14. J. A. Bonadies, W. M. Butler, V. L. Percoraro and C. J. Carrano, Inorg. Chem., 26, 1218 (1987).

    Google Scholar 

  15. J. Selbin, Coord. Chem. Rev., 1, 293 (1966).

    Google Scholar 

  16. A. Pasini and M. Gulloti, J. Coord. Chem., 3, 319 (1974).

    Google Scholar 

  17. G. A. Kolawole and K. S. Patel, J. Chem. Soc., Dalton Trans., 1241 (1981).

  18. R. L. Farmer and F. L. Urbach, Inorg. Chem., 13, 587 (1974).

    Google Scholar 

  19. L. J. Boucher and T. F. Yen, Inorg. Chem., 8, 689 (1969).

    Google Scholar 

  20. H. A. Kuska and P. H. Yang, Inorg. Chem., 16, 1938 (1977).

    Google Scholar 

  21. G. A. Kolawole and K. S. Patel, J. Coord. Chem., 14, 235 (1986).

    Google Scholar 

  22. R. L. Farmer and F. L. Urbach, J. Chem. Soc., Chem. Commun., 1515 (1970).

  23. G. A. Kolawole and K. S. Patel, J. Coord. Chem., 12, 121 (1982).

    Google Scholar 

  24. R. L. Farmer and F. L. Urbach, Inorg. Chem., 11, 2562 (1970).

    Google Scholar 

  25. J. C. Dutton, G. D. Fallon and K. S. Murray, Inorg. Chem., 27, 34 (1988).

    Google Scholar 

  26. J. R. Zamian, Masters Thesis, Universidade Federal de São Carlos, 1990.

  27. J. R. Zamian, E. R. Dockal, G. Casetallano and G. Oliva, Polyhedron, 15, 245 (1995).

    Google Scholar 

  28. J. R. Zamian, E. R. Inone, R. Collazo, F. A. do Amaral, A. P. M. de Azevedo, C. T. Seisdedos, J. M. de Souza and E. R. Dockal, Unpublished work.

  29. H. L. David, M. Ionashiro, A. V. Benedetti, J. R. Zamian and E. R. Dockal, Thermochim. Acta, 202, 45 (1992).

    Google Scholar 

  30. J. C. D. Lopes, P. R. Olivato, P. A. M. Vazaquez and Y. Hase, Anais Assoc. Brasil. Quim., 41–42, 87 (1992–1993).

    Google Scholar 

  31. R. N. Jones, T. E. Bach, H. Furher, V. B. Kartra, J. Pitha, K. S. Seschardi, R. Venkataraghavan and R. P. Young Computer Programs for Infrared Spectrophotometry, National Research Council of Canada Bulletin, No. 11, 2nd Edit., 1976.

  32. K. Ueno and A. E. Martel, J. Phys. Chem., 60, 1270 (1956).

    Google Scholar 

  33. J. A. Faniran, K. S. Patel and J. C. Bailar, Jr, J. Inorg. Nucl. Chem., 36, 1547 (1974).

    Google Scholar 

  34. H. H. Freedman, J. Am. Chem. Soc., 83, 2900 (1961).

    Google Scholar 

  35. R. M. Silverstein, G. C. Bassler and T. C. Morrill, Spectrometric Identification of Organic Compounds, 5th Edit., Wiley, New York, 1991, p. 110.

    Google Scholar 

  36. F. A. Bottino, P. Finocchiaro and E. Libertini, J. Coord. Chem., 16, 341 (1988).

    Google Scholar 

  37. P. Gluvchinsky, G. M. Mockler and E. Sinn, Spectrochim. Acta, 33A, 1073 (1977).

    Google Scholar 

  38. R. J. Hill and C. E. F. Rickard, J. Inorg. Nucl. Chem., 40, 793 (1978).

    Google Scholar 

  39. X. Wang, X. M. Zhang and H. X. Lin, Transition Met. Chem., 19, 611 (1994).

    Google Scholar 

  40. X. Wang, X. M. Zhang and H. X. Lin, Polyhedron, 14, 293 (1995).

    Google Scholar 

  41. G. C. Percy and J. Thornton, J. Inorg. Nucl. Chem., 35, 2319 (1973).

    Google Scholar 

  42. K. S. Patel and G. A. Kolawole, J. Coord. Chem., 11, 231 (1982).

    Google Scholar 

  43. K. S. Patel and J. C. Bailar, Jr, J. Coord. Chem., 3, 113 (1973).

    Google Scholar 

  44. D. L. Daughdrill, D. F. Martin and J. S. Binford, Jr, J. Inorg. Nucl. Chem., 32, 2885 (1970).

    Google Scholar 

  45. G. A. Kolawole and K. S. Patel, J. Coord. Chem., 14, 57 (1985).

    Google Scholar 

  46. K. P. Callahan and P. J. Durand, Inorg. Chem., 19, 3211 (1980).

    Google Scholar 

  47. J. L. Selbin, L. H. Holmes, Jr and S. P. McGlynn, Inorg. Chem., 25, 1359 (1963).

    Google Scholar 

  48. G. C. Percy and H. S. Stenton, Spectrochim. Acta, 32A, 1615 (1976).

    Google Scholar 

  49. K. Nakamato, Infrared and Raman Spectra of Inorganic and Coordination, 3rd Edit., Wiley, New York, 1978, p. 436.

    Google Scholar 

  50. G. A. da Silva and E. R. Dockal, Unpublished work.

  51. R. M. Silverstein, G. C. Bassler and T. C. Morrill, Spectrometric Identification of Organic Compounds, 5th Edit., Wiley, New York, 1991, p. 289.

    Google Scholar 

  52. B. Bosnich, J. Am. Chem. Soc., 90, 627 (1968).

    Google Scholar 

  53. K. S. Patel and J. C. Bailar, Jr, Inorg. Chem., 33, 1399 (1971).

    Google Scholar 

  54. R. S. Downing and F. L. Urbach, J. Am. Chem. Soc., 92, 5861 (1970).

    Google Scholar 

  55. A. C. Braithwaite and T. N. Waters, J. Inorg. Nucl. Chem., 35, 3223 (1973).

    Google Scholar 

  56. A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd Edit., Elsevier Science Publishers, Amsterdam, 1984, p. 161.

    Google Scholar 

  57. L. G. Vanquickenborne and S. P. McGlynn, Theoret. Chim. Acta, 9, 390 (1968).

    Google Scholar 

  58. H. A. Kuska and P. H. Yang, Inorg. Chem., 13, 1090 (1974).

    Google Scholar 

  59. H. J. Stoklosa, J. R. Wasson and B. J. McCormick, Inorg. Chem., 13, 592 (1974).

    Google Scholar 

  60. M. Mathew, A. J. Carty and G. J. Palenik, J. Am. Chem. Soc., 92, 3197 (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Química, Universidade Federal de Pará, Caixa Postal 10101, 66065-360, Belém, PA, Brazil

    José R. Zamian

  2. Departamento de Química, Universidade Federal de São Carlos, Caixa Postal 676, 13565-905, São Carlos, SP, Brazil

    Edward R. Dockal

Authors
  1. José R. Zamian
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Edward R. Dockal
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zamian, J.R., Dockal, E.R. Tetradentate Schiff base oxovanadium(IV) complexes. Transition Met Chem 21, 370–376 (1996). https://doi.org/10.1007/BF00139036

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00139036

Keywords

Search

Navigation