Abstract
The reactions of aminals, the Mannich bases, and azomethines derived from substituted salicylaldehydes were studied. Derivatives of tetrahydrocyclopenta[b]- and hexahydrocyclohepta[b]chromenes and substituted 2,2"-spirobichromenes were prepared from aminals, and substituted hexahydroxanthenes were synthesized from the Mannich bases. Azomethine derivatives of 5-nitrosalicylaldehyde and aliphatic amines react with cyclohexanone to form 4a-amino-7-nitro-2,3,4,4a-tetrahydro-1H-xanthenes. 4a-Morpholino-7-nitro-9-phenylethynyl-1,2,3,4,9,9a-hexahydroxanthene was studied by X-ray diffraction analysis.
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Ukhin, L.Y., Belousova, L.V., Orlova, Z.I. et al. Reactions of nitrogenous derivatives of substituted salicylaldehydes with cyclic ketones and enamines. Russian Chemical Bulletin 51, 1262–1269 (2002). https://doi.org/10.1023/A:1020956614588
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DOI: https://doi.org/10.1023/A:1020956614588