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Laser-produced iron nitrides seen by Mössbauer spectroscopy

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Abstract

Mössbauer spectroscopy is a very powerful tool to investigate technological processes performed mainly at the surface of materials. Nitriding of metals and steel is well established in surface engineering, and gas nitriding is used most frequently. Laser nitriding, i.e. the nitrogen take-up from the ambient gas upon irradiation of a steel surface with short laser pulses, is presented in its application to iron, stainless steel and plain carbon steels. It will be demonstrated how Mössbauer spectroscopy in combination with complementary methods (Rutherford backscattering spectroscopy, Resonant nuclear reaction analysis, Nanoindentation) can help to reveal basic mechanisms in these processes.

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References

  1. R. W. Cahn and P. Haasen:Physical Metallurgy, North-Holland Physics Publishing, Amsterdam-Oxford-New York-Tokyo, 1983.

    Google Scholar 

  2. P. Schaaf: Progress in Materials Science46 (2001), in print.

  3. C. Illgner, P. Schaaf, K.-P. Lieb, R. Queitsch, and J. Barnikel: J. Appl. Phys.83 (1998) 2907.

    Article  ADS  Google Scholar 

  4. F. Landry, K.-P. Lieb, and P. Schaaf: J. Appl. Phys.86 (1999) 168.

    Article  ADS  Google Scholar 

  5. P. Schaaf, A. Krämer, L. Blaes, G. Wagner, F. Aubertin, and U. Gonser: Nucl. Instrum. Methods B53 (1991) 184.

    Article  ADS  Google Scholar 

  6. F. Landry and P. Schaaf (unpublished).

  7. F. E. Wagner, J. Physique37, C6 (1976) 673.

    Google Scholar 

  8. U. Gonser and P. Schaaf: Fresenius J. Anal. Chem.341 (1991) 131.

    Article  Google Scholar 

  9. P. Schaaf, A. Krämer, F. Aubertin, and U. Gonser: Z. Metallkunde82 (1991) 815.

    Google Scholar 

  10. G. Rixecker, P. Schaaf, and U. Gosner: J. Phys. D: Appl. Phys.26 (1993) 870.

    Article  ADS  Google Scholar 

  11. M. Uhrmacher, K. Pampus, F. J. Bergmeister, D. Purschke, and K.-P. Lieb: Nucl. Instr. Methods B9 (1985) 234.

    Article  ADS  Google Scholar 

  12. F. Landry and P. Schaaf: Nucl. Instrum. Methods B (2000), submitted.

  13. K. H. Jack: Proc. Roy. Soc. A208 (1951) 216.

    Article  ADS  Google Scholar 

  14. K. H. Jack: Acta Crystallogr.5 (1952) 404.

    Article  Google Scholar 

  15. D. H. Jack and K. H. Jack: Mater. Sci. Eng.11 (1973) 1.

    Article  Google Scholar 

  16. E. Lehrer: Z. Electrochem.36 (1930) 460.

    Google Scholar 

  17. O. Eisenhut and E. Kaupp: Z. Elektrochem.36 (1930) 392.

    Google Scholar 

  18. H. A. Wriedt, N. A. Gokcen, and R. H. Nafziger: Bulletin Alloy Phase Diagrams8 (1987) 355.

    Google Scholar 

  19. A. F. Guillermet and H. Du: Z. Metallkunde85 (1994) 154.

    Google Scholar 

  20. J. Kunze:Nitrogen and carbon in iron and steel, Akademie Verlag, Berlin, 1990.

    Google Scholar 

  21. L. Kaufman and H. Bernstein:Computer Calculation of Phase Diagrams, Academic Press, New York, 1970; see also the journal “Calphad”, Pergamon Press.

    Google Scholar 

  22. K. Frisk: Calphad15 (1991) 79.

    Article  Google Scholar 

  23. L. Rissanen, M. Neubauer, K.-P. Lieb, and P. Schaaf: J. Alloys Compounds274 (1998) 74.

    Article  Google Scholar 

  24. T. Hinomura and S. Nasu: inProc. Int. Conf. Applications Mössbauer Effect (ICAME), (Ed. by I. Ortalli) Compositori SIF, Sept. 10–16, 1995, Rimini, Italy, 1995.

  25. A. Oueldennaoua, E. Bauer-Grosse, M. Foos, and C. Frantz: Scripta Metall.19 (1985) 1503.

    Article  Google Scholar 

  26. K. Suzuki, H. Morita, T. Kaneko, H. Yoshida, and H. Fujimori: J. Alloys Compounds201 (1993) 232.

    Google Scholar 

  27. H. Nakagawa, S. Nasu, H. Fujii, M. Takahashi, and F. Kanamaru: Hyperfine Interactions69 (1991) 455.

    Article  Google Scholar 

  28. L. Rissanen, P. Schaaf, M. Neubauer, K.-P. Lieb, J. Keinonen, and T. Sajavaara: Appl. Surf. Sci.138–139 (1999) 261.

    Article  Google Scholar 

  29. T. Hinomura: Ph.D. Thesis, Osaka University, Division of Materials Physics, Osaka, 1998 (in English).

    Google Scholar 

  30. D. Horstmann:Das Zustandsschaubild Eisen-Kohlenstoff, Verlag Stahleisen mbH, Düsseldorf, 1985.

    Google Scholar 

  31. U. Gonser, C. J. Meechan, A. H. Muir, and H. Wiedersich: J. Appl. Phys.34 (1963) 2373.

    Article  ADS  Google Scholar 

  32. M. Mekata, H. Yoshimura, and H. Takaki: J. Phys. Soc. Jpn.33 (1972) 62.

    Article  ADS  Google Scholar 

  33. T. Yamaoka, M. Mekata, and H. Takaki: J. Phys. Soc. Jpn.35 (1973).

  34. J. Bainbridge, D. A. Channing, W. H. Whitlow, and R. E. Pendlebury: J. Phys. Chem. Solids34 (1973) 1579.

    Article  Google Scholar 

  35. P. Schaaf, C. Illgner, M. Niederdrenk, and K.-P. Lieb: Hyperfine Interactions95 (1995) 199.

    Article  Google Scholar 

  36. P. Schaaf: Hyperfine Interactions111 (1998) 113.

    Article  ADS  Google Scholar 

  37. P. Schaaf, F. Landry, M. Neubauer, and K.-P. Lieb: Hyperfine Interactions113 (1998) 429.

    Article  ADS  Google Scholar 

  38. P. Schaaf and F. Landry: inMössbauer Spectroscopy in Materials Science, NATO Science Series “High Technologies” (Eds. M. Miglierini and D. Petridis), Kluwer Academic Publishers, Dordrecht, 1999, p. 161.

    Google Scholar 

  39. M. Ron: inApplications of Mössbauer spectroscopy II (Ed. R. L. Cohen), Academic Press, New York, 1980, p. 329.

    Google Scholar 

  40. N. DeChristofaro and R. Kaplow: Metall. Trans. A8 (1977) 35.

    Article  Google Scholar 

  41. J. M. D. Coey, K. O’Donnell, Q. Qinian, E. Touchais, and K. H. Jack: J. Phys. Condens. Matter6 L23 (1994).

  42. A. J. Nozik, J. C. Wood, and G. Haacke: Solid State Commun.7 (1969) 1677.

    Article  Google Scholar 

  43. M. J. Clauser: Solid State Commun.8 (1970) 781.

    Article  Google Scholar 

  44. R. S. Figueiredo and V. Drago, Solid State Commun.80 (1991) 757.

    Article  Google Scholar 

  45. M. Niederdrenk, P. Schaaf, K.-P. Lieb, and O. Schulte: J. Alloys Compounds237 (1996) 81.

    Article  Google Scholar 

  46. L. de Wit, T. Weber, J. S. Custer, and F. W. Saris: Phys. Rev. Lett.72 (1994) 3835.

    Article  ADS  Google Scholar 

  47. J. Foct, P. Rochegude, and A. Hendry: Acta Metall.36 (1988) 501.

    Article  Google Scholar 

  48. K. Oda, K. Umezu, and H. Ino: J. Phys. Condens. Matter2 (1990) 10147.

    Article  ADS  Google Scholar 

  49. G. Wagner, R. Leutenecker, and U. Gonser: Hyperfine Interactions56 (1990) 1653.

    Article  Google Scholar 

  50. I. Fall and J.-M. R. Génin: Hyperfine Interactions69 (1991) 513.

    Article  Google Scholar 

  51. P. Bauer, O. N. C. Uwakweh, and J. M. R. Génin: Hyperfine Interactions41 (1988) 555.

    Article  Google Scholar 

  52. H. Jacobs, D. Rechenbach, and U. Zachwieja: J. Alloys Compounds227 (1995) 10.

    Article  Google Scholar 

  53. D. Rechenbach and H. Jacobs: J. Alloys Compounds235 (1996) 15.

    Article  Google Scholar 

  54. H. J. Grabke: ISIJ. Int.36 (1996) 777.

    Google Scholar 

  55. T. Weber, L. de Wit, F. W. Saris, A. Königer, B. Rauschenbach, G. K. Wolf, and S. Krauss: Mater. Sci. Eng. A199 (1995) 205.

    Article  Google Scholar 

  56. T. Weber, J. Verhoeven, F. W. Saris, T. Osipowicz, and W. D. Münz: Nucl. Instrum. Methods B106 (1995) 159.

    Article  ADS  Google Scholar 

  57. P. Rochegude and J. Foct: Phys. Status Solidi A88 (1985) 137.

    Article  Google Scholar 

  58. P. Rochegude and B. Billon: Scripta Metall.20 (1986) 1095.

    Article  Google Scholar 

  59. S. B. Hendricks and P. R. Kosting: Z. Kristallogr.74 (1930) 511.

    Google Scholar 

  60. D. Rechenbach: Ph.D. Thesis, Universität Dortmund, Dortmund, 1995.

    Google Scholar 

  61. M. A. J. Somers, B. J. Kooi, L. Maldzinski, E. J. Mittemeijer, A. A. van der Horst, A. M. van der Kraan, and N. M. van der Pers: Acta Metall. Mater.45 (1997) 2013.

    Google Scholar 

  62. N. DeChristofaro and R. Kaplow: Metall. Trans. A8 (1977) 425.

    Article  Google Scholar 

  63. K. E. Eickel and W. Pitsch: Phys. Status Solidi39 (1970) 121.

    Article  Google Scholar 

  64. P. Rochegude and B. Billon: Scr. Metall.20 (1986) 1095.

    Article  Google Scholar 

  65. G. M. Chen, N. K. Jaggl, J. B. Butt, E. B. Yeh, and L. H. Schwartz: J. Phys. Chem.87 (1983) 5326.

    Article  Google Scholar 

  66. P. Schaaf, F. Landry, H. Man, and K.-P. Lieb: Hyperfine Interactions126 (2000) 211.

    Article  ADS  Google Scholar 

  67. B. J. Kooi: Ph.D. Thesis, Technische Universiteit Delft, Delft, 1995.

    Google Scholar 

  68. C. Illgner, P. Schaaf, K.-P. Lieb, E. Schubert, R. Queitsch, and H. W. Bergmann: Appl. Phys. A61 (1995) 1.

    ADS  Google Scholar 

  69. C. Illgner, K.-P. Lieb, P. Schaaf, K. Mann, H. Köster, and G. Marowsky: Appl. Phys. A62 (1996) 231.

    ADS  Google Scholar 

  70. P. Schaaf: Prog. Mater. Sci.46 (2001) (in print).

  71. P. Schaaf, S. Wiesen, and U. Gonser: Acta Metall.40 (1992) 373.

    Article  Google Scholar 

  72. J. Kunze: Härterei-Technische Mitteilungen51 (1996) 348.

    Google Scholar 

  73. T. Weber, L. de Wit, F. W. Saris, and P. Schaaf: Thin Solid Films279 (1996) 217.

    Article  Google Scholar 

  74. H.-J. Spies and F. Vogt: Härterei-Technische Mitteilungen52 (1997) 342.

    Google Scholar 

  75. H.-J. Spies, P. Schaaf, and F. Vogt: Materialwiss. Werkstofftech.29 (1998) 588.

    Article  Google Scholar 

  76. S. Mändl, R. Günzel, E. Richter, and W. Moeller: Surface Coatings Technology100–101 (1998) 367.

    Google Scholar 

  77. V. M. Nadutov: Mater. Sci. Eng. A254 (1998) 234.

    Article  Google Scholar 

  78. J. C. Ion, K. E. Easterling, and M. F. Ashby: Acta Metall.32 (1984) 1949.

    Article  Google Scholar 

  79. A. Gillner, K. Wissenbach, and E. W. Kreutz: inLaser surface melting of cast iron: processing parameters, structures, hardness (Ed. B. L. Mordike), DGM Informationsgesellschaft, Oberursel, 1987, p. 213.

    Google Scholar 

  80. R. Jaschek, P. Konrad, R. Mayerhofer, H. W. Bergmann, P. Bickel, R. Kowalewicz, A. Kuttenberger, and J. Christiansen: Proc. SPIE2502 (1995) 724.

    Article  ADS  Google Scholar 

  81. M. S. Mikhalev and T. I. Egorova: Combustion-, Explosion Shock Waves11 (1975) 321 (Transl. Fiz.-Goreniya Vzryva).

    Google Scholar 

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This work is partially supported by the Deutsche Forschungsgemeinschaft (DFG Scha 632/3).

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Schaaf, P., Lieb, K.P., Carpene, E. et al. Laser-produced iron nitrides seen by Mössbauer spectroscopy. Czech J Phys 51, 625–650 (2001). https://doi.org/10.1023/A:1017688914737

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