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Hierarchical porous Mo-Co3O4-CNTc nanosheets for aqueous rechargeable zinc ion batteries with ultralong life

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Abstract

Aqueous rechargeable zinc ion batteries (ZIBs) are a promising next-generation energy storage device, which suffers from poor capacity and limited cycle life. In this work, a ZIB cathode material was reported, consisting of a composite of Co3O4 doped with Mo and carboxylic carbon nanotubes (Mo-Co3O4-CNTc), with a hierarchical porous structure arising from ultrathin nanosheets. The composite was prepared via a sol-gel method in an emulsion system. The experimental electrochemical data and density-functional first-principles calculations showed that the as-prepared Mo-Co3O4-CNTc composites with 152.9 mAh g−1 showed superior electrochemical performance compared to pure Co3O4 (as 107.3 mAh g−1) and Mo-Co3O4 (as 112.0 mAh g−1) electrode materials. Furthermore, the as-prepared MoCo-Zn batteries, with zinc metal foil anode and Mo-Co3O4-CNTc cathode, exhibited a specific capacity of 195.7 mAh g−1 at 0.5 A g−1, energy density of 237.6 Wh kg−1 at 1692.4 W kg−1, and a remarkable ultralong cycling life of over 10,000 cycles with 85.1% capacity retention. The superior performance can be attributed to the hierarchical porous structures with open spaces acting as “ion-buffering reservoirs.” The summary of zinc ion storage mechanism in the MoCo-Zn batteries was investigated during the charge-discharge process. Therefore, this work promotes the development of innovative strategies to synthesize carbon-modified composites with hierarchical porous nanosheets as cathode materials, for the ultra-long cycle-life aqueous rechargeable ZIBs.

Graphical Abstract

The cathode materials of Mo-doped in hierarchical porous Mo-Co3O4-CNTc composites were fabricated for aqueous rechargeable zinc ions batteries with ultra-long cycle life.

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Funding

This work was supported by the Science and Technology Project of Henan Province (nos. 222102240103 and 192102210048); the Natural Science Foundation of Henan Province (no. 212300410099); the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF2020R1|1A3070962); and the Ph. D. Research Start-up Fund of Anyang Institute of Technology (no. BSJ2019033).

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  1. Henan Joint International Research Laboratory of Nanocomposite Sensing Materials, School of Materials Science and Engineering, Anyang Institute of Technology, Anyang, 455000, People’s Republic of China

    Changwei Lai, Yao Guo, Miaomiao Li & Haixiang Song

  2. Department of Advanced Materials Engineering, Kyungsung University, Busan, 48434, Republic of Korea

    Changwei Lai & Kwan Lee

  3. Department of Optics and Mechatronics Engineering, College of Nanoscience and Nanotechnology, Pusan National University, Busan, 46241, Republic of Korea

    Xiaoxiao Qu

  4. Department of Electronic Materials Engineering, The University of Suwon, Hwaseong, 18323, Republic of Korea

    Kwan Lee

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  1. Changwei Lai
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Contributions

Changwei Lai carried out the experimental parts of materials synthesis and characterizations, and wrote the main manuscript text. Xiaoxiao Qu prepared Fig. 1a. Yao Guo wrote the part “2.6 Computational methods” and prepared Fig. 7. Miaomiao Li prepared some data curation. Haixiang Song and Kwan Lee contributed the writing-review and editing, and funding acquisition. All authors reviewed the manuscript.

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Lai, C., Qu, X., Guo, Y. et al. Hierarchical porous Mo-Co3O4-CNTc nanosheets for aqueous rechargeable zinc ion batteries with ultralong life. Adv Compos Hybrid Mater 6, 91 (2023). https://doi.org/10.1007/s42114-023-00669-6

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