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Basic catalytic performance of amino and acylamide functionalized metal-organic framework in the synthesis of chloropropene carbonate from CO2 under atmospheric pressure

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Abstract

In this work, a metal-organic framework with free standing basic groups(e. g., amino and acylamide groups) decorated in the pore wall was utilized to catalyze the CO2 cycloaddition reaction and its basic properties were tested in Knoevenagel condensation reactions. The results reveal that the metal-organic framework(MOF) material has excellent catalytic activity and high repeatability for the synthesis of chloropropene carbonate from CO2 and epichlorohydrin with no co-catalyst under mild reaction conditions, suggesting that it is a promising heterogeneous catalyst for CO2 cycloaddition reaction.

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Authors and Affiliations

  1. Institute of Applied Chemistry, College of Chemistry, Nanchang University, Nanchang, 330031, P. R. China

    Lili Song, Chao Chen, Xiangbin Chen & Ning Zhang

Authors
  1. Lili Song
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  2. Chao Chen
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  3. Xiangbin Chen
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  4. Ning Zhang
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Corresponding authors

Correspondence to Chao Chen or Ning Zhang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21261017, 21561020) and the Union of Industry Study Fund of Dongguan City, China(No.2014509112210).

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Song, L., Chen, C., Chen, X. et al. Basic catalytic performance of amino and acylamide functionalized metal-organic framework in the synthesis of chloropropene carbonate from CO2 under atmospheric pressure. Chem. Res. Chin. Univ. 32, 838–842 (2016). https://doi.org/10.1007/s40242-016-6076-8

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  • DOI: https://doi.org/10.1007/s40242-016-6076-8

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