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MgFe2O4/cellulose/SO3H nanocomposite: a new biopolymer-based nanocatalyst for one-pot multicomponent syntheses of polysubstituted tetrahydropyridines and dihydropyrimidinones

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Abstract

A new biopolymer cellulose-based magnetic heterogeneous catalyst, MgFe2O4/cellulose/SO3H nanocomposite, was prepared. Fourier-transform infrared spectra, X-ray diffraction, energy-dispersive X-ray, field-emission scanning electron microscopy, thermal analysis (TG, DTG and DSC), dynamic light scattering and vibrating sample magnetometer measurements have been used to characterize the catalyst. Then, it was applied efficiently as an inexpensive and green catalyst in two multicomponent syntheses of polysubstituted tetrahydropyridines and dihydropyrimidinones under solvent-free conditions. The nanocatalyst can be recovered and reused several times without significant loss of catalytic activity.

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Acknowledgements

The authors gratefully acknowledge the partial support from the Research Council of the Iran University of Science and Technology.

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Authors and Affiliations

  1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 1684613114, Iran

    Ali Maleki & Somayeh Yousefi

  2. Department of Chemistry, Faculty of Science, Yazd University, Yazd, 89195.741, Iran

    Abbas Ali Jafari & Somayeh Yousefi

Authors
  1. Ali Maleki
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  2. Abbas Ali Jafari
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  3. Somayeh Yousefi
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Correspondence to Ali Maleki.

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Maleki, A., Jafari, A.A. & Yousefi, S. MgFe2O4/cellulose/SO3H nanocomposite: a new biopolymer-based nanocatalyst for one-pot multicomponent syntheses of polysubstituted tetrahydropyridines and dihydropyrimidinones. J IRAN CHEM SOC 14, 1801–1813 (2017). https://doi.org/10.1007/s13738-017-1120-2

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  • DOI: https://doi.org/10.1007/s13738-017-1120-2

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