Skip to main content
Log in

Investigating the hydrogeological properties of springs in a karstic aquifer in Dorfak region (Guilan Province, Iran)

  • Original Article
  • Published:
Environmental Earth Sciences Aims and scope Submit manuscript

Abstract

Karstic aquifers are considered as the main sources of groundwater in the northeast of Rudbar, Iran. The present study was conducted to evaluate the hydrogeological properties of karstic springs in this region. For this purpose, saturation indices (SI values) were calculated using the geochemical PHREEQC model for a number of minerals in the groundwater in the karstic aquifer. Moreover, AqQA-RockWare software packages were used to prepare hydrogeochemical plots for the aquifer, using which the sources of the ions in the water were identified. The origin of bicarbonate, calcium, and magnesium ions in water was determined using chloro-alkaline indices. Moreover, through plotting a Piper diagram for spring water samples, it was discovered that water type of all springs is the Ca-HCO3 type, confirming the karstic characteristic of springs in the area. A Durov diagram also suggests that the water composition of the springs is of the bicarbonate type with the dominant Ca cation, suggesting the calcareous effects of the region on the quality of groundwater and exhibiting a single source for the springs. The calculated saturation indices show that most of the water samples are undersaturated with respect to calcite, dolomite, and CO2. The stable isotopes (δ18O and δ2H) and deuterium excess values were used to get information about transport pathways in groundwater, atmospheric moisture, and the degree of interaction between these reservoirs. The degree of karstification of the recharge area of the karst aquifer was determined to be 5.5 from an analysis of the hydrograph Sefidab Spring.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3

(Reproduced with the permission from Safari et al. 2013)

Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17

Similar content being viewed by others

References

  • Aggarwal PK, Froehlich K, Gonfiantini R, Gat JR (2005) Isotope hydrology: a historical perspective from the IAEA. In: Aggarwal PK, Gat JR, Froehlich K (eds) Isotopes in the water cycle: past, present and future of a developing science. Springer, Berlin, pp 3–8

    Chapter  Google Scholar 

  • Aghazadeh N, Asghari Mogaddam A (2011) Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, Iran. Environ Monit Assess 176:183–195

    Article  Google Scholar 

  • Castany G (1968) Prospection et Exploitation des Eaux Souterraines. DUNOT, Paris

    Google Scholar 

  • Chidambaram S, Karmegam U, Prasanna MV, Sasidhar P, Vasanthavigar M (2011) A study on hydrochemical elucidation of coastal groundwater in and around Kalpakkam region, Southern India. Environ Earth Sci 64:1419–1431

    Article  Google Scholar 

  • Clark I, Fritz P (1997) Environmental isotopes in hydrogeology. Lewis, Boca Raton

    Google Scholar 

  • Coetsiers M, Walraevens K (2006) Chemical characterization of the Neogene Aquifer, Belgium. Hydrogeol J 14:1556–1568

    Article  Google Scholar 

  • Drever JI (1997) The geochemistry of natural waters, 3rd edn. Prentice Hall, New Jersey, p 436

    Google Scholar 

  • Ferronsky VI, Polyakov VA (2012) Isotopes of the earth’s hydrosphere. Springer, Berlin, p 567

    Book  Google Scholar 

  • Florea LJ, McGee DK (2010) Isotopic and geochemical variability within shallow groundwater beneath a hardwood hammock and surface water in an adjoining slough (Everglades National Park, Florida, USA). Isot Environ Health Stud 46:190–209

    Article  Google Scholar 

  • Ford D, Williams P (2007) Karst hydrogeology and geomorphology. Wiley, New York, pp 1–562

    Book  Google Scholar 

  • Fröhlich K, Gibson JJ, Aggarwal P (2002) Deuterium excess in precipitation and its climatological significance. http://www.iaea.org/inis/collection/NCLCollectionStore/_Public/34/017/34017972.pdf

  • Gams I (1974) Kras = Karst, Slovenska Matica. Ljubljana, Slovenia

    Google Scholar 

  • Gat JR (1996) Oxygen and hydrogen isotopes in the hydrologic cycle. Ann Rev Earth Planet Sci 24:225–262

    Article  Google Scholar 

  • Gibbs RJ (1970) Mechanism controlling world water chemistry. Science 170:1088–1090

    Article  Google Scholar 

  • Giggenbach WF (1988) Geothermal solute equilibria. Derivation of Na–K–Mg–Ca geoindicators. Geochim Cosmochim Acta 52:2749–2765

    Article  Google Scholar 

  • Guler C, Thyne GD (2004) Hydrologic and geologic factors controlling surface and groundwater chemistry in Indian Wells-Owens Valley area, southeastern California, USA. J Hydrol 285:177–198

    Article  Google Scholar 

  • Hatipoglu-Bagci Z, Sazan MS (2014) Characteristics of karst springs in Aydıncık (Mersin, Turkey), based on recession curves and hydrochemical and isotopic parameters. Q J Eng Geol Hydrogeol 47(2014):89–99

    Article  Google Scholar 

  • Herczeg AL, Leaney FW (2011) Environmental tracers in arid–zone hydrology. Hydrogeol J 19:17–29

    Article  Google Scholar 

  • Hobbs SL, Smart PL (1986) Characterization of carbonate aquifers: a conceptual base. In: Proceedings of the 9th international congress of speleology, Barcelona, vol 1, pp 43–46

  • Howard KWF, Mullings E (1996) Hydrochemical analysis of groundwater flow and saline intrusion in the Clarendon basin, Jamaica. Groundwater 34:801–810

    Article  Google Scholar 

  • http://karst.iah.org

  • IAEA (2005) Isotopic composition of precipitation in the Mediterranean Basin in relation to air circulation patterns and climate. Final report of a coordinated research project 2000–2004, p 230

  • Jeelani G, Shah RA, Deshpande RD, Fryar AE, Perrin J, Mukherjee A (2017) Distinguishing and estimating recharge to karst springs in snow and glacier dominated mountainous basins of the western Himalaya, India. J Hydrol 550(2017):239–252

    Article  Google Scholar 

  • Kresic N, Bonacci O (2010) Spring discharge hydrograph. In: Kresic N, Stevanovic Z (eds) Groundwater hydrology of springs: engineering, theory, management, and sustainability, Chap 4. Elsevier, Amsterdam, pp 129–163

  • Krishnaraj S, Murugesan V, Vijayaraghavan K, Sabarathinam C, Paluchamy A, Ramachandran M (2011) Use of hydrochemistry and stable isotopes as tools for groundwater evolution and contamination investigations. Geosciences 1(1):16–25. https://doi.org/10.5923/j.geo.20110101.02

    Google Scholar 

  • Kuhta M, Brkić Ž, Stroj A (2012) Hydrodynamic characteristics of Mt. Biokovo foothill springs in Croatia. Geol Croat 65(1):41–51

    Article  Google Scholar 

  • Lambs L, Moussa I, Brunet F (2013) Air masses origin and isotopic tracers: a study case of the oceanic and Mediterranean Rainfall Southwest of France. Water 5:617–628. https://doi.org/10.3390/w5020617

    Article  Google Scholar 

  • Lastennet R, Mudry J (1997) Role of karstification and rainfall in the behavior of a heterogeneous karst system. Environ Geol 32(2):114–123

    Article  Google Scholar 

  • Li PY, Qian H, Wu JH, Ding J (2010) Geochemical modeling of groundwater in southern plain area of Pengyang County, Ningxia, China. Water Sci Eng 3(3):282–291

    Google Scholar 

  • Malík P, Vojtková S (2012) Use of recession-curve analysis for estimation of karstification degree and its application in assessing overflow/underflow conditions in closely spaced karstic springs. Environ Earth Sci 65(8):2245–2257

    Article  Google Scholar 

  • Marie A, Vengosh A (2001) Sources of salinity in ground water from Jericho area, Jordan Valley. Ground Water 39:240–248

    Article  Google Scholar 

  • McLean W, Jankowski J, Lavitt N (2000) Groundwater quality and sustainability in an alluvial aquifer, Australia. In: Sililo O et al (eds) Groundwater, past achievements and future challenges. A Balkema, Rotterdam, pp 567–573

    Google Scholar 

  • Mijatovic B (1970) A method of studying the hydrodynamic regime of karst aquifers by analysis of the discharge curve and level fluctuation during recession. Institute for Geological and Geophysical Research, Beograd

    Google Scholar 

  • Milanovic P (1981) Karst hydrogeology. Water Resources Publications, Littleton, p 434

    Google Scholar 

  • Mohammadzadeh H, Aravena R (2015) Investigating the origin and interaction between Karstic and Alluvial Aquifers in NW of Zagros Mountain Range, Iran, using isotopic and geochemical tools. Proc Earth Planet Sci 13(2015):256–260

    Article  Google Scholar 

  • Mustafa O, Merkel B, Weise SM (2015) Assessment of hydrogeochemistry and environmental isotopes in karst springs of Makook Anticline, Kurdistan Region, Iraq. Hydrology 2:48–68. https://doi.org/10.3390/hydrology2020048

    Article  Google Scholar 

  • Piper AM (1944) A graphic procedure in the geochemical interpretation of water analyses. Am Geophys Union Trans 25:914–923

    Article  Google Scholar 

  • Safari HO, Ghassemi MR, Razavi-Pash R (2013) Determination and structural analysis of the Lahijan transverse fault in forestall region of Alborz Mountains, Iran: a geospatial application. Int J Rem Sens Appl. https://doi.org/10.14355/ijrsa.2013.0304.06215

    Google Scholar 

  • Sanford WE, Aeschbach-Hertig W, Herczeg AL (2011) Preface: insights from environmental tracers in groundwater systems. Hydrogeol J 19:1–3

    Article  Google Scholar 

  • Schoeller H (1977) Geochemistry of groundwater. Groundwater studies—an international guide for research and practice, vol 15. UNESCO, Paris, pp 1–18

    Google Scholar 

  • Shamsi A, Kazemi GA (2014) A review of research dealing with isotope hydrology in Iran and the first Iranian meteoric water line. Geopersia 4:73–86

    Google Scholar 

  • Sidle WC (1998) Environmental isotopes for resolution of hydrology problems. Environ Monit Assess 52:389–410

    Article  Google Scholar 

  • Singh EJ, Gupta A, Singh NR (2013) Groundwater quality in Imphal West district, Manipur, India, with multivariate statistical analysis of data. Environ Sci Pollut Res Int 20:2421–2434

    Article  Google Scholar 

  • Singhal BBS, Gupta RP (1999) Applied hydrogeology of fractured rocks. Kluwer Academic Publisher, Dordretch, p 400

    Book  Google Scholar 

  • Srinivasamoorthy K, Vasanthavigar M, Vijayaraghavan K, Sarathidasan R, Gopinath S (2011) Hydrochemistry of groundwater in a coastal region of Cuddalore district, Tamilnadu, India: implication for quality assessment. Arab J Geosci. https://doi.org/10.1007/s12517-011-0351-2

    Google Scholar 

  • Stober I, Bucher K (1999) Deep groundwater in the crystalline basement of the Black Forest region. Appl Geochem 14:237–254

    Article  Google Scholar 

  • Stossel RK (1997) Delineating the chemical composition of the salinity source for saline groundwater: an example from east central Canadian Parish, Luisiana. Ground Water 35:409–417

    Article  Google Scholar 

  • Subba Rao N (2002) Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India. Environ Geol 41:552–562

    Article  Google Scholar 

  • Subramani T, Elango L, Damodarasamy SR (2005) Groundwater quality and its suitability for drinking and agricultural use in Chithar River Basin, Tamil Nadu, India. Environ Geol 47:1099–1110

    Article  Google Scholar 

  • Thomas JM, Rose TP (2003) Environmental isotopes in hydrogeology. Environ Geol 43:532

    Google Scholar 

  • Timms W, Acworth RI, Jankowski J, Lawson S (2000) Groundwater quality trends related to aquitard salt storage at selected sites in the Lower Murumbidgee alluvium, Australia. Groundwater 25:655–660

    Google Scholar 

  • White WB (1969) Conceptual models for carbonate aquifers. Ground Water 7(3):15–21

    Article  Google Scholar 

  • White WB (1997) Thermodynamic equilibrium, kinetics, activation barriers, and reaction mechanisms for chemical reactions in karst terrains. Environ Geol 30:46–58

    Article  Google Scholar 

  • Zhang J, Huang WW, Letolle R, Jusserand C (1995) Major element chemistry of the Huanghe (Yellow River), China—weathering processes and chemical fluxes. J Hydrol 168:173–203

    Article  Google Scholar 

Download references

Acknowledgements

We would like to show our gratitude to the management of the Regional Water Company of Guilan Province and Mr. Fatehi, the head of the Office of Water Resources Studies, for the support of this research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Dehban Avan Stakhri.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ghobadi, M.H., Dehban Avan Stakhri, M. & Mirarabi, A. Investigating the hydrogeological properties of springs in a karstic aquifer in Dorfak region (Guilan Province, Iran). Environ Earth Sci 77, 96 (2018). https://doi.org/10.1007/s12665-018-7270-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12665-018-7270-4

Keywords

Navigation