Abstract
In Morocco, the production of argan oil generates a natural organic residue available at a low cost, which is known as argan cake. It shows potential as a biodiesel resource due to its substantial oil residue content. A kinetic study of transesterification was conducted to evaluate the potential of argan cake oil (ACO) in producing biodiesel. The obtained activation energy is equal to Ea = 30.85 kJ/mol, and the reaction rate falls within the range of 0.0121 to 0.0241 min−1 at temperatures between 40 and 60 °C. Realizing that the catalyst type has a significant impact on the reaction kinetics, a comparison was made between homogeneous, heterogeneous, and enzymatic catalysts using the multi-criteria decision-making (MCDM) method. This method was employed to select the catalyst that maximizes biodiesel yield while minimizing cost and environmental impact. Five catalyst types were studied: homogeneous acid and basic catalysts, heterogeneous acid and basic catalysts, and enzymatic catalysts. In the classification process, eight criteria were considered: catalyst sensitivity to free fatty acid (FFA) and water in the raw material, biodiesel yield, reaction rate, glycerol recovery, catalyst recovery and recycling, energy cost, catalyst cost, and environmental impact. The results from the Fuzzy Technique for Order of Preference by Similarity to the Ideal Solution (FTOPSIS) showed that the basic heterogeneous catalyst outperforms the other four examined catalysts.
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References
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Acknowledgements
This study was performed within the framework of a research project funded by the Ministry of National Education, Vocational Training, Higher Education and Scientific Research (Morocco) / Department of Higher Education and Scientific Research (MENFPESRS/DESRS). The authors would like to thank MENFPESRS/DESRS for the financial support.
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Bahani, N., El Kourdi, S. & Abderafi, S. Argan Cake Oil Transesterification Kinetics and an Optimized Choice of a High-Performance Catalyst for Biodiesel Production. Waste Biomass Valor 15, 2591–2610 (2024). https://doi.org/10.1007/s12649-023-02315-0
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DOI: https://doi.org/10.1007/s12649-023-02315-0