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(Ti-Mo-Zr)60AlxSiy High Entropy Alloy: Correlation Between Microstructure, Mechanical, and Corrosion Properties

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Abstract

Multicomponent (Ti, Mo, Zr, Al, and Si) high-entropy alloys (HEAs) are prepared via high energy ball milling technique and followed by spark plasma sintering (SPS) technique for their compaction using the general formula (Ti-Mo-Zr)60AlxSiy (labeled as (TMZ)60AlxSiy)) where x & y as at% of equiatomic and non-equiatomic stoichiometric ratios of Ti, Mo, Zr, Al, and Si elements. XRD traces recorded the presence of FCC and BCC solid solution phases, at 20 h of milling schedule and stability of as precipitated phases are analyzed using DSC profiles. Mechanical properties include maximum load, compressive strength, Young’s Modulus, and Vickers’s hardness are acquired to be maximum for equiatomic (TMZ)60Al30Si10 HEA pellet (rate of heat treatment: 125 °C/min), compared with all other compositions under investigation. The superior corrosion properties such as corrosion current density (ic), passive current density (ip), corrosion potential (Ec), and passive potential (Ep) of obtained non-equiatomic (TMZ)60Al30Si10 HEA pellet made this group of the network an expected possibility for use in lightweight vehicle applications.

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Acknowledgements

The author wishes to thank Mrs. Tanu Sri Vasthava, Scientist “G” DMRL, and Hyderabad for helping out us to carryout SEM analysis. This work is partially supported by GITAM (Deemed to be university), under seed grant with grant No: 2021/0033.

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Authors and Affiliations

  1. Department of Mechanical Engineering, School of Technology, GITAM (Deemed to be University), Hyderabad, 502329, India

    Kiran Kumar Karnati & Eshwaraiah Punna

  2. Department of Mechanical Engineering, National Institute of Technology (NIT-Raipur), Raipur, CG-492010, India

    Swamy Naidu Neigapula Venkata

  3. Department of Physics, School of Technology, GITAM (Deemed to be University), Hyderabad, 502329, India

    Balaji Rao Ravuri

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  1. Kiran Kumar Karnati
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  2. Eshwaraiah Punna
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Contributions

Kiran Kumar Karnati (Lead) – Conceptualization, Eshwaraiah Punna and Kiran Kumar Karnati (Lead) - Data curation, Kiran Kumar Karnati, and Swamy Naidu Neigapula Venkata (Lead) – Methodology, Kiran Kumar Karnati and Balaji Rao Ravuri (Lead) – Conceptualization, Data curation and Drafting.

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Correspondence to Balaji Rao Ravuri.

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Karnati, K.K., Punna, E., Venkata, S.N.N. et al. (Ti-Mo-Zr)60AlxSiy High Entropy Alloy: Correlation Between Microstructure, Mechanical, and Corrosion Properties. Silicon 14, 10637–10650 (2022). https://doi.org/10.1007/s12633-022-01779-4

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  • DOI: https://doi.org/10.1007/s12633-022-01779-4

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