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A review on photocatalytic systems capable of synchronously utilizing photogenerated electrons and holes

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Abstract

With the continuous progress and development of current industrial civilization, energy crisis and environmental pollution are serious problems that threaten human beings need to be solved. Photocatalytic technologies that can use clean solar light energy to manufacture clean H2 fuel and high value chemicals provide a feasibility to solve the above problem. However, traditional photocatalytic water splitting mainly focused on the utilization of photogenerated electrons to produce H2 which leads to the waste of the holes. It is vital to develop photocatalysts capable of synchronously utilizing photogenerated electrons and holes for the future practical application. In this paper, the latest progress of photocatalytic system with collaborative photooxidation-reduction application has been summarized, and water splitting for H2 production combining different organic synchronous reaction process has been clarified. Finally, the prospect of photocatalysts capable of synchronously utilizing photogenerated electrons and holes are proposed.

Graphical abstract

摘要

随着当前工业文明的不断进步和发展, 能源危机和环境污染是威胁人类的严重问题, 亟待解决。利用清洁的太阳能将光能转化为清洁的H2燃料和高价值化学品的光催化技术为解决上述问题提供了可行性。然而, 传统的光催化水裂解主要集中在利用光产生的电子来生产H2, 这导致了空穴的浪费。开发能够同步利用光生电子和空穴的光催化剂对未来的实际应用至关重要。本文总结了具有协同光氧化-还原应用的光催化系统的最新进展, 并阐明了结合不同有机同步反应过程的水分裂制氢。最后, 提出了同步利用光生电子和空穴的光催化剂的前景。

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Reproduced with permission from Ref. [63]. Copyright 2021, Elsevier

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Reproduced with permission from Ref. [33]. Copyright 2020, Wiley

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Reproduced with permission from Ref. [79]. Copyright 2018, American Chemical Society

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Reproduced with permission from Ref. [80]. Copyright 2021, Elsevier

Fig. 8

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Fig. 10

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 21975110 and 21972058) and Taishan Youth Scholar Program of Shandong Province.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Jiangsu University, Zhenjiang, 212013, China

    Li-Juan Sun, Hai-Wei Su, Qin-Qin Liu, Jie Hu, Le-Le Wang & Hua Tang

  2. School of Environmental Science and Engineering, Qingdao University, Qingdao, 266071, China

    Hua Tang

  3. State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China

    Le-Le Wang

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  1. Li-Juan Sun
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  2. Hai-Wei Su
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  6. Hua Tang
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Correspondence to Qin-Qin Liu, Jie Hu or Hua Tang.

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Sun, LJ., Su, HW., Liu, QQ. et al. A review on photocatalytic systems capable of synchronously utilizing photogenerated electrons and holes. Rare Met. 41, 2387–2404 (2022). https://doi.org/10.1007/s12598-022-01966-7

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  • DOI: https://doi.org/10.1007/s12598-022-01966-7

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