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Physicochemical sensitivities of tropical peat to electrokinetic environment

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Abstract

Tropical peat is unconsolidated superficial deposits with high non-crystalline colloid (humus) content, constituting the subsurface of wetland systems. Laboratory experiments were carried out on a very slightly decomposed fibric and a highly decomposed amorphous, undisturbed tropical peat soils, to determine the physicochemical effects on the peats due to electrokinetic (EK) treatment in terms of mechanisms and resulting effects in the presence of peat water. The different specimens were treated for 3, 6, 12, and 20-day periods. A constant electrical potential of 40 V was applied across the specimens. The untreated and treated specimens were tested for liquid limit (LL), undrained shear strength (Su), water content (WC), zeta potential (ζ), pH, and cation exchange capacity (CEC). The peat water flew from anode to cathode because of the negative charges on the humus. In the vicinity of the anode, the CEC and ζ of the specimens decreased, and the Su and LL of the specimens increased because of the acidic conditions, while alkaline conditions at the cathode had an opposite effect. The sensitivity of the amorphous peat to the EK environment was higher than the sensitivity of the fibric peat to the EK environment because of larger quantities of the colloids and quality of the charges. The acid/base distributions in EK soil processing influenced the soil surface charges, which were fully pH-dependent, resulting in the variations of the CEC and ζ. The ζ variations caused thinning and expanding of the diffuse double layer around the humus particles, and were linked to the flocculation and dispersion of the particles, and subsequently affected the LL and Su of the specimens. The study was found its significance in that it confirmed the relationship between the degree of peat decomposition and the peat sensitivity to the EK treatment.

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References

  • Acar, Y.B., Gale, R.J., Putnam, G.A, Hamed, J., and Wong, R. L., 1990, Electrochemical processing of soils: Theory of pH gradient development by diffusion, migration, and linear convection. Journal of Environmental Science and Health, Part A, 6, 687–714.

    Article  Google Scholar 

  • Acar, Y.B. and Alshawabkeh, A.N., 1993, Principles of Electrokinetic Remediation. Environmental Science and Technology, 27, 2638–2647.

    Article  Google Scholar 

  • Alshawabkeh, A.N. and Acar, Y.B., 1992, Removal of Contaminants from Soils by Electrokinetics: A Theoretical Treatise. Journal of Environmental Science and Health, A27, 1835–1861.

    Article  Google Scholar 

  • Asadi, A., Huat, B.B.K, Hanafi, M.M., Mohamed, T.A., and Shariatmadari, N., 2009, Role of organic matter on electroosmotic properties and ionic modification of organic soils. Geosciences Journal, 13, 175–181.

    Article  Google Scholar 

  • Asavadorndeja, P. and Glawe, U., 2005, Electrokinetic strengthening of soft clay using the anode depolarization method. Bulletin of Engineering Geology and the Environment, 64, 237–245.

    Article  Google Scholar 

  • ASTM D 1997-91, Test Method for the Laboratory Determination of Fiber Content of Peat Samples by Dry Mass. American Society for Testing and Materials, West Conshohochen, PA, 275–276.

  • ASTM D 2974-87, Test Method for Moisture, Ash, Organic Matter of Peat and Other Organic Soils. American Society for Testing and Materials, West Conshohochen, PA, 401–402.

  • Barker, J.E, Rojers, C.D.F., Boardman, D.I., and Peterson, J., 2004, Electrokinetic stabilization: an overview and case study. Ground Improvement, 8, 47–58.

    Google Scholar 

  • Brady, N.C. and Weil, R.R., 2007, The Nature and Properties of Soils. Prentice Hall, New Jersey, 980 p.

    Google Scholar 

  • Brindley, G.W. and Brown, G., 1980, Crystal structure of clay minerals and their X-ray identification. Mineralogical Society, London, 495 p.

    Google Scholar 

  • British Standard Institution, 1990, Methods of test for soils for civil engineering purposes. BSI1377, Part 1-9, HMSO, London, 427 p.

    Google Scholar 

  • Casagrande, L., 1949, Electro-osmosis in soils. Geotechnique, 1, 159–177.

    Article  Google Scholar 

  • Casagrande, L., 1983, Stabilization of soils by means of electroosmosis state of the art. Journal Boston Society of Civil Engineers, 69, 255–302.

    Google Scholar 

  • Castillo, A.M., Soriano, J.J., and Delgado, R.A.G., 2008, Changes in chromium distribution during the electrodialytic remediation of a Cr (VI)-contaminated soil. Environmental Geochemistry and Health, 30, 153–157.

    Article  Google Scholar 

  • Das, M.B., 2008, Advanced Soil Mechanics. Taylor and Francis, New York, 567 p.

    Google Scholar 

  • Dengiz, O., Ozaytekin, H.H., Cayci, G., and Baran, A., 2009, Characteristics, genesis and classification of a basin peat soil under negative human impact in Turkey. Environmental Geology, DOI 10.1007/s00254-008-1206-3.

  • Edil, T.B. and Fox, P.J., 2000, Geotechnics of High Water Content Materials. ASTM, West Conshohocken, PA, 392 p.

    Book  Google Scholar 

  • Eykholt, G.R. and Daniel, D.E., 1994, Impact of system chemistry on electroosmosis in contaminated soil. Journal of Geotechnical Engineering, ASCE, 120, 797–815.

    Article  Google Scholar 

  • Fang, H.Y. and Daniels, J.L., 2006, Introductory Geotechnical Engineering: An environmental perspective. Taylor and Francis, New York, 545 p.

    Google Scholar 

  • Fernandez, A., Hlavackova, P., Pome’s, V., and Sardin M., 2009, Physicochemical limitations during the electrokinetic treatment of a polluted soil. Chemical Engineering Journal, 145, 355–361.

    Article  Google Scholar 

  • Forsberg, S. and Alden, L., 1988, Dewatering of peat: characterization of colloidal and subcolloidal particles in peat. Colloids Surfaces, 34, 355–343.

    Article  Google Scholar 

  • Gillman, G.P. and Sumpter, E.A., 1986, Modification to compulsive exchange method for measuring exchange characteristics of soils. Australian Journal of Soil Research, 24, 61–66.

    Article  Google Scholar 

  • Gray, D.H., 1970, Electrochemical hardening of clay soils. Geotechnique, 20, 81–93.

    Article  Google Scholar 

  • Gray, D.H. and Mitchell, H.K., 1967, Fundamental aspects of electro-osmosis in soils. Journal of the Soil Mechanics and Foundations, ASCE, 93, 209–236.

    Google Scholar 

  • Han, S.-J., Kim, S.-S., and Kim, B.-I., 2004, Electroosmosis and pore pressure development characteristics in lead contaminated soil during electrokinetic remediation. Geosciences Journal, 8, 85–93.

    Article  Google Scholar 

  • Huat, B.K., Gew, S.S., and Ali, F.H., 2004, Tropical Residual Soils. Routledge, London, 245 p.

    Google Scholar 

  • Huat, B.K., 2004, Organic and Peat Soils Engineering. Serdang, University Putra, Malaysia Press, 146 p.

    Google Scholar 

  • Huat, B.K., Ali, F.H., and Low, T.H., 2006, Water infiltration characteristics of unsaturated soil slope and its effect on suction and stability. Geotechnical and Geological Engineering, 24, 1293–1306.

    Article  Google Scholar 

  • Hunter, R.J., 1981, Zeta potential in colloid science: Principles and Applications. Academic Press, London, 386 p.

    Google Scholar 

  • Kim, S.O., Kim, W.S., and Kim, K.W., 2005, Evaluation of electrokinetic remediation of arsenic-contaminated soils. Environmental Geochemistry and Health, 27, 443–453.

    Article  Google Scholar 

  • Kwak, J.C.T., Ayub, A.L., and Sheppard, J.D., 1986, The role of Colloid Science in Peat Dewatering: Principles and Dewatering Studies. In: Fuchsman, C.H. (ed.), Peat and Water: Aspects of Water Retention and Dewatering in Peat. Elsevier Applied Science Publishers Ltd., New York, p. 95–118.

    Google Scholar 

  • Lee, M.H., Kamon, M., Kim, S.S., Lee, J.Y., and Chung, H.I., 2007, Desorption characteristics of kaolin clay contaminated with zinc from electrokinetic soil processing. Environmental Geochemistry and Health, 29, 281–288.

    Article  Google Scholar 

  • Loughnan, F.C., 1969, Chemical Weathering of Silicate Minerals. Elsevier, New York, 145 p.

    Google Scholar 

  • Mikutta, R., Kleber, M., Kaiser, K., and Jahn, R., 2005, Organic Matter Removal from Soils using Hydrogen Peroxide, Sodium Hypochlorite, and Disodium Peroxodisulfate. Soil Science Society of America Journal, 69, 120–135

    Article  Google Scholar 

  • Mitchell, J.K. and Soga, K., 2005, Fundamentals of Soil Behavior. John Wiley and Sons, New Jersey, 577 p.

    Google Scholar 

  • Mohamed, A.M.O. and Antia, H.E., 1998, Geoenvironmental Engineering (Developments in Geotechnical Engineering). Elsevier Science, Amsterdam, 730 p.

    Google Scholar 

  • Mohamedelhassan, E. and Shang, J.Q., 2003, Electrokinetics generated pore fluid and ionic transport in an offshore calcareous soil. Canadian Geotechnical Journal, 40, 1185–1199.

    Article  Google Scholar 

  • Naik, D., 1986, Effect of temperature and pore fluid on shear characteristic of clay. In: Proceedings of the 1st International Symposium on Environmental Geotechnology, 1, 382–390.

    Google Scholar 

  • Ozkan, S., Gale, R.J., and Seals, R.K., 1999, Electrokinetic stabilization of kaolinite by injection of Al and PO4 3 ions. Ground Improvement, 3,135–144.

    Google Scholar 

  • Stern, O.Z., 1924, Electrochemistry, 30, 508.

    Google Scholar 

  • Stevenson, F.J., 1994, Humus Chemistry: Genesis, Composition, Reactions. John Wiley and Sons, New York, 496 p.

    Google Scholar 

  • Sze, A., Erickson, D., Ren, L., and Li, D., 2003, Zeta-potential measurement using the Smoluchowski equation and the slope of current-time relationship in electroosmotic flow. Journal of Colloid and Interface Science, 261, 402–410

    Article  Google Scholar 

  • Weng, C.H. and Yuan, C., 2001, Removal of Cr(III) from Clay Soils by Electrokinetics. Environmental Geochemistry and Health, 23, 281–285.

    Article  Google Scholar 

  • Yu, T.R., 1997, Chemistry of Variable Charge Soils. Oxford University Press, New York, 520 p.

    Google Scholar 

  • Yule, C.M., and Gomez, L.N., 2008, Leat litter decomposition in a tropical peat swamp forest in Peninsular Malaysia. Wetlands Ecology and Management, DOI 10.1007/s11273-008-9103-9.

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Correspondence to Afshin Asadi.

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Asadi, A., Huat, B.B.K., Hanafi, M.M. et al. Physicochemical sensitivities of tropical peat to electrokinetic environment. Geosci J 14, 67–75 (2010). https://doi.org/10.1007/s12303-010-0008-2

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  • DOI: https://doi.org/10.1007/s12303-010-0008-2

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