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Dehydro-Diels—Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6

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Abstract

Dehydro-Diels—Alder (DDA) reaction is a textbook reaction for preparing six-membered rings in solution but is scarcely seen in solid-state synthesis. In this work, using multiple characterization techniques, we demonstrate that the bowl-shaped clusters C18Te3Br4(Bu-O)6 might experience a DDA reaction at room temperature and high pressure between 5.5 and 7.4 GPa. Above 17.0 GPa, it is found that the bonding conversion from the intramolecular sp2 to the intermolecular sp3 occurred, in the form of pressure-induced diamondization. The recovered samples from 20.0 and 36.1 GPa showed incomplete reversibility, while the decompression-induced graphitization of glassy carbon was observed during decompression from 46.5 GPa. The electrochemical impedance spectroscopy results indicated that the transport properties changed from grain boundary dominant to grain dominant due to the DDA reaction and the grain boundary effect disappeared as the intermolecular sp3 bonding building-up and carrier transmission channel formation above 17.0 GPa. The results in this study open a new route to construct the crystalline carbon materials with different transport properties.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 52090020 and 11874076) and the National Research Foundation of Korea (Nos. 2016K1A4A3914691 and 2018R1DA1B070498).

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Authors and Affiliations

  1. College of Physical Science and Technology, Yangzhou University, Yangzhou, 225002, China

    Jinbo Zhang, Manli Ma, Rong Zhou, Hongqiang Chu, Xue Wang, Rongxing Cao, Guoqing Wu & Xianghua Zeng

  2. Center for High Pressure Science (CHiPS), State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, China

    Jinbo Zhang, Shaojie Wang, Lin Wang & Yongjun Tian

  3. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, China

    Huhu Tian & Hao-Li Zhang

  4. Baotou Research Institute of Rare Earths, Baotou, 014000, China

    Huhu Tian

  5. Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen, 518055, China

    Zhipeng Yan

  6. Center for High Pressure Science and Technology Advanced Research, Shanghai, 201203, China

    Mingtao Li

  7. Department of Physics, and High Pressure Research Center, Hanyang University, Seoul, 04763, Republic of Korea

    Zhongyan Wu, Bin Li, Jiafeng Yan, Lan Anh Thi Nguyen & Jaeyong Kim

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  1. Jinbo Zhang
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Zhang, J., Ma, M., Zhou, R. et al. Dehydro-Diels—Alder reaction and diamondization of bowl-shaped clusters C18Te3Br4(Bu-O)6. Nano Res. 15, 4606–4612 (2022). https://doi.org/10.1007/s12274-022-4215-8

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