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Hierarchical yolk-shell structured Li-rich cathode boosting cycling and voltage stabled LIBs

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Abstract

Despite the high energy density of lithium-rich (Li-rich) cathodes, their implementation is hampered by the unsatisfied rate capacity and poor cycling performance accompanied with substantial voltage decay. To address these issues, the hierarchical yolk-shell structured Li1.2Mn0.54Ni0.13Co0.13O2 cathodes (YK-LMNCO) was proposed and synthesized through a facile glycerol assisted solvothermal approach and the following lithiation process. Benefitting from the shortened lithium diffusion lengths and the enhanced tolerance to the large volume variation upon lithium ions intercalation/de-intercalation, the unique structure reciprocates an initial coulombic efficiency of 85.8%, an outstanding capacity retention rate of 89.1% after cycling at 2.0 C for 200 cycles with a minor voltage drop, and a capacity retention rate of 93.8% after cycling at 10.0 C for 500 cycles, 85.2% for 1,000 cycles. When assembled with graphite as anode, the YK-LMNCO//graphite full cell shows a remarkable capacity retention rate of 87.2% after cycling at 5.0 C for 50 cycles. Our facile strategy for constructing the yolk-shell structured Li-rich cathodes with high capacity and voltage stability sheds light on synthesizing other lithium storage materials.

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Acknowledgements

The authors acknowledge the financial support from Natural Science Foundation of Guangdong Province (No. 2018A030313721), the National Key Research and Development Program of China (No. 2018YFB0703500) and the National Natural Science Foundation of China (No. 91963113).

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  1. Yanchen Liu and Yafen Chen contributed equally to this work.

Authors and Affiliations

  1. Shenzhen Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China

    Yanchen Liu, Yafen Chen, Jing Wang, Wei Wang, Zhiyu Ding, Leyuan Li, Yang Zhang & Junwei Wu

  2. School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin, 300072, China

    Yanchen Liu, Yida Deng & Yanan Chen

  3. School of Materials Science and Engineering, Hainan University, Haikou, 570228, China

    Yida Deng

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  1. Yanchen Liu
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Liu, Y., Chen, Y., Wang, J. et al. Hierarchical yolk-shell structured Li-rich cathode boosting cycling and voltage stabled LIBs. Nano Res. 15, 3178–3186 (2022). https://doi.org/10.1007/s12274-021-3890-1

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