Abstract
One of the effective techniques for improving separation properties of polymeric membranes is incorporation of suitable nanoparticles into their matrices. This study presents the preparation of three types of nanocomposite membranes comprising three grades of poly (ether-block-amide) (Pebax 1074, Pebax 1657 and Pebax 2533) and modified multi-walled carbon nanotubes (MWCNTs) with different loadings (1, 1.5, 2 and 2.5 wt%). The prepared membranes were characterized by field emission scanning electron microscopy (FESEM), attenuated total reflection-Fourier transfer infrared spectroscopy (ATR-FTIR) and X-ray diffraction (XRD). Permeation of CO2 and CH4 gases through the prepared membranes was measured at the pressure range of 2-8 bars and 25 °C. The results showed that the incorporation of MWCNTs into the polymers matrices improves CO2/CH4 selectivity. Further, Pebax 1074/MWCNT nanocomposite membrane exhibits better performance for CO2/CH4 separation compared to the neat Pebax and the two other nanocomposite membranes.
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D. Zhao, J. Ren, H. Li, X. Li and M. Deng, J. Membr. Sci., 467, 41 (2014).
J. K. Adewole and A. L. Ahmad, Korean. J. Chem. Eng., 33, 2998 (2016).
M. T. Ravanchi, S. Sahebdelfar and F. T. Zangeneh, Front. Chem. Sci. Eng., 5, 173 (2011).
W. Yave, A. Car and K. V. Peinemann, J. Membr. Sci., 350, 124 (2010).
A. Car, C. Stropnik, W. Yave and K.-V. Peinemann, Sep. Purif. Technol., 62, 110 (2008).
N. Azizi, T. Mohammadi and R. M. Behbahani, J. Energy Chem., (2017).
L. M. Robeson, J. Membr. Sci., 62, 165 (1991).
L. M. Robeson, J. Membr. Sci., 320, 390 (2008).
L. Robeson, B. Freeman, D. Paul and B. Rowe, J. Membr. Sci., 341, 178 (2009).
M. A. Semsarzadeh, B. Ghalei, M. Fardi, M. Esmaeeli and E. Vakili, Korean. J. Chem. Eng., 31, 841 (2014).
F. Peng, L. Lu, H. Sun, Y. Wang, H. Wu and Z. Jiang, J. Membr. Sci., 275, 97 (2006).
M. Sadeghi, H. T. Afarani and Z. Tarashi, Korean J. Chem. Eng., 32, 97 (2015).
D. Zhao, J. Ren, H. Li, K. Hua and M. Deng, J. Energy Chem., 23, 227 (2014).
H. Lin and B. D. Freeman, J. Mol. Struct., 739, 57 (2005).
N. Azizi, T. Mohammadi and R. M. Behbahani, J. Nat. Gas. Sci. Eng., 37, 39 (2017).
A. Jomekian, R. M. Behbahani, T. Mohammadi and A. Kargari, Korean J. Chem. Eng., 34, 440 (2017).
S. Kim, L. Chen, J. K. Johnson and E. Marand, J. Membr. Sci., 294, 147 (2007).
F. H. Akhtar, M. Kumar and K.-V. Peinemann, J. Membr. Sci., 525, 187 (2017).
D. Zhao, J. Ren, Y. Wang, Y. Qiu, H. Li, K. Hua, X. Li, J. Ji and M. Deng, J. Membr. Sci., 521, 104 (2017).
A. Jomekian, B. Bazooyar, R. M. Behbahani, T. Mohammadi and A. Kargari, J. Membr. Sci., 524, 652 (2017).
E. Molyanyan, S. Aghamiri, M. R. Talaie and N. Iraji, Int. J. Environ. Sci. Technol., 13, 2001 (2016).
Y.-C. Tsai and J.-D. Huang, Electrochem. Commun., 8, 956 (2006).
Z. Es’haghi, M. A. Golsefidi, A. Saify, A. A. Tanha, Z. Rezaeifar and Z. Alian-Nezhadi, J. Chromatogr. A, 1217, 2768 (2010).
J. Shen, W. Huang, L. Wu, Y. Hu and M. Ye, Mater. Sci. Eng. A, 464, 151 (2007).
N. Azizi, T. Mohammadi and R. Mosayebi Behbahani, Chem. Eng. Res. Des., 117, 177 (2017).
M. Isanejad, N. Azizi and T. Mohammadi, J. Appl. Polym. Sci., 134 (2017).
H. R. Mahdavi, N. Azizi and T. Mohammadi, J. Polym. Res., 24, (2017).
S. A. Stern, J. Polym. Sci. A. Polym. Phys., 6, 1933 (1968).
J. H. Kim and Y. M. Lee, J. Membr. Sci., 193, 209 (2001).
A. F. Ismail, K. C. Khulbe and T. Matsuura, Gas Separation Membranes: Polymeric and Inorganic, Springer International Publishing, Cham (2015).
S. Sridhar, R. Suryamurali, B. Smitha and T. M. Aminabhavi, Colloid. Surf., A. Phys. Eng. Aspects, 297, 267 (2007).
S. Sridhar, B. Smitha, R. Suryamurali and T. M. Aminabhavi, Des. Mono. Polym., 11, 17 (2008).
R. Surya Murali, A. F. Ismail, M. A. Rahman and S. Sridhar, Sep. Purif. Technol., 129, 1 (2014).
R. S. Murali, S. Sridhar, T. Sankarshana and Y. Ravikumar, Ind. Eng. Chem. Res., 49, 6530 (2010).
P. Zaheri, T. Mohammadi, H. Abolghasemi and M. G. Maraghe, Chem. Eng. Res. Des., 100, 81 (2015).
A. Ghadimi, M. Amirilargani, T. Mohammadi, N. Kasiri and B. Sadatnia, J. Membr. Sci., 458, 14 (2014).
H. Rabiee, A. Ghadimi, S. Abbasi and T. mohammadi, Chem. Eng. Res. Des., 98, 96 (2015).
A. Ehsani and M. Pakizeh, J. Taiwan. Instit. Chem. Eng., 66, 414 (2016).
M. C. Choi, J. Y. Jung, H. S. Yeom and Y. W. Chang, Polym. Eng. Sci., 53, 982 (2013).
V. Nafisi and M.-B. Hägg, J. Membr. Sci., 459, 244 (2014).
B. Yu, H. Cong, Z. Li, J. Tang and X. S. Zhao, J. Appl. Polym. Sci., 130, 2867 (2013).
D. Zhao, J. Ren, H. Li, X. Li and M. Deng, J. Membr. Sci., 467, 41 (2014).
M. Rezakazemi, A. Vatani and T. Mohammadi, RSC Adv., 5, 82460 (2015).
H. Rabiee, S. Meshkat Alsadat, M. Soltanieh, S. A. Mousavi and A. Ghadimi, J. Indust. Eng. Chem., 27, 223 (2015).
H. Cong, J. Zhang, M. Radosz and Y. Shen, J. Membr. Sci., 294, 178 (2007).
S. Wang, Y. Liu, S. Huang, H. Wu, Y. Li, Z. Tian and Z. Jiang, J. Membr. Sci., 460, 62 (2014).
L. Ge, Z. Zhu, F. Li, S. Liu, L. Wang, X. Tang and V. Rudolph, J. Phys. Chem. C., 115, 6661 (2011).
S. Habibzare, M. Asghari and A. Djirsarai, Int. J. Nano. Dimension, 5, 247 (2014).
H. Rabiee, A. Ghadimi and T. Mohammadi, J. Membr. Sci., 476, 286 (2015).
D. W. Van Krevelen and K. Te Nijenhuis, Properties of Polymers, Elsevier, Amsterdam (2009).
A. Jomekian, R. M. Behbahani, T. Mohammadi and A. Kargari, J. Nat. Gas. Sci. Eng., 31, 562 (2016).
S. Feng, J. Ren, K. Hua, H. Li, X. Ren and M. Deng, Sep. Purif. Technol., 116, 25 (2013).
A. Mahmoudi, M. Asghari and V. Zargar, J. Indust. Eng. Chem., 23, 238 (2015).
A. Fonseca, S. Reijerkerk, J. Potreck, K. Nijmeijer, Z. Mekhalif and J. Delhalle, Desalination, 250, 1150 (2010).
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Azizi, N., Arzani, M., Mahdavi, H.R. et al. Synthesis and characterization of poly(ether-block-amide) copolymers/multi-walled carbon nanotube nanocomposite membranes for CO2/CH4 separation. Korean J. Chem. Eng. 34, 2459–2470 (2017). https://doi.org/10.1007/s11814-017-0152-8
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DOI: https://doi.org/10.1007/s11814-017-0152-8