Abstract
Modified ultra-porous ZIF-8 particles were used to prepare novel ZIF-8/Pebax 1657 mixed matrix membranes (MMMs) on PES support for separation of CO2 from CH4 using spin coating method. TEM and SEM were used to characterize modified ZIF-8 particles. SEM was also used to investigate the morphology of synthesized MMMs. The MMMs with thinner selective layer showed higher CO2 permeability and lower CO2/CH4 selectivity in permeation tests compared to MMMs with thicker selective layer. The plasticization was recognized as the main reason for rise in CO2 permeability and drop in CO2/CH4 selectivity of thinner MMMs. The gas sorption results showed that the high permeability of CO2 in MMMs is mainly due to the high solubility of this gas in MMMs, leading to high CO2/CH4 solubility selectivity for MMMs. The fractional free volume and void volume fraction of MMMs increased as the thickness of membrane decreased. Applying higher mixed feed pressures and permeation tests temperatures resulted in increase in CO2 permeability and decrease in CO2/CH4 selectivity. At highest testing temperature (60 °C), the CO2 permeability of synthesized MMMs with thinner selective layer remarkably increased.
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A. Jomekian, R. M. Behbahani, T. Mohammadi and A. Kargari, J. Nat. Gas. Sci. Eng., 31, 562 (2016).
E. Ebrahimzadeh, J. Matagi, F. Fazlollahi and L. L. Baxter, Appl. Therm. Eng., 96, 39 (2016).
F. Fazlollahi, A. Bown, E. Ebrahimzadeh and L. L. Baxter, Energy, 90, Part 1, 244 (2015).
F. Fazlollahi, A. Bown, E. Ebrahimzadeh and L. L. Baxter, Energy, 103, 369 (2016).
E. Ebrahimzadeh and L. L. Baxter, Appl. Therm. Eng., 102, 785 (2016).
M. Binns, S.-Y. Oh, D.-H. Kwak and J.-K. Kim, Korean J. Chem. Eng., 32, 383 (2015).
C. Chen, J. Kim and W.-S. Ahn, Korean J. Chem. Eng., 31, 1919 (2014).
H. Lin, E. VanWagner, R. Raharjo, B. D. Freeman and I. Roman, Adv. Mater., 18, 39 (2006).
M. Rezakazemi, A. Ebadi Amooghin, M. M. Montazer-Rahmati, A. F. Ismail and T. Matsuura, Prog. Polym. Sci., 39, 817 (2014).
L. M. Robeson, J. Membr. Sci., 320, 390 (2008).
V. M. Aceituno Melgar, J. Kim and M. R. Othman, J. Ind. Eng. Chem., 28, 1 (2015).
D. Bastani, N. Esmaeili and M. Asadollahi, J. Ind. Eng. Chem., 19, 375 (2013).
S. R. Venna and M. A. Carreon, Chem. Eng. Sci., 124, 3 (2015).
M. H. Nematollahi, A. H. S. Dehaghani and R. Abedini, Korean J. Chem. Eng., 33, 657 (2016).
J. Lillepärg, P. Georgopanos and S. Shishatskiy, J. Membr. Sci., 467, 269 (2014).
H. Yang, Z. Xu, M. Fan, R. Gupta, R. B. Slimane, A. E. Bland and I. Wright, J. Environ. Sci., 20, 14 (2008).
M. Buonomenna, W. Yave and G. Golemme, RSC Adv., 2, 10745 (2012).
R. Hilke, N. Pradeep, A. R. Behzad, S. P. Nunes and K.-V. Peinemann, J. Membr. Sci., 472, 39 (2014).
E. Ahmadpour, A. A. Shamsabadi, R. M. Behbahani, M. Aghajani and A. Kargari, J. Nat. Gas Sci. Eng., 21, 518 (2014).
M. A. Ardestani, A. Babaluo, M. Peyravi, M. R. Aghjeh and E. Jannatdoost, Desalination, 250, 1140 (2010).
J. C. Chen, X. Feng and A. Penlidis, Sep. Sci. Technol., 39, 149 (2005).
Y. Chen, B. Wang, L. Zhao, P. Dutta and W. S. Winston Ho, J. Membr. Sci., 495, 415 (2015).
E. Esposito, G. Clarizia, P. Bernardo, J. C. Jansen, Z. Sedláková, P. Izák, S. Curcio, B. d. Cindio and F. Tasselli, Chem. Eng. Process. Process Intensif., 94, 53 (2015).
S. Feng, J. Ren, H. Li, K. Hua, X. Li and M. Deng, J. Energ. Chem., 22, 837 (2013).
S. Feng, J. Ren, Z. Li, H. Li, K. Hua, X. Li and M. Deng, Int. J. Greenhouse Gas Control, 19, 41 (2013).
A. Ghadimi, T. Mohammadi and N. Kasiri, Int. J. Hydrogen Energy, 40, 9723 (2015).
T. Li, Y. Pan, K.-V. Peinemann and Z. Lai, J. Membr. Sci., 425-426, 235 (2013).
R. S. Murali, K. P. Kumar, A. Ismail and S. Sridhar, Micropor. Mesopor. Mater., 197, 291 (2014).
R. S. Murali, S. Sridhar, T. Sankarshana and Y. Ravikumar, Ind. Eng. Chem. Res., 49, 6530 (2010).
V. Nafisi and M.-B. Hägg, J. Membr. Sci., 459, 244 (2014).
J. Potreck, K. Nijmeijer, T. Kosinski and M. Wessling, J. Membr. Sci., 338, 11 (2009).
H. Rabiee, S. Meshkat Alsadat, M. Soltanieh, S. A. Mousavi and A. Ghadimi, J. Ind. Eng. Chem., 27, 223 (2015).
H. Rabiee, M. Soltanieh, S. A. Mousavi and A. Ghadimi, J. Membr. Sci., 469, 43 (2014).
M. M. Rahman, V. Filiz, S. Shishatskiy, C. Abetz, S. Neumann, S. Bolmer, M. M. Khan and V. Abetz, J. Membr. Sci., 437, 286 (2013).
M. M. Rahman, S. Shishatskiy, C. Abetz, P. Georgopanos, S. Neumann, M. M. Khan, V. Filiz and V. Abetz, J. Membr. Sci., 469, 344 (2014).
J. H. Kim and Y. M. Lee, J. Membr. Sci., 193, 209 (2001).
R. Surya Murali, A. F. Ismail, M. A. Rahman and S. Sridhar, Sep. Purif. Technol., 129, 1 (2014).
J. Cravillon, S. Münzer, S.-J. Lohmeier, A. Feldhoff, K. Huber and M. Wiebcke, Chem. Mater., 21, 1410 (2009).
M. Fang, C. Wu, Z. Yang, T. Wang, Y. Xia and J. Li, J. Membr. Sci., 474, 103 (2015).
S. Hwang, W. S. Chi, S. J. Lee, S. H. Im, J. H. Kim and J. Kim, J. Membr. Sci., 480, 11 (2015).
Y.-R. Lee, M.-S. Jang, H.-Y. Cho, H.-J. Kwon, S. Kim and W.-S. Ahn, Chem. Eng. J., 271, 276 (2015).
N. A. H. M. Nordin, A. Ismail, A. Mustafa, R. S. Murali and T. Matsuura, RSC Adv., 4, 52530 (2014).
R. L. Papporello, E. E. Miró and J. M. Zamaro, Micropor. Mesopor. Mater., 211, 64 (2015).
Y. Wang, Y. Xu, H. Ma, R. Xu, H. Liu, D. Li and Z. Tian, Micropor. Mesopor. Mater., 195, 50 (2014).
A. Jomekian, R. M. Behbahani, T. Mohammadi and A. Kargari, Micropor. Mesopor. Mater., 234, 43 (2016).
Y.-R. Lee, J. Kim and W.-S. Ahn, Korean J. Chem. Eng., 30, 1667 (2013).
J. Cravillon, C. A. Schröder, R. Nayuk, J. Gummel, K. Huber and M. Wiebcke, Angew. Chem. Int. Ed. Engl., 123, 8217 (2011).
S. Cao, G. Gody, W. Zhao, S. Perrier, X. Peng, C. Ducati, D. Zhao and A. K. Cheetham, Chem. Sci., 4, 3573 (2013).
E. L. Bustamante, J. L. Fernández and J. M. Zamaro, J. Colloid Interface Sci., 424, 37 (2014).
J. Cravillon, R. Nayuk, S. Springer, A. Feldhoff, K. Huber and M. Wiebcke, Chem. Mater., 23, 2130 (2011).
A. F. Gross, E. Sherman and J. J. Vajo, Dalton Trans., 41, 5458 (2012).
C.-W. Tsai and E. H. Langner, Micropor. Mesopor. Mater., 221, 8 (2016).
D. Yamamoto, T. Maki, S. Watanabe, H. Tanaka, M. T. Miyahara and K. Mae, Chem. Eng. J., 227, 145 (2013).
P. Zhang, F. Sun, Z. Xiang, Z. Shen, J. Yun and D. Cao, Energy Environ. Sci., 7, 442 (2014).
Y.-Y. Fu, C.-X. Yang and X.-P. Yan, Chem. Commun., 49, 7162 (2013).
L. G. Qiu, T. Xu, Z. Q. Li, W. Wang, Y. Wu, X. Jiang, X. Y. Tian and L. D. Zhang, Angew. Chem. Int. Ed. Eng., 47, 9487 (2008).
L.-B. Sun, J.-R. Li, J. Park and H.-C. Zhou, J. Am. Chem. Soc., 134, 126 (2011).
A. Jomekian, R. M. Behbahani, T. Mohammadi and A. Kargari, J. Solid State Chem., 235, 212 (2016).
J. H. Kim, S. Y. Ha and Y. M. Lee, J. Membr. Sci., 190, 179 (2001).
D. Zhao, J. Ren, H. Li, K. Hua and M. Deng, J. Energ. Chem., 23, 227 (2014).
K. Norrman, A. Ghanbari-Siahkali and N. B. Larsen, Annual Reports Section “C” (Physical Chemistry), 101, 174 (2005).
P. Burmann, B. Zornoza, C. Téllez and J. Coronas, Chem. Eng. Sci., 107, 66 (2014).
Y. Shen and A. C. Lua, Chem. Eng. J., 188, 199 (2012).
A. Bondi, J. Phys. Chem., 68, 441 (1964).
D. Hua, Y. K. Ong, Y. Wang, T. Yang and T.-S. Chung, J. Membr. Sci., 453, 155 (2014).
M. A. Aroon, A. F. Ismail, T. Matsuura and M. M. Montazer-Rahmati, Sep. Purif. Technol., 75, 229 (2010).
A. F. Ismail and W. Lorna, Sep. Purif. Technol., 27, 173 (2002).
C. P. Ribeiro, B. D. Freeman and D. R. Paul, J. Membr. Sci, 377, 110 (2011).
Y. Li and T.-S. Chung, Int. J. Hydrogen Energy, 35, 10560 (2010).
F. Dorosti, M. Omidkhah and R. Abedini, Chem. Eng. Res. Des., 92, 2439 (2014).
F. Dorosti, M. Omidkhah and R. Abedini, J. Nat. Gas Sci. Eng., 25, 88 (2015).
R. Mahajan and W. J. Koros, Polym. Eng. Sci., 42, 1420 (2002).
R. Mahajan and W. J. Koros, Polym. Eng. Sci., 42, 1432 (2002).
T. T. Moore, R. Mahajan, D. Q. Vu and W. J. Koros, AIChE J., 50, 311 (2004).
D. Q. Vu, W. J. Koros and S. J. Miller, J. Membr. Sci., 211, 311 (2003).
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Jomekian, A., Behbahani, R.M., Mohammadi, T. et al. High speed spin coating in fabrication of Pebax 1657 based mixed matrix membrane filled with ultra-porous ZIF-8 particles for CO2/CH4 separation. Korean J. Chem. Eng. 34, 440–453 (2017). https://doi.org/10.1007/s11814-016-0269-1
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DOI: https://doi.org/10.1007/s11814-016-0269-1