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A novel post-synthetic modification of magnetic MIL-101(Cr) metal–organic framework with 1,8-diaminonaphthalene chelator and its utilization for separation/determination of cadmium and nickel in food samples

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Abstract

This research describes a novel post-synthetic modification of magnetic metal–organic framework with 1,8-diaminonaphthalene chelator and its utilization in the separation/extraction of cadmium and nickel ions from food samples. This is the first report on the post-synthetic modification of a metal–organic framework with 1,8-diaminonaphthalene chelator and its use in the separation/extraction of Cd(II) and Ni(II) in food matrixes. The fabricated material was characterized by scanning electron microscopy, X-ray diffraction, vibrating sample magnetometry, and Fourier transform infrared techniques. Afterward, a Box–Behnken design method was used to explore the factors affecting preconcentration performance. The best uptake% was obtained by adjusting the pH of the solution at 6.5, performing the extraction for 9.0 min, and using a 30 mg adsorbent dose. In the elution step, the best efficiency was attained by using 1.25 mL of 1.0 mol/L nitric acid as an eluent and by conducting the extraction for 11.0 min. The limits of detection were 0.07, and 0.2 µg L−1 for Cd(II), and Ni(II) ions, respectively. The linear dynamic ranges for Cd(II), and Ni(II) are 0.2–120 and 0.7–150 µg L−1, respectively. The repeatability of the new method at three concentration level of 1.0, 10.0, and 100 μg L−1 (n = 3) was 10.8%, 8.5% and 6.0%, respectively. The maximum adsorption capacities were 213 mg/g for Cd(II), and 195 mg/g for Ni(II). Ultimately, the new material was used in the separation/determination of trace amounts of Cd(II) and Ni(II) ions in food samples, and the favorable results were attained (Relative recovery, 86–112%; RSD%, < 9.3%).

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Authors and Affiliations

  1. Department of Medicinal Chemistry, Pharmaceutical Science Branch, Islamic Azad University, P.O. Box 193951495, Tehran, Iran

    Mahnaz Barzin

  2. Department of Chemistry, Karaj Branch, Islamic Azad University, P.O. Box 31485-313, Karaj, Iran

    Mohsen Pooladi

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  1. Mahnaz Barzin
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  2. Mohsen Pooladi
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Correspondence to Mahnaz Barzin.

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Barzin, M., Pooladi, M. A novel post-synthetic modification of magnetic MIL-101(Cr) metal–organic framework with 1,8-diaminonaphthalene chelator and its utilization for separation/determination of cadmium and nickel in food samples. Chem. Pap. 76, 5561–5570 (2022). https://doi.org/10.1007/s11696-022-02265-2

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