Abstract
Based on thermodynamic calculations, four alloys in the system Mg-Ca-Zn produced by gravity die casting were solution treated and aged at 175 °C for different times. The scanning electron microscopy and X-ray diffraction analyses of the solutionized alloys were in good agreement with the thermodynamic calculations. In these Mg-Ca-Zn alloys, the hardness increases with aging time up to 8 hours followed by typical overaging, during which the hardness decreases. According to the calculations and scanning transmission electron microscopy analyses, the change in the hardness can be correlated to the precipitation of Ca2Mg6Zn3.
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T. Horie, H. Iwahori, Y. Seno, and Y. Awano: Magnesium Technology 2000, Proc. Symp., TMS, Warrendale, PA, 2000, pp. 261–69.
S.M. Zhu, X. Gao, and J.F. Nie: Magnesium Technology 2004, Proc. Symp., TMS, Warrendale, PA, 2004, pp. 325–30.
M. Vogel: Ph.D. Thesis, University of Stuttgart, Stuttgart, Germany, 2002.
C.O. Brubaker and Z.K. Liu: J. Alloys Compounds, 2004, vol. 370, pp. 114–22.
T.V. Larionova, W.W. Park, and B.S. You: Scripta Mater., 2001, vol. 45, pp. 7–12.
J.F. Nie and B.C. Muddle: Scripta Mater., 1997, vol. 37, pp. 1475–81.
P.M. Jardim, G. Solorzano, and J.B. Vander Sande: Microsc. Microanalysis, 2002, vol. 8, pp. 487–96.
J. Gröbner, I. Chumak, and R. Schmid-Fetzer: Intermetallics, 2003, vol. 11, pp. 1065–74.
K. Ozturk, Z.-K. Liu, and A. Luo: Mg Technology 2003 Symp., TMS, Warrendale, PA, 2003, pp. 195–200.
H. Liang, S.L. Chen, and Y.A. Chang: Metall. Trans. A, 1997, vol. 28A, pp. 1725–34.
J. Gröbner, D. Kevorkov, I. Chumak, and R. Schmid-Fetzer: Z. Metallkd., 2003, vol. 94, pp. 976–82.
N. Saunders and A.P. Miodownik: in CALPHAD (Calculation of Phase Diagrams): A Comprehensive Guide, R.W. Cahn, ed., Pergamon Materials Series, United Kingdom, 1998, vol. I.
P.M. Jardim, G. Solorzano, and J.B. Vander Sande: Mater. Sci. Eng. A, 2004, vol. A381 (1–2), pp. 196–205.
R.E. Reed-Hill and R. Abbaschian: Physical Metallurgy Principles, PWS-KENT Publishing Co., Boston, MA, 1992, pp. 677–78.
D.B. Williams and J.I. Goldstein: in Electron Probe Quantitation, K.F.J. Heinrich and D.E. Newbury, eds., Plenum Press, New York, NY, 1991, pp. 371–98.
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Bamberger, M., Levi, G. & Vander Sande, J.B. Precipitation hardening in Mg-Ca-Zn alloys. Metall Mater Trans A 37, 481–487 (2006). https://doi.org/10.1007/s11661-006-0019-9
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DOI: https://doi.org/10.1007/s11661-006-0019-9