Abstract
A thermodynamic description of the Al-Mg-Zn system was developed based on critically evaluated experimental data. All binary intermetallic phases are assumed to have negligible ternary solubility except for MgZn2. Three different thermodynamic models are applied to three different types of phases in this system, i.e., disordered solution phases, stoichiometric compounds, and semistoichiometric phases. The model parameters are optimized based on the thermodynamic descriptions of the constituent binaries and experimental phase equilibrium and thermodynamic data available in the literature. The good agreement obtained between several calculated isopleths and thermodynamic values of the liquid phase and experimental data shows that the current description of this system is reasonable. The calculated phase equilibria in the Al-rich corner are believed to be reliable for practical applications, while those away from the Al-rich region are subjected to large uncertainty. Additional experimental investigations are needed to firmly establish the phase equilibrium of this system over wide ranges of composition and temperature.
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S.-L. Chen, Y. Zuo, H. Liang, and Y.A. Chang: Metall. Mater. Trans. A., 1997, vol. 28A, pp. 435–46.
Y. Zuo and Y.A. Chang: CALPHAD, 1993, vol. 17, pp. 161–74.
S.-L. Chen and Y.A. Chang: CALPHAD, 1993, vol. 17 (2), pp. 113–24.
R. Agarwal, S.G. Fries, H.L. Lukas, G. Petzow, F. Sommer, T.G. Chart, and G. Effenbrerg: Z. Metallkd., 1992, vol. 83, pp. 216–23.
G. Eger: Int. Z. Metallogr., 1913, vol. 4, pp. 50–128.
W. Sandner and K.L. Meissner: Z. Metallkd., 1923, vol. 15, pp. 160–83.
W. Sandner: Z. Anorg. Allg. Chem., 1926, 154, 144–51.
A.A. Bochvar and M.D. Kuznetzov: Metallurgy, 1933, 8, 7–14.
V. Fuss: Metallography of Aluminum and Its Alloys, Verlag Julius Springer, Berlin, 1934, pp. 154–55.
F. Laves, K. Lohberg, and H. Witte: Metall-Wirtschaft, 1935, 14, 793–94.
W.L. Fink and L.A. Willey: Met. Technol., 1936, 8, 3–32.
M. Hamasumi: Sci. Rep. Tohoku Imp. Univ. Honda Anniv., 1936, 748–76.
M. Hamasumi: Tetsu to Hagané (J. Iron Steel Inst. Jpn.), 1936, 22, 258–71.
W. Koster and W. Wolf: Z. Metallkd., 1936, 28, 155–58.
W. Koster and W. Dullenkopf: Z. Metallkd., 1936, 28, 309–12.
W. Koster and W. Dullenkopf: Z. Metallkd., 1936, 28, 363–67.
K. Riederer: Z. Metallkd., 1936, 28, 312–17.
W.L. Fink and L.A. Willey: Trans. TMS-AIME, 1937, 124, 78–110.
P.Y. Saldau and M.J. Zamotorin: Izv. Sekt. Fiz. Khim. Anal., 1938, 11, 27–36.
G.G. Urasov, N.A. Filin, and A.B. Shashin: Metallurgy, 1940, 15, 3–11
E. Butchers, G.V. Raynor, and W. Hume-Rothery: J. Inst. Met., 1943, 69, 209–28.
A.T. Little, G.V. Raynor, and W. Hume-Rothery: J. Inst. Met., 1943, 69, 423–40.
A.T. Little, G.V. Raynor, and W. Hume-Rothery: J. Inst. Met., 1943, 69, 467–84.
G. Siebel: Z. Elektrochem., 1943, 49, 218–21.
V.I. Mikheeva and O.S. Kryukova: Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1944, 4, 296–308.
E. Butchers and W. Hume-Rothery: J. Inst. Met., 1945, 71, 291–311.
V.I. Mikheeva and O.S. Kryukova: Dokl. Akad. Nauk SSSR, 1945 vol. 50, pp. 243–46.
V.I. Mikheeva and O.S. Kryukova: Dokl. Akad. Nauk SSSR, 1945, 50, 247–48.
V.I. Mikheeva: Magnesium Alloys with Aluminum and Zinc, Publishing House of the Academy of Sciences of USSR, Moscow, 1946.
D.J. Strawbridge, W. Hume-Rothery, and A.T. Little: J. Inst. Met., 1947, 74, 191–225.
W. Koster: Z. Metallkd., 1948, 40, 211–13.
P.Y. Saldau: Izv. Sekt. Fiz. Khim. Anal., 1949, 19, 487–96.
G. Bergman, L.T. Waugh, and L. Pauling: Nature, 1952, 169, 1057–58.
H. Haneman and A. Schrader: Atlar Metallographicus, Verlag Stahleisen M.B.H., Dusseldorf, 1952, vol. 3 (2), pp. 133–49.
M.I. Zamotorin: trudy Leningrad Politekhn. Inst., 1955, 180, 38–43.
G. Bergman, L.T. Waugh, and L. Pauling: Acta Crystallogr., 1957, 10, 254–59.
J.B. Clark and F.N. Rhines: Trans. Am. Soc. Met., 1959, 51, 199–221.
H. Watanabe: Nippon Kinzoku Gakkai-Si, 1959, 23, 285–88.
Z. Kozuka, J. Moriyama, and J. Kushima: J. Electrochem. Soc. Jpn., 1960, 28, 298–301.
J.B. Clark: Trans. Am. Soc. Met., 1961, 53, 295–306.
P.Y. Saldau: Ph.D. Thesis, Publishing House, Moscow, 1961, pp. 5–8.
E.H. Wright: Aluminum Research Laboratories, Aluminum Company of America, private communication referred by J.B. Clark, 1961.
A.S. Yue and J.B. Clark: Trans. TMS-AIME, 1961, vol. 22, pp. 383–89.
I.A. Aleksakhin and A.A. Semionow: Metalloved. Term. Obrab. Met., 1962, 4, 40–45.
J.H. Ault and B.E. Williams: Acta Crystallogr., 1966, 21, 830–31.
P.A. Thackery: J. Inst. Met., 1968, 96, 228–35.
A.S. Yue: Metall. Trans., 1970, 1, 19–22.
E.E. Lukashenco and A.M. Pogodayev: Zh. Fiz. Khimii, 1971, vol. 45 (8), pp. 1182–84.
L.F. Mondolfo: Met. Rev., 1971, 16, 95–124.
L.D. Willey: Metals Handbook, 8th ed, ASM, Metals Park, OH, 1973, pp. 397–99.
A.M. Pogodayev and E.E. Lukashenco: Izv. Acad. Nauk SSSR Metall., 1974, vol. 6, pp. 90–93.
J.H. Auld and S. McK Cousland: Met. Sci., 1976, 73, 445–48.
L.F. Mondolfo: Aluminum Alloys: Structure and Properties, Butterworth and Co., London, 1976, pp. 575–90.
M.E. Drits: Phase Diagram of Aluminum and Magnesium Alloy Systems, Baikov Institute of Metallurgy, Moscow, 1946.
W. Stiller and H. Hoffmeister: Z. Metallkd., 1979, vol. 70, pp. 817–24.
G.M. Kuznetsov, A.D. Barsukov, G.B. Krivosheeva, and V.V. Istomin-Kastorovski: Izv. Vyss. Uchebn. Zaved. Tsvetn. Metall., 1985, 1, 88–93.
G.M. Kuznetsov, A.D. Barsukov, G.B. Krivosheeva, and E.V. Bashashkina: Izv. Vyss. Uchebn. Zaved. Tsvetn. Metall., 1985, 2, 91–95.
N.U. Despande, K.K. Ray, and A.K. Mallik: J. Alloy Phase Diagram, 1986, vol. 2 (2), pp. 108–30.
G.M. Kuznetsov, A.D. Barsukov, G.B. Krivosheeva, and E.G. Dieva: Izv. Akad. Nauk SSSR Metall., 1986, 4, 198–200.
D.A. Petrov: in Ternary Alloys, G. Petzow and G. Effenberg, eds. ASM INTERNATIONAL, Materials Park, OH, 1993, vol. 7, pp. 57–71.
F.S. Rhines: Phase Diagrams in Metallurgy, McGraw-Hill, New York, NY, 1956.
Y.A. Chang, J.P. Neumann, A. Mikula, and D. Goldberg: INCRA Monograph VI, Phase Diagrams and Thermodynamic Properties of Ternary Copper-Metal Systems, The International Copper Research Association, Inc., New York, NY, 1979.
Y.M. Muggianu, M. Gambino, and J.P. Bros: J. Chim. Phys., 1975, 72, 83–87.
O. Redlich and A.T. Kister: Ind. Eng. Chem., 1948, 40, 345–48.
S.-L. Chen: Ph.D. Thesis, University of Wisconsin-Madison, Madison, WI, 1994.
S.-L. Chen, Y. Zuo, C.R. Kao, and Y.A. Chang: CALPHAD, 1993, 17, 47–56.
S.-L. Chen, K.-C. Chou, and Y.A. Chang: CALPHAD, 1993, 17, 237–50.
S.-L. Chen, K.-C. Chou, and Y.A. Chang: CALPHAD, 1993, 17, 287–302.
H.L. Lukas, J. Weiss, and E.-Th. Henig: CALPHAD, 1982, vol. 6 (3), pp. 229–51.
U.R. Kattner and B.J. Boettinger: Mater. Sci. Eng., 1992, A152, 9–17.
N. Saunders: CALPHAD, 1990, 14, 61–70.
S. an Mey and G. Effenberg: Z. Metallkd., 1986, vol. 77 (7), pp. 449–53.
S. an Mey: Z. Metallkd., 1993, vol. 84 (7), pp. 451–55.
B. Sundman, B. Jansson, and J.-O. Andersson: CALPHAD, 1985, vol. 9, pp. 153–90.
A.T. Dinsdale: CALPHAD, 1991, 15, 317–425.
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Liang, H., Chen, S.L. & Chang, Y.A. A thermodynamic description of the Al-Mg-Zn system. Metall Mater Trans A 28, 1725–1734 (1997). https://doi.org/10.1007/s11661-997-0104-8
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DOI: https://doi.org/10.1007/s11661-997-0104-8