Abstract
A nonionic waterborne polyurethane(WPU) was synthesized by the self-emulsification method using polyether diol (N220), isophorone diisocyanate (IPDI), trimethylolpropane poly (ethylene glycol monomethyl ether) (N120), 1,4-butanediol (BDO) and trimethylolpropane (TMP) as the main materials. The effects of the NCO/OH ratio on the emulsion and film properties of NWPU were explored. The experimental results show that the NWPU prepared at an NCO/OH ratio of 1.1 has good emulsion stability and easy film formation, and the resultant film was elastic, soft, and transparent. The sample was used for wool finishing and the application performance was evaluated. When the NWPU dosage reached 40 g·L−1, the fabric area felt shrinkage rate reduced from 8.97% to 4.75%, the pilling rating raised from grade 2–3 to grade 4, and the whiteness value only decreased by 3.87%.
Similar content being viewed by others
References
Du Z, Hu CY, Xie Z, et al. A Bio-antifelting Agent Based on Waterborne Polyurethane and Keratin Polypeptides Extracted by Protease from Waste Wool[J]. Fibers Polym., 2017, 18: 641–648
Zhu L, Ding X, Wu X. A Novel Method for Improving the Anti-pilling Property of Knitted Wool Fabric with Engineered Water Nanostructures[J]. J. Mater. Res. Technol., 2020, 9: 3 649–3 658
Shi JH, Han X, Yan KL. A Novel Bio-functional Finishing Agent for Wool Based on Waterborne Polyurethane Mixed with Chitosan[J]. Text. Res. J., 2014, 84: 1174–1182
Li L, Zhou W. Analysis on the Pilling Factors of Cashmere Knitted Fabric[J]. Fibers Polym., 2006, 7: 213–216
Cui L, Chen T, Ding C, et al. Spatial Distribution of Total Halogenated Organic Compounds (TX), Adsorbable Organic Halogens (AOX), and Heavy Metals in Wetland Soil Irrigated with Pulp and Paper Wastewa-ter[J]. Chemical Speciation & Bioavailability, 2016, 29: 15–24
Zhang R, Wang A. Modification of Wool by Air Plasma and Enzymes as a Cleaner and Environmentally Friendly Process[J]. J. Cleaner Prod., 2015, 87: 961–965
Hassan MM, Carr CM. A Review of the Sustainable Methods in Imparting Shrink Resistance to Wool Fabrics[J]. J. Adv. Res., 2019, 18: 39–60
Iglesias MS, Sequeiros C, García S, et al. Eco-friendly Anti-felting Treatment of Wool Top Based on Biosurfactant and Enzymes[J]. J. Cleaner Prod., 2019, 220: 846–852
Kaur A, Chakraborty JN. Controlled Eco-friendly Shrink-resist Finishing of Wool Using Bromelain[J]. J. Cleaner Prod., 2015, 108: 503–513
Araujo R, Silva C, Machado R, et al. Proteolytic Enzyme Engineering: A Tool for Wool[J]. Biomacromolecules, 2009, 10: 1655–61
Muzaffar S, Bhatti IA, Zuber M, et al. Synthesis, Characterization and Efficiency Evaluation of Chitosan-polyurethane Cased Textile Finishes[J]. Int. J. Biol. Macromol., 2016, 93: 145–155
Yang ZH, Zang H, Wu GF. Study of Solvent-free Sulfonated Waterborne Polyurethane as an Advanced Leather Finishing Material[J]. J. Polym. Res., 2019, 26: 213–225
Gao C, Han S, Zhang D, et al. A Facile Preparation of UV-cured Films from Waterborne Unsaturated Polyester via Click Reaction[J]. Prog. Org. Coat., 2018, 124: 232–239.
Hu L, Pu Z, Zhong Y, et al. Effect of Different Carboxylic Acid Group Contents on Microstructure and Properties of Waterborne Polyurethane Dispersions[J]. J. Polym. Res., 2020, 27: 129–137
Wu G, Li Y, Yang Z, et al. Preparation and Characterization of Glucose and Sulfamate Double-Modified Biodegradable Waterborne Polyure-thane[J]. Chemistry Select, 2021, 6: 8 140–8 149
He X, Zhang X, He J, et al. Preparation and Properties of Hydrox-yl-terminated Cationic Waterborne Polyurethanes for Cathodic Electro-deposition Coatings[J]. Adv. Polym. Technol., 2018, 37: 3 831–3 841
Liang H, Liu L, Lu J, et al. Castor Oil-based Cationic Waterborne Polyurethane Dispersions: Storage Stability, Thermo-physical Properties and Antibacterial Properties[J]. Ind. Crops Prod., 2018, 117: 169–178
He X, He J, Sun Y, et al. Preparation and Characterization of Cationic Waterborne Polyurethanes Containing a Star-branched Polydimethylsi-loxane[J]. J. Coat. Technol. Res., 2022, 19: 1 055–1 066
Li B, Peng D, Zhao N, et al. The Physical Properties of Nonionic Waterborne Polyurethane with a Polyether as Side Chain[J]. J. Appl. Polym. Sci., 2013, 127: 1 848–1 852
Mishra VK, Patel KI. Nonionic Diol Modified UV-Curable Polyurethane Dispersions: Preparation and Characterization[J]. J. Dispersion Sci. Technol., 2014, 36: 351–362
Xu C, Ouyang L, Liu H, et al. Synthesis of Blocking Polyether Silicone Oil and Silicone Blocking Waterborne Polyurethane and Application to Cashmere Knitted Fabric Finishing[J]. Text. Res. J., 2015, 85: 2 040–2 050
Chen SY, Zhuang RQ, Chuang FS, et al. Synthetic Scheme to Increase the Abrasion Resistance of Waterborne Polyurethane-urea by Controlling Micro-phase Separation[J]. J. Appl. Polym. Sci., 2021, 138: 50 561
Zhang M, Lian X, Cui J, et al. Synthesis of Waterborne Polyurethane Ink Binder with High T-peel Strength and Its Application in Biaxially Oriented Polypropylene Film Printing[J]. J. Appl. Polym. Sci., 2020, 138: 50 273
Celia C, Trapasso E, Cosco D, et al. Turbiscan Lab (R) Expert Analysis of the Stability of Ethosomes (R) and Ultradeformable Liposomes Containing a Bilayer Fluidizing Agent[J]. Colloids and Surfaces B-Biointerfaces, 2009, 72: 155–160
Pamir O, Ocal N, Aydogan F. Synthesis, Characterization and Dispersion Stabilities of Novel Ionic and Nonionic Diol Modified Waterborne Polyurethane Dispersions with Different Polyols[J]. J. Dispersion Sci. Technol., 2021: 9
Kim T, Kim JC, Seo B. Real-Time Monitoring of the Dispersion Stability of Poly(Carbonate Urethane)s Using the Turbiscan Technique[J]. J. Eng. Mater. Technol., 2017, 737: 198–205
Ma L, Song LN, Wang H, et al. Synthesis and Characterization of Poly(propylene carbonate) Glycol-based Waterborne Polyurethane with a High Solid Content[J]. Prog. Org. Coat., 2018, 122: 38–44
Zheng J, Nie Q, Guan H, et al. A Novel Waterborne Fluorinated Polyurethane-acrylate Film for Ultraviolet Blocking and Antiprotein Fouling[J]. J. Coat. Technol. Res., 2021, 18: 1 295–1 307
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
All authors declare that there are no competing interests.
Rights and permissions
About this article
Cite this article
Yin, Y., Feng, M., Yao, J. et al. Synthesis and Characterization of Nonionic Waterborne Polyurethane and Application to Wool Fabric Finishing. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 39, 497–505 (2024). https://doi.org/10.1007/s11595-024-2905-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-024-2905-7