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Lithium ion transport in PVC/PEG 2000 blend polymer electrolytes complexed with LiX (X=ClO −4 , BF −4 , and CF3SO −3 )

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Abstract

This paper describes preparation and characterization of polyvinyl chloride and polyethylene glycol 2000 blend polymer electrolytes with LiX (X=ClO −4 , BF −4 , and CF3SO −3 ) salt by solution casting technique. Ethylene carbonate and propylene carbonate mixture was used as the plasticizers. LiClO4-based electrolytes exhibited better ionic conduction behavior than other salts. The thermal profiles ascertain the stability of the membranes up to 120°C by differential scanning calorimetry. Complexation and crystallinity were studied through X-ray diffraction measurements. Phase morphological study reveals the porous nature of the polymer electrolyte membranes.

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Author notes

  1. Vanchiappan Aravindan

    Present address: Faculty of Applied Chemical Engineering, Chonnam National University, Gwang-ju, 500757, Republic of Korea

Authors and Affiliations

  1. Department of Physics, Gandhigram Rural University, Gandhigram, 624302, India

    Palanisamy Vickraman & Vanchiappan Aravindan

  2. Faculty of Applied Chemical Engineering, Chonnam National University, 300 Yongbong-dong, Gwang-ju, 500757, Republic of Korea

    Yun-Sung Lee

Authors
  1. Palanisamy Vickraman
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  2. Vanchiappan Aravindan
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  3. Yun-Sung Lee
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Correspondence to Palanisamy Vickraman.

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Vickraman, P., Aravindan, V. & Lee, YS. Lithium ion transport in PVC/PEG 2000 blend polymer electrolytes complexed with LiX (X=ClO −4 , BF −4 , and CF3SO −3 ). Ionics 16, 263–267 (2010). https://doi.org/10.1007/s11581-009-0387-4

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  • DOI: https://doi.org/10.1007/s11581-009-0387-4

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