Abstract
Toxic organic dyes (colorants) are one of the main causes of water pollution that releases destructive effluents in the environment. To overcome this issue, a fundamental need to produce a novel, efficient catalyst for the degradation and mineralization of dye mixtures has arisen. The objective of this research is to develop an eminent Ni-doped magnetic carbon aerogel (Ni-MCA) catalyst using graft co-polymerization method having xanthan gum as backbone doped with Ni-magnetic nanoparticles (Ni-MNPs), that do not show agglomeration and easy to separate. The examination revealed that Ni-MCA provided exceptional magnetic characteristics (Ms = 52.75 emu/g) and potent catalytic activity for the degradation of mono- as well as binary-dye solutions of Congo red (CR) and methyl green (MG) dyes. The formation was verified by various characterization techniques such as FTIR, VSM, XRD, XPS, SEM, TEM, and EDX mapping. Interestingly, Ni-MCA shows faster result on anionic dye CR up to 97% with degradation rate of 5.647 × 10−1 min−1, and MG dye shows degradation of 95.7% with the degradation rate of 2.169 × 10−1 min−1, while dye mixture is showing 90% degradation with rate of 2.159 × 10−1 min−1.
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References
Abd Rani U, Ng LY, Ng YS et al (2022) Photocatalytic degradation of methyl green dye by nitrogen-doped carbon quantum dots: optimisation study by Taguchi approach. Mater Sci Eng B 283:115820
Ahmed MA, Abou-Gamra ZM, Medien HAA, Hamza MA (2017) Effect of porphyrin on photocatalytic activity of TiO2 nanoparticles toward rhodamine B photodegradation. J Photochem Photobiol B Biol 176:25–35
Ahmed SF, Mofijur M, Ahmed B et al (2022) Nanomaterials as a sustainable choice for treating wastewater. Environ Res 214. https://doi.org/10.1016/j.envres.2022.113807
Al-Nuaim MA, Alwasiti AA, Shnain ZY (2023) The photocatalytic process in the treatment of polluted water. Chem Pap 77:677–701. https://doi.org/10.1007/s11696-022-02468-7
Aroh K (2019) Globalization, industralization and population growth the fundamental drivers of pollution in a given society (India). SSRN Electron J. https://doi.org/10.2139/ssrn.3453740
Ayodhya D (2023) Fabrication of SPR triggered Ag-CuO composite from Cu(II)-Schiff base complex for enhanced visible-light-driven degradation of single and binary-dyes and fluorometric detection of nitroaromatic compounds. Inorg Chem Commun 148:1–8. https://doi.org/10.1016/j.inoche.2022.110295
Barzegar MH, Sabzehmeidani MM, Ghaedi M et al (2021) S-scheme heterojunction g-C3N4/TiO2 with enhanced photocatalytic activity for degradation of a binary mixture of cationic dyes using solar parabolic trough reactor. Chem Eng Res Des 174:307–318. https://doi.org/10.1016/j.cherd.2021.08.015
Bel Hadjltaief H, Ben Zina M, Galvez ME, Da Costa P (2016) Photocatalytic degradation of methyl green dye in aqueous solution over natural clay-supported ZnO-TiO2 catalysts. J Photochem Photobiol A Chem 315:25–33. https://doi.org/10.1016/j.jphotochem.2015.09.008
Biswal BK, Balasubramanian R (2022) Adsorptive removal of sulfonamides, tetracyclines and quinolones from wastewater and water using carbon-based materials: Recent developments and future directions. J Clean Prod 349:131421
Bousnoubra I, Djebbar K, Abdessemed A, Sehili T (2016) Decolorization of methyl green and bromocresol purple in mono and binary systems by photochemical processes: direct UV photolysis, acetone/UV and H2O2/UV. A comparative study. Desalin Water Treat 57:27710–27725
Chaudhary S, Goyal S, Umar A (2023) Fabrication of biogenic carbon-based materials from coconut husk for the eradication of dye. Chemosphere 340:139823
Chen C-C, Lu C-S (2007) Mechanistic studies of the photocatalytic degradation of methyl green: an investigation of products of the decomposition processes. Environ Sci Technol 41:4389–4396
Cheng Y, Wang H, Qian T, Yan C (2022) Interfacial engineering of carbon-based materials for efficient electrocatalysis: recent advances and future. EnergyChem 4:100074
Crini G, Lichtfouse E (2019) Advantages and disadvantages of techniques used for wastewater treatment. Environ Chem Lett 17:145–155. https://doi.org/10.1007/s10311-018-0785-9
Cui S, Wang X, Zhang X et al (2018) Preparation of magnetic MnFe2O4-cellulose aerogel composite and its kinetics and thermodynamics of Cu(II) adsorption. Cellulose 25:735–751. https://doi.org/10.1007/s10570-017-1598-x
Ding C, Zhao H, Zhu X, Liu X (2022) Preparation of cotton linters’ aerogel−based C/NiFe2O4 photocatalyst for efficient degradation of methylene blue. Nanomaterials 12. https://doi.org/10.3390/nano12122021
Dutta S, Adhikary S, Bhattacharya S et al (2024) Contamination of textile dyes in aquatic environment: adverse impacts on aquatic ecosystem and human health, and its management using bioremediation. J Environ Manage 353:120103
El-Shazly AN, Rashad MM, Abdel-Aal EA et al (2016) Nanostructured ZnO photocatalysts prepared via surfactant assisted Co-precipitation method achieving enhanced photocatalytic activity for the degradation of methylene blue dyes. J Environ Chem Eng 4:3177–3184
Fowsiya J, Madhumitha G, Al-Dhabi NA, Arasu MV (2016) Photocatalytic degradation of Congo red using Carissa edulis extract capped zinc oxide nanoparticles. J Photochem Photobiol B Biol 162:395–401. https://doi.org/10.1016/j.jphotobiol.2016.07.011
Hamza MA, Abd El-Rahman SA, Abou-Gamra ZM (2022) Facile one-pot solid-state fabrication of a novel binary nanocomposite of commercial ZnO and commercial PbCrO4 with enhanced photocatalytic degradation of rhodamine B dye. Opt Mater (amst) 124:1–7. https://doi.org/10.1016/j.optmat.2022.111987
Hernández-Zamora M, Martínez-Jerónimo F (2019) Congo red dye diversely affects organisms of different trophic levels: a comparative study with microalgae, cladocerans, and zebrafish embryos. Environ Sci Pollut Res 26:11743–11755
Jiao G-J, Ma J, Zhang J et al (2022) High-efficiency capture and removal of phosphate from wastewater by 3D hierarchical functional biomass-derived carbon aerogel. Sci Total Environ 827:154343
Kalwar NH, Sirajuddin SRA et al (2014) Synthesis and characterization of highly efficient nickel nanocatalysts and their use in degradation of organic dyes. Int J Met 2014:1–10. https://doi.org/10.1155/2014/126103
Khalaf EI, El-Shafai NM, Nassar AM et al (2023) Enhancing the photoinduced via a novel nano-combination of terbium oxide and nickel oxide on graphene oxide surface: cytotoxicity and water treatment. Spectrochim Acta Part A Mol Biomol Spectrosc 286:121949
Krishnakumar B, Alsalme A, Alharthi FA et al (2021) Synthesis, characterization of gelatin assisted ZnO and its effective utilization of toxic azo dye degradation under direct sunlight. Opt Mater (amst) 113:110854
Kumari H, Sonia, Suman et al (2023) A review on photocatalysis used for wastewater treatment: dye degradation. Water Air Soil Pollut 234(6):349
Li L, Fu R, Zou J et al (2023) Research progress of iron-based catalysts in ozonation wastewater treatment. ACS ES&T Water 3:908–922
Li S, Chen X, Cheng Z et al (2021) Promoting effect of cellulose-based carbon dots at different concentrations on multifunctional photocatalytic degradation of dyes by ZnO. Opt Mater (amst) 121:111591
Lin L, Yang H, Xu X (2022) Effects of water pollution on human health and disease heterogeneity: a review. Front Environ Sci 10:880246. https://doi.org/10.3389/fenvs.2022.880246
Lu Y, Ma F, Mao J et al (2023) Nickel-iron layered double hydroxide modified by NiS2/FeS2 with regulated electronic structure as a high-performance catalyst for oxygen evolution reaction. J Alloys Compd 960:170842
Mariana M, Hps AK, Yahya EB et al (2022) Recent trends and future prospects of nanostructured aerogels in water treatment applications. J Water Process Eng 45:102481
Masood Z, Ikhlaq A, Rizvi OS et al (2023) A novel hybrid treatment for pharmaceutical wastewater implying electroflocculation, catalytic ozonation with Ni-Co zeolite 5A° catalyst followed by ceramic membrane filtration. J Water Process Eng 51:103423
Meng L, Chang L, Hou J (2022) Degradation of methyl green from wastewater with ultrasound synergized with Bi2O2CO3 catalysis: kinetics, products, and pathways. J Clean Prod 342:130976
Meng Y, Young TM, Liu P et al (2015) Ultralight carbon aerogel from nanocellulose as a highly selective oil absorption material. Cellulose 22:435–447. https://doi.org/10.1007/s10570-014-0519-5
Michel CR, Martínez-Preciado AH (2023) Adsorption and photocatalytic degradation of Congo red and malachite green by nanostructured Y2O3 synthesized by the coprecipitation method. Open Ceram 13:100336. https://doi.org/10.1016/j.oceram.2023.100336
Mittal H, Parashar V, Mishra SB, Mishra AK (2014) Fe3O4 MNPs and gum xanthan based hydrogels nanocomposites for the efficient capture of malachite green from aqueous solution. Chem Eng J 255:471–482. https://doi.org/10.1016/j.cej.2014.04.098
Mudgal D, Singh RP, Yadav N et al (2023a) Exploring the catalytic efficiency of copper-doped magnetic carbon aerogel towards the coupling reaction of isatin oxime with phenylboronic acid derivatives. SynOpen 7:570–579
Mudgal D, Yadav N, Singh J et al (2023b) Xanthan gum-based copper nano-magnetite doped carbon aerogel: a promising candidate for environmentally friendly catalytic dye degradation. Int J Biol Macromol 127491. https://doi.org/10.1016/j.ijbiomac.2023.127491
Nasron AN, Azman NS, Mohd Rashid NSS, Said NR (2018) Degradation of congo red dye in aqueous solution by using advanced oxidation processes. J Acad 6:1–11
Nguyen PTT, Do NHN, Goh XY et al (2022) Recent progresses in eco-friendly fabrication and applications of sustainable aerogels from various waste materials. Waste Biomass Valor 13:1825–1847. https://doi.org/10.1007/s12649-021-01627-3
Nur ASM, Sultana M, Mondal A et al (2022) A review on the development of elemental and codoped TiO2 photocatalysts for enhanced dye degradation under UV–vis irradiation. J Water Process Eng 47:102728
Panda SK, Aggarwal I, Kumar H et al (2021) Magnetite nanoparticles as sorbents for dye removal: a review. Environ Chem Lett 19:2487–2525
Rajasulochana P, Preethy V (2016) Comparison on efficiency of various techniques in treatment of waste and sewage water – a comprehensive review. Resour Technol 2:175–184. https://doi.org/10.1016/j.reffit.2016.09.004
Ramkumar R, Dhakal G, Shim JJ, Kim WK (2022) NiO/Ni nanowafer aerogel electrodes for high performance supercapacitors. Nanomaterials 12(21):3813. https://doi.org/10.3390/nano12213813
Rana N, Bassi A (2023) Role of nanomaterials in the treatment of wastewater. Mod Nanotechnol 125–144. https://doi.org/10.1007/978-3-031-31111-6_6
Saykova D, Saikova S, Mikhlin Y et al (2020) Synthesis and characterization of core–shell magnetic nanoparticles nife2 o4 @au. Metals (basel) 10:1–13. https://doi.org/10.3390/met10081075
Shao B, Xu Y, Liu Z et al (2022) Application of carbon aerogel-based materials in persulfate activation for water treatment: a review. J Clean Prod 384:135518
Singh KK, Singh A, Rai S (2022) A study on nanomaterials for water purification. Mater Today Proc 51:1157–1163
Sowmya SR, Madhu GM, Hashir M (2018) Studies on nano-engineered TiO2 photo catalyst for effective degradation of dye. In: IOP Conference Series: Materials Science and Engineering. IOP Publishing, p 12026
Srivastava A, Mishra V, Singh P et al (2012) Comparative study of thermal degradation behavior of graft copolymers of polysaccharides and vinyl monomers. J Therm Anal Calorim 107:211–223
Tacal Ö, Özer I (2004) Adduct-forming tendencies of cationic triarylmethane dyes with proteins: metabolic and toxicological implications. J Biochem Mol Toxicol 18:253–256
Wang J, Zhang S, Cao H et al (2022) Water purification and environmental remediation applications of carbonaceous nanofiber-based materials. J Clean Prod 331:130023
Yadav G, Mishra SR, Gadore V et al (2023) A smart and sustainable pathway for abatement of single and binary mixtures of dyes through magnetically retrievable Ca4Fe9O17 anchored on Biochar matrix. Sci Rep 13:1–21. https://doi.org/10.1038/s41598-023-40077-w
Yadav N, Gaikwad RP, Mishra V, Gawande MB (2022a) Synthesis and photocatalytic applications of functionalized carbon quantum dots. Bull Chem Soc Jpn 95:1638–1679
Yadav N, Mudgal D, Anand R et al (2022b) Recent development in nanoencapsulation and delivery of natural bioactives through chitosan scaffolds for various biological applications. Int J Biol Macromol 220:537–572
Zeng FY, Sui ZY, Liu S et al (2018) Nitrogen-doped carbon aerogels with high surface area for supercapacitors and gas adsorption. Mater Today Commun 16:1–7. https://doi.org/10.1016/j.mtcomm.2018.03.015
Zhai Z, Ren B, Xu Y et al (2019) Green and facile fabrication of Cu-doped carbon aerogels from sodium alginate for supercapacitors. Org Electron 70:246–251. https://doi.org/10.1016/j.orgel.2019.04.028
Zhang H, Luo W, Du Y et al (2023) The g-C3N4 decorated carbon aerogel with integrated solar steam generation and photocatalysis for effective desalination and water purification. Desalination 564:116821
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VM duly thanks the Science and Engineering Research Board, New Delhi, for the financial support in the terms of SERB-TARE Project (TAR/2022/000673) and Amity University Noida.
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All authors contributed to the study conception and design. Material preparation, data collection, and analysis were performed by Deeksha Mudgal and Nisha Yadav. The first draft of the manuscript was written by Deeksha Mudgal, and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.
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Mudgal, D., Yadav, N. & Mishra, V. Nickel-doped magnetic carbon aerogel derived from xanthan gum: a competent catalyst for the degradation of single and binary dye-based water pollutants. Environ Sci Pollut Res (2024). https://doi.org/10.1007/s11356-024-33605-2
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DOI: https://doi.org/10.1007/s11356-024-33605-2