Abstract
The development of eco-friendly photocatalysts is gaining attention as an effective approach for degrading organic pollutants. In the present study, the composite materials are composed of various components with varying structures that combine to enhance their characteristics and widen their applications. This work uses the hydrothermal method for the fabrication of a novel and steady SiO2/g-C3N4 photocatalyst. The amount of SiO2 was fixed, and graphitic carbon nitride (g-C3N4) was varied in the ratio (1:x, where x = 1, 2, 3) and abbreviated as SCN1, SCN2, and SCN3. The optical properties, surface morphology, and structural analysis of the prepared nanocomposites were studied using various techniques such as FTIR, TGA, X-ray diffraction, and ultraviolet–visible spectroscopy. The results show that SCN2 nanocomposites significantly improved the photocatalytic activity, with a degradation efficiency of 70% for auramine O and 84.6% for xylenol orange dye under visible light irradiation, which is a result of their large surface area and efficient electron–hole separation rate.
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References
Abbasi F, Hashemi H, Samaei MR, SavarDashtaki A, Azhdarpoor A, Fallahi MJ (2021) The synergistic interference effect of silica nanoparticles concentration and the wavelength of ELISA on the colorimetric assay of cell toxicity. Sci Rep 11:1–11. https://doi.org/10.1038/s41598-021-92419-1
Akhter F, Rao AA, Abbasi MN, Wahocho SA, Mallah MA, Anees-ur-Rehman H, Chandio ZA (2022) A comprehensive review of synthesis, applications and future prospects for silica nanoparticles (SNPs). SILICON 1:1–16
Bray RT, Jankowska K, Kulbat E, Łuczkiewicz A, Sokołowska A (2021) Ultrafiltration process in disinfection and advanced treatment of tertiary treated wastewater. Membranes (Basel) 11. https://doi.org/10.3390/membranes11030221
Cao S, Low J, Yu J, Jaroniec M (2015) Polymeric photocatalysts based on graphitic carbon nitride. Adv Mater 27:2150–2176. https://doi.org/10.1002/adma.201500033
de Jesus Azevedo CC, de Oliveira R, Suares-Rocha P, Sousa-Moura D, Li AT, Grisolia CK, de Aragão UG et al (2021) Auramine dyes induce toxic effects to aquatic organisms from different trophic levels: an application of predicted non-effect concentration (PNEC). Environ Sci Pollut Res 28:1866–1877. https://doi.org/10.1007/s11356-020-10462-3
Dubey RS, Rajesh YBRD, More MA (2015) Synthesis and characterization of SiO2 nanoparticles via sol-gel method for industrial applications. Materials today: proceedings. Elsevier Ltd, New York, pp 3575–3579
Eghbali P, Hassani A, Sündü B, Metin Ö (2019) Strontium titanate nanocubes assembled on mesoporous graphitic carbon nitride (SrTiO3/mpg-C3N4): preparation, characterization and catalytic performance. J Mol Liq 290:111208. https://doi.org/10.1016/j.molliq.2019.111208
Ezugbe EO, Rathilal S (2020) Membrane technologies in wastewater treatment: a review. Membranes (Basel) 10. https://doi.org/10.3390/membranes10050089
Fang W, Deng Y, Tang L, Zeng G, Zhou Y, Xie X, Wang J et al (2017) Synthesis of Pd/Au bimetallic nanoparticle-loaded ultrathin graphitic carbon nitride nanosheets for highly efficient catalytic reduction of p-nitrophenol. J Colloid Interface Sci 490:834–843. https://doi.org/10.1016/j.jcis.2016.12.017
Feng P, Chang H, Liu X, Ye S, Shu X, Ran Q (2020) The significance of dispersion of nano-SiO2 on early age hydration of cement pastes. Mater Des 186:108320. https://doi.org/10.1016/j.matdes.2019.108320
Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochem Photobiol C Photochem Rev 1:1–21. https://doi.org/10.1016/S1389-5567(00)00002-2
Giannakis S, Rtimi S, Pulgarin C (2017) Light-assisted advanced oxidation processes for the elimination of chemical and microbiological pollution of wastewaters in developed and developing countries. Molecules 22:1070. https://doi.org/10.3390/molecules22071070
Giraldo LJ, Giraldo MA, Llanos S, Maya G, Zabala RD, Nassar NN, Franco CA et al (2017) The effects of SiO2 nanoparticles on the thermal stability and rheological behavior of hydrolyzed polyacrylamide based polymeric solutions. J Pet Sci Eng 159:841–852. https://doi.org/10.1016/j.petrol.2017.10.009
Hao Q, Niu X, Nie C, Hao S, Zou W, Ge J, Chen D et al (2016) A highly efficient g-C3N4/SiO2 heterojunction: the role of SiO2 in the enhancement of visible light photocatalytic activity. Phys Chem Chem Phys 18:31410–31418. https://doi.org/10.1039/c6cp06122b
Hassani A, Eghbali P, Metin Ö (2018) Sonocatalytic removal of methylene blue from water solution by cobalt ferrite/mesoporous graphitic carbon nitride (CoFe2O4/mpg-C3N4) nanocomposites: response surface methodology approach. Environ Sci Pollut Res 25:32140–32155. https://doi.org/10.1007/s11356-018-3151-3
Hassani A, Faraji M, Eghbali P (2020) Facile fabrication of mpg-C3N4/Ag/ZnO nanowires/Zn photocatalyst plates for photodegradation of dye pollutant. J Photochem Photobiol A Chem 400:112665. https://doi.org/10.1016/j.jphotochem.2020.112665
Hassani A, Krishnan S, Scaria J, Eghbali P, Nidheesh PV (2021) Z-scheme photocatalysts for visible-light-driven pollutants degradation: a review on recent advancements. Curr Opin Solid State Mater Sci 25:100941. https://doi.org/10.1016/j.cossms.2021.100941
Iliev V, Tomova D, Bilyarska L, Petrov L (2004) Photooxidation of xylenol orange in the presence of palladium-modified TiO2 catalysts. Catal Commun 5:759–763. https://doi.org/10.1016/j.catcom.2004.09.005
Karim AV, Hassani A, Eghbali P, Nidheesh PV (2022) Nanostructured modified layered double hydroxides (LDHs)-based catalysts: a review on synthesis, characterization, and applications in water remediation by advanced oxidation processes. Curr Opin Solid State Mater Sci 26:100965. https://doi.org/10.1016/j.cossms.2021.100965
Khan MN, Bhutto S (2010) Kinetic study of the oxidative decolorization of xylenol orange by hydrogen peroxide in micellar medium. J Chil Chem Soc 55:170–175. https://doi.org/10.4067/s0717-97072010000200005
Khan ME, Khan MM, Min BK, Cho MH (2018) Microbial fuel cell assisted band gap narrowed TiO2 for visible light-induced photocatalytic activities and power generation. Sci Rep 8. https://doi.org/10.1038/s41598-018-19617-2
Li K, Gao S, Wang Q, Xu H, Wang Z, Huang B, Dai Y et al (2015) In-situ-reduced synthesis of Ti3+ self-doped TiO2/g-C3N4 heterojunctions with high photocatalytic performance under LED light irradiation. ACS Appl Mater Interfaces 7:9023–9030. https://doi.org/10.1021/am508505n
Lin J, Liu Y, Liu Y, Huang C, Liu W, Mi X, Fan D et al (2019) SnS2 nanosheets/H-TiO2 nanotube arrays as a type II heterojunctioned photoanode for photoelectrochemical water splitting. Chemsuschem 12:961–967. https://doi.org/10.1002/cssc.201802691
Liu R, Chen Z, Yao Y, Li Y, Cheema WA, Wang D, Zhu S (2020a) Recent advancements in g-C3N4-based photocatalysts for photocatalytic CO2reduction: a mini review. RSC Adv 10:29408–29418. https://doi.org/10.1039/d0ra05779g
Liu R, Yang W, He G, Zheng W, Li M, Tao W, Tian M (2020b) Ag-modified g-C3N4 prepared by a one-step calcination method for enhanced catalytic efficiency and stability. ACS Omega 5:19615–19624. https://doi.org/10.1021/acsomega.0c02161
Madihi-Bidgoli S, Asadnezhad S, Yaghoot-Nezhad A, Hassani A (2021) Azurobine degradation using Fe2O3@multi-walled carbon nanotube activated peroxymonosulfate (PMS) under UVA-LED irradiation: performance, mechanism and environmental application. J Environ Chem Eng 9:106660. https://doi.org/10.1016/j.jece.2021.106660
Martin E, Ori G, Duong TQ, Boero M, Massobrio C (2022) Thermal conductivity of amorphous SiO2 by first-principles molecular dynamics. J Non Cryst Solids 581:121434. https://doi.org/10.1016/j.jnoncrysol.2022.121434
Mittal A, Mari B, Sharma S, Kumari V, Maken S, Kumari K, Kumar N (2019) Non-metal modified TiO2: a step towards visible light photocatalysis. J Mater Sci Mater Electron 30:3186–3207. https://doi.org/10.1007/s10854-018-00651-9
Patidar D, Yadav A, Paul DR, Sharma A, Nehra SP (2019) Nanohybrids cadmium selenide-reduced graphene oxide for improving photo-degradation of methylene blue. Phys E Low-Dim Syst Nanostruct 114:113560. https://doi.org/10.1016/j.physe.2019.113560
Paul DR, Sharma R, Panchal P, Malik R, Sharma A, Tomer VK, Nehra SP (2019) Silver doped graphitic carbon nitride for the enhanced photocatalytic activity towards organic dyes. J Nanosci Nanotechnol 19:5241–5248. https://doi.org/10.1166/jnn.2019.16838
Paul DR, Gautam S, Panchal P, Nehra SP, Choudhary P, Sharma A (2020) ZnO-modified g-C3N4: a potential photocatalyst for environmental application. ACS Omega 5:3828–3838. https://doi.org/10.1021/acsomega.9b02688
Peng L, Li ZW, Zheng RR, Yu H, Dong XT (2019) Preparation and characterization of mesoporous g-C3N4/SiO2 material with enhanced photocatalytic activity. J Mater Res 34:1785–1794. https://doi.org/10.1557/jmr.2019.113
Prakash K, Kumar PS, Latha P, Saravanakumar K, Karuthapandian S (2018) Design and fabrication of a novel metal-free SiO2/g-C3N4 nanocomposite: a robust photocatalyst for the degradation of organic contaminants. J Inorg Organomet Polym Mater 28:268–278. https://doi.org/10.1007/s10904-017-0715-5
Precious Sibiya N, Rathilal S, KweinorTetteh E (2021) Coagulation treatment of wastewater: kinetics and natural coagulant evaluation. Molecules 26. https://doi.org/10.3390/molecules26030698
Ragupathi V, Panigrahi P, Ganapathi Subramaniam N (2020) Bandgap engineering in graphitic carbon nitride: effect of precursors. Optik (stuttg) 202:163601. https://doi.org/10.1016/j.ijleo.2019.163601
Rattan Paul D, Nehra SP (2021) Graphitic carbon nitride: a sustainable photocatalyst for organic pollutant degradation and antibacterial applications. Environ Sci Pollut Res 28:3888–3896. https://doi.org/10.1007/s11356-020-09432-6
Retamoso C, Escalona N, González M, Barrientos L, Allende-González P, Stancovich S, Serpell R et al (2019) Effect of particle size on the photocatalytic activity of modified rutile sand (TiO2) for the discoloration of methylene blue in water. J Photochem Photobiol A Chem 378:136–141. https://doi.org/10.1016/j.jphotochem.2019.04.021
Rtimi S, Pulgarin C, Sanjines R, Kiwi J (2015) Kinetics and mechanism for transparent polyethylene-TiO2 films mediated self-cleaning leading to MB dye discoloration under sunlight irradiation. Appl Catal B Environ 162:236–244. https://doi.org/10.1016/j.apcatb.2014.05.039
Rtimi S, Giannakis S, Bensimon M, Pulgarin C, Sanjines R, Kiwi J (2016) Supported TiO2 films deposited at different energies: implications of the surface compactness on the catalytic kinetics. Appl Catal B Environ 191:42–52. https://doi.org/10.1016/j.apcatb.2016.03.019
Shoran S, Chaudhary S, Sharma A (2022) Photocatalytic dye degradation and antibacterial activities of CeO2/g-C3N4 nanomaterials for environmental applications. Environ Sci Pollut Res. https://doi.org/10.1007/S11356-022-23815-X
Subashini A, Varun Prasath P, Sagadevan S, Anita Lett J, Fatimah I, Mohammad F, Al-Lohedan HA, et al (2021) Enhanced photocatalytic degradation efficiency of graphitic carbon nitride-loaded CeO2 nanoparticles. Chem Phys Lett 769. https://doi.org/10.1016/j.cplett.2021.138441
Sun R, Chen Z, Yang Y, Peng J, Zheng T (2019) Effects and mechanism of SiO2 on photocatalysis and super hydrophilicity of TiO2 films prepared by sol-gel method. Mater Res Express 6:046409. https://doi.org/10.1088/2053-1591/aafa8c
Sun H, Qin J, Yi L, Ruan Y, Wang J, Fang D (2022) A new process for degradation of auramine O dye and heat generation based on orifice plate hydrodynamic cavitation (HC): parameter optimization and performance analyses. Process Saf Environ Prot 161:669–683. https://doi.org/10.1016/j.psep.2022.03.058
Tezcan Un U, Ates F (2019) Low-cost adsorbent prepared from poplar sawdust for removal of disperse orange 30 dye from aqueous solutions. Int J Environ Sci Technol 16:899–908. https://doi.org/10.1007/s13762-018-1716-9
Tseng IH, Sung YM, Chang PY, Chen CY (2019) Anatase TiO2-decorated graphitic carbon nitride for photocatalytic conversion of carbon dioxide. Polymers (Basel) 11.https://doi.org/10.3390/polym11010146
Van Dao D, Nguyen TTD, Song HY, Yang JK, Kim TW, Yu YT, Lee IH (2018) Ionic liquid-assisted preparation of Ag-CeO2 nanocomposites and their improved photocatalytic activity. Mater Des 159:186–194. https://doi.org/10.1016/j.matdes.2018.08.042
Verma M, Haritash AK (2019) Degradation of amoxicillin by Fenton and Fenton-integrated hybrid oxidation processes. J Environ Chem Eng 7:102886. https://doi.org/10.1016/j.jece.2019.102886
Wang X, Wang S, Hu W, Cai J, Zhang L, Dong L, Zhao L et al (2014) Synthesis and photocatalytic activity of SiO2/g-C 3N4 composite photocatalyst. Mater Lett 115:53–56. https://doi.org/10.1016/j.matlet.2013.10.016
Wang W, Zhang M, Zhao B, Liu L, Han R, Wang N (2021) Synthesis of Bi2WO6/g-C3N4 photocatalyst and high degradation of rhodamine B under visible light irradiation. Pigment Resin Technol 51:91–100. https://doi.org/10.1108/PRT-09-2020-0097
Wu P, Wang J, Zhao J, Guo L, Osterloh FE (2014) Structure defects in g-C3N4 limit visible light driven hydrogen evolution and photovoltage. J Mater Chem A 2:20338–20344. https://doi.org/10.1039/c4ta04100c
Acknowledgements
The authors are thankful to Monika Dhanda, Surface Lab, Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal, for electrochemical analysis; Central Instrumentation Lab (Lovely Professional University) for TGA and FTIR testing; and SAIF (AIIMS, New Delhi) for morphological studies.
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Anshu Sharma acknowledges the University Grants Commission, Ministry of Education, Govt. of India, for providing Start-Up-Grant reference no. 30–545/2021 (BSR).
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Sachin Shoran: conceptualization; methodological analysis; investigation; roles/writing—original draft; writing—review and editing. Sudesh Chaudhary and Anshu Sharma: supervision; project administration; conceptualization; methodology; roles/writing—original draft; writing—review and editing.
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Shoran, S., Sharma, A. & Chaudhary, S. Visible light enhanced photocatalytic degradation of organic pollutants with SiO2/g-C3N4 nanocomposite for environmental applications. Environ Sci Pollut Res 30, 98732–98746 (2023). https://doi.org/10.1007/s11356-022-24837-1
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DOI: https://doi.org/10.1007/s11356-022-24837-1