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Insights into the reactivity of supported Au nanoparticles: combining theory and experiments

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The origin of the extraordinary catalytic activity of gold nanoparticles is discussed on the basis of density-functional calculations, adsorption studies on single crystal surfaces, and activity measurements on well characterized supported gold particles. A number of factors are identified contributing to the activity, and it is suggested that it is useful to consider low-coordinated Au atoms as the active sites, for example, CO oxidation and that the effect of the support can be viewed as structural and electronic promotion. We identify the adsorption energy of oxygen and the Au-support interface energy as important parameters determining the catalytic activity.

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References

  1. M. Haruta, N. Kobayashi, H. Sano and N. Yamada, Chem. Lett. (1987) 405

  2. T. Kobayashi M. Haruta H. Sano M. Nakane (1988) Sens. Actuators 13 339 Occurrence Handle1:CAS:528:DyaL1cXhslalsro%3D Occurrence Handle10.1016/0250-6874(88)80047-7

    Article  CAS  Google Scholar 

  3. M. Haruta N. Yamada T. Kobayashi S. Ijima (1989) J. Catal. 115 301 Occurrence Handle1:CAS:528:DyaL1MXhtVamsbY%3D Occurrence Handle10.1016/0021-9517(89)90034-1

    Article  CAS  Google Scholar 

  4. M. Haruta H. Kageyama N. Kamijo T. Kobayashi F. Delannay (1989) Stud. Surf. Sci. Catal. 44 33 Occurrence Handle1:CAS:528:DyaL1MXhsVahsL4%3D

    CAS  Google Scholar 

  5. M. Haruta S. Tsubota T. Kobayashi H. Kageyama M.J. Genet B. Delmon (1993) J. Catal. 144 175 Occurrence Handle1:CAS:528:DyaK2cXhs1GitQ%3D%3D Occurrence Handle10.1006/jcat.1993.1322

    Article  CAS  Google Scholar 

  6. M. Valden X. Lai D.W. Goodman (1998) Science 281 1647 Occurrence Handle9733505 Occurrence Handle1:CAS:528:DyaK1cXmtVSqu7w%3D Occurrence Handle10.1126/science.281.5383.1647 Occurrence Handle1998Sci...281.1647V

    Article  PubMed  CAS  ADS  Google Scholar 

  7. M. Valden S. Pak X. Lai D.W. Goodman (1998) Catal. Lett. 56 7 Occurrence Handle1:CAS:528:DyaK1cXotVaksb0%3D Occurrence Handle10.1023/A:1019028205985

    Article  CAS  Google Scholar 

  8. G.C. Bond D.T. Thomson (1999) Catal. Rev. Sci. Eng. 41 319 Occurrence Handle1:CAS:528:DyaK1MXmvFehsLk%3D Occurrence Handle10.1081/CR-100101171

    Article  CAS  Google Scholar 

  9. D.T. Wickham D.H. Parker G.N. Kastanas M.A. Lazaga B.E. Koel (1992) Prepr. - Am. Chem. Soc., Div. Pet. Chem. 37 1034 Occurrence Handle1:CAS:528:DyaK3sXks1Gqug%3D%3D

    CAS  Google Scholar 

  10. M.A. Lazaga D.T. Wickham D.H. Parker G.N. Kastanas B.E. Koel (1993) ACS Symp. Ser. 523 90 Occurrence Handle1:CAS:528:DyaK3sXlvV2nsLw%3D Occurrence Handle10.1021/bk-1993-0523.ch008

    Article  CAS  Google Scholar 

  11. B. Hammer J.K. Nørskov (1995) Nature 376 238 Occurrence Handle1:CAS:528:DyaK2MXntFSmurk%3D Occurrence Handle10.1038/376238a0 Occurrence Handle1995Natur.376..238H

    Article  CAS  ADS  Google Scholar 

  12. T. Hayashi K. Tanaka M. Haruta (1996) Prepr. Am. Chem. Soc., Div. Pet. Chem. 41 71 Occurrence Handle1:CAS:528:DyaK28XisF2is70%3D

    CAS  Google Scholar 

  13. M. Haruta (1997) Stud. Surf. Sci. Catal. 110 123 Occurrence Handle1:CAS:528:DyaK1cXptleitw%3D%3D

    CAS  Google Scholar 

  14. B.S. Uphade, S. Tsubota, T. Hayashi and M. Haruta, Chem. Lett. (1998) 1277

  15. Y.A. Kalvachev T. Hayashi S. Tsubota M. Haruta (1999) J. Catal. 186 228 Occurrence Handle1:CAS:528:DyaK1MXls1eit7g%3D Occurrence Handle10.1006/jcat.1999.2540

    Article  CAS  Google Scholar 

  16. M.A.P. Dekkers M.J. Lippits B.E. Nieuwenhuys (1999) Catal. Today 54 381 Occurrence Handle1:CAS:528:DyaK1MXnvVWitb0%3D Occurrence Handle10.1016/S0920-5861(99)00201-1

    Article  CAS  Google Scholar 

  17. B.S. Uphade M. Okumura S. Tsubota M. Haruta (2000) Appl. Catal. A 190 43 Occurrence Handle1:CAS:528:DC%2BD3cXlsFSksQ%3D%3D Occurrence Handle10.1016/S0926-860X(99)00285-9

    Article  CAS  Google Scholar 

  18. T.V. Choudhary D.W. Goodman (2002) Top. Catal. 21 25 Occurrence Handle1:CAS:528:DC%2BD38Xnslaqu7Y%3D Occurrence Handle10.1023/A:1020595713329

    Article  CAS  Google Scholar 

  19. R.J.H. Grisel J.J. Slyconish B.E. Nieuwenhuys (2001) Top. Catal. 16/17 425 Occurrence Handle1:CAS:528:DC%2BD3MXns1GgtbY%3D Occurrence Handle10.1023/A:1016694022941

    Article  CAS  Google Scholar 

  20. R.J.H. Grisel B.E. Nieuwenhuys (2001) Catal. Today 64 69 Occurrence Handle1:CAS:528:DC%2BD3MXht1Khu7Y%3D Occurrence Handle10.1016/S0920-5861(00)00510-1

    Article  CAS  Google Scholar 

  21. S. Carrettin, P. McMorn, P. Johnston, K. Griffin and G.J. Hutchings, Chem. Commun. (2002) 696

  22. S. Schimpf M. Lucas C. Mohr U. Rodemerck A. Brückner J. Radnik H. Hofmeister P. Claus (2002) Catal. Today 72 63 Occurrence Handle1:CAS:528:DC%2BD38XisV2jtLc%3D Occurrence Handle10.1016/S0920-5861(01)00479-5

    Article  CAS  Google Scholar 

  23. P. Landon, P.J. Collier, A.J. Papworth, C.J. Kiely and G.J. Hutchings, Chem. Commun. (2002) 2058

  24. S. Carrettin P. McMorn P. Johnston K. Griffin C.J. Kiely G.J. Hutchings (2003) Phys. Chem. Chem. Phys. 5 1329 Occurrence Handle1:CAS:528:DC%2BD3sXhsFKrt7w%3D Occurrence Handle10.1039/b212047j

    Article  CAS  Google Scholar 

  25. M. Okumura Y. Kitagawa K. Yamagcuhi T. Akita S. Tsubota M. Haruta (2003) Chem. Lett. 32 822 Occurrence Handle1:CAS:528:DC%2BD3sXnt1WnsrY%3D Occurrence Handle10.1246/cl.2003.822

    Article  CAS  Google Scholar 

  26. J.A. Moulijn, A. Zwijnenburg, W.G. Sloof, M.W.J. Craje and M.␣Makkee, Abstract of Papers, 226th ACS National Meeting, New York, NY (2003)

  27. S. Carrettin P. McMorn P. Johnston K. Griffin C.J. Kiely G.A. Attard G.J. Hutchings (2004) Top. Catal. 27 131 Occurrence Handle1:CAS:528:DC%2BD2cXntleksw%3D%3D Occurrence Handle10.1023/B:TOCA.0000013547.35106.0d

    Article  CAS  Google Scholar 

  28. R. Meyer C. Lemire S. Shaikhutdinov H.J. Freund (2004) Gold Bull. 37 72 Occurrence Handle1:CAS:528:DC%2BD2cXnt1emsLg%3D

    CAS  Google Scholar 

  29. M.D. Hughes Y.J. Xu P. Jenkins P. McMorn P. Landon D.I. Enache A.F. Carley G.A. Attard G.J. Hutchings F. King E.H. Stitt P. Johnston K. Griffin C.J. Kiely (2005) Nature 437 1132 Occurrence Handle16237439 Occurrence Handle1:CAS:528:DC%2BD2MXhtFahtLzN Occurrence Handle10.1038/nature04190 Occurrence Handle2005Natur.437.1132H

    Article  PubMed  CAS  ADS  Google Scholar 

  30. A. Abad P. Concepcion A. Corma H. Garcia (2005) Angew. Chem. Int. Ed. 44 4066 Occurrence Handle1:CAS:528:DC%2BD2MXmtF2gsrc%3D Occurrence Handle10.1002/anie.200500382

    Article  CAS  Google Scholar 

  31. A.C. Gluhoi, M.A.P. Dekkers and B.E. Nieuwenhuys, J. Catal. 219 (2003) 197; J. Catal. 229 (2005) 154; J. Catal. 232 (2005) 96

    Google Scholar 

  32. C.H. Christensen B. Jørgensen J. Rass-Hansen K. Egeblad R. Madsen S.K. Klitgaard S.M. Hansen M.R. Hansen H.C. Andersen A. Riisager (2006) Ang. Chem. Int. 45 4648 Occurrence Handle1:CAS:528:DC%2BD28Xnt1Kqt7g%3D Occurrence Handle10.1002/anie.200601180

    Article  CAS  Google Scholar 

  33. I.S. Nielsen, E. Taarning, K. Egeblad, R. Madsen and C.H. Christensen, Catal. Lett. DOI: 10.1007/s10562-007-9086-9 (2007)

  34. T.A. Nijhuis M. Makkee J.A. Moulijn B.M. Weckhuysen (2006) Ind. Eng. Chem. Res. 45 3447 Occurrence Handle1:CAS:528:DC%2BD28XjtVygtLg%3D Occurrence Handle10.1021/ie0513090

    Article  CAS  Google Scholar 

  35. J.D. Grunwaldt M. Maciejewski O.S. Becker P. Fabrizioli A Baiker (1999) J. Catal. 186 458 Occurrence Handle1:CAS:528:DyaK1MXlvFahsbc%3D Occurrence Handle10.1006/jcat.1999.2564

    Article  CAS  Google Scholar 

  36. M. Mavrikakis P. Stoltze J.K. Nørskov (2000) Catal. Lett. 64 101 Occurrence Handle1:CAS:528:DC%2BD3cXhslSgtLk%3D Occurrence Handle10.1023/A:1019028229377

    Article  CAS  Google Scholar 

  37. N. Lopez J.K. Nørskov (2002) J. Am. Chem. Soc. 124 11262 Occurrence Handle12236728 Occurrence Handle1:CAS:528:DC%2BD38Xms1Wntb8%3D Occurrence Handle10.1021/ja026998a

    Article  PubMed  CAS  Google Scholar 

  38. N. Lopez J.K. Nørskov (2002) Surf. Sci. 515 175 Occurrence Handle1:CAS:528:DC%2BD38XlvVSrs7c%3D Occurrence Handle10.1016/S0039-6028(02)01873-3

    Article  CAS  Google Scholar 

  39. S. Shaikhutdinov R. Meyer M. Naschitzki M. Baeumer H.J. Freund (2003) Catal. Lett. 86 211 Occurrence Handle1:CAS:528:DC%2BD3sXhslWhurk%3D Occurrence Handle10.1023/A:1022616102162

    Article  CAS  Google Scholar 

  40. G. Mills M.S. Gordon H. Metiu (2003) J. Chem. Phys. 118 4198 Occurrence Handle1:CAS:528:DC%2BD3sXht1Cksr4%3D Occurrence Handle10.1063/1.1542879 Occurrence Handle2003JChPh.118.4198M

    Article  CAS  ADS  Google Scholar 

  41. C. Lemire R. Meyer S. Shaikhutdinov H.-J. Freund (2004) Surf. Sci. 552 27 Occurrence Handle1:CAS:528:DC%2BD2cXhs1Oksb4%3D Occurrence Handle10.1016/j.susc.2004.01.029 Occurrence Handle2004SurSc.552...27L

    Article  CAS  ADS  Google Scholar 

  42. C. Lemire R. Meyer S. Shaikhutdinov H.J. Freund (2004) Angew. Chem. Int. Ed. 43 118 Occurrence Handle10.1002/anie.200352538 Occurrence Handle1:CAS:528:DC%2BD2cXhsVCrsg%3D%3D

    Article  CAS  Google Scholar 

  43. N. Lopez T.V.W. Janssens B.S. Clausen Y. Xu M. Mavrikakis T. Bligaard J.K. Nørskov (2004) J. Catal. 223 232 Occurrence Handle1:CAS:528:DC%2BD2cXislWjsb4%3D Occurrence Handle10.1016/j.jcat.2004.01.001

    Article  CAS  Google Scholar 

  44. R. Zanella S. Giorgio C.H. Shin C.R. Henry C. Louis (2004) J. Catal. 222 357 Occurrence Handle1:CAS:528:DC%2BD2cXhvV2gsLs%3D Occurrence Handle10.1016/j.jcat.2003.11.005

    Article  CAS  Google Scholar 

  45. M.M. Biener J. Biener C.M. Friend (2005) Surf. Sci. 590 L259 Occurrence Handle1:CAS:528:DC%2BD2MXot1Ciur0%3D Occurrence Handle10.1016/j.susc.2005.06.003

    Article  CAS  Google Scholar 

  46. X. Deng B.K. Min A. Guloy C.M. Friend (2005) J. Am. Chem. Soc. 127 9267 Occurrence Handle15969608 Occurrence Handle1:CAS:528:DC%2BD2MXkslSgu7Y%3D Occurrence Handle10.1021/ja050144j

    Article  PubMed  CAS  Google Scholar 

  47. T.V.W. Janssens A. Carlsson A. Puig-Molina B.S. Clausen (2006) J. Catal. 240 108 Occurrence Handle1:CAS:528:DC%2BD28XksFaqtro%3D Occurrence Handle10.1016/j.jcat.2006.03.008

    Article  CAS  Google Scholar 

  48. X. Lai T.P. Clair M. Valden D.W. Goodman (1998) Prog. Surf. Sci. 59 25 Occurrence Handle1:CAS:528:DyaK1MXmslKjug%3D%3D Occurrence Handle10.1016/S0079-6816(98)00034-3

    Article  CAS  Google Scholar 

  49. X. Lai D.W. Goodman (2000) J. Mol. Catal. A 162 33 Occurrence Handle1:CAS:528:DC%2BD3cXovFejtro%3D Occurrence Handle10.1016/S1381-1169(00)00320-4

    Article  CAS  Google Scholar 

  50. Z. Yang R. Wu D.W. Goodman (2000) Phys. Rev. B 61 14066 Occurrence Handle1:CAS:528:DC%2BD3cXjs1Smu7s%3D Occurrence Handle10.1103/PhysRevB.61.14066 Occurrence Handle2000PhRvB..6114066Y

    Article  CAS  ADS  Google Scholar 

  51. A. Sanchez S. Abbet U. Heiz W.-D. Schneider H. Häkkinen R.N. Barnett U. Landman (1999) J. Phys. Chem. A 103 9573 Occurrence Handle1:CAS:528:DyaK1MXntFalurc%3D Occurrence Handle10.1021/jp9935992

    Article  CAS  Google Scholar 

  52. D. Ricci A. Bongiorno G. Pacchioni U. Landman (2006) Phys. Rev. Lett. 97 036106 Occurrence Handle16907518 Occurrence Handle10.1103/PhysRevLett.97.036106 Occurrence Handle1:CAS:528:DC%2BD28Xnt1Kgt7w%3D Occurrence Handle2006PhRvL..97c6106R

    Article  PubMed  CAS  ADS  Google Scholar 

  53. J.A. Bokhoven Particlevan C. Louis J.T. Miller M. Tromp O.V. Safonova P. Glatzel (2006) Angew. Chem. Int. Ed. 45 4651 Occurrence Handle10.1002/anie.200601184 Occurrence Handle1:CAS:528:DC%2BD28Xnt1KqtLs%3D

    Article  CAS  Google Scholar 

  54. M. Okumura S. Nakamura S. Tsubota T. Nakamura M. Azuma M. Haruta (1998) Catal. Lett. 51 53 Occurrence Handle1:CAS:528:DyaK1cXjtlSht70%3D Occurrence Handle10.1023/A:1019020614336

    Article  CAS  Google Scholar 

  55. M.M. Schubert S. Hackenberg A.C. Veen Particlevan M. Muhler V. Plzak R.J. Behm (2001) J. Catal. 113 197

    Google Scholar 

  56. Z.P. Liu P. Hu A. Alavi (2002) J. Am. Chem. Soc. 124 14770 Occurrence Handle12465990 Occurrence Handle1:CAS:528:DC%2BD38Xos1Sgs7w%3D Occurrence Handle10.1021/ja0205885

    Article  PubMed  CAS  Google Scholar 

  57. L.M. Molina B. Hammer (2003) Phys. Rev. Lett. 90 206102 Occurrence Handle12785908 Occurrence Handle1:CAS:528:DC%2BD3sXktVarur4%3D Occurrence Handle10.1103/PhysRevLett.90.206102 Occurrence Handle2003PhRvL..90t6102M

    Article  PubMed  CAS  ADS  Google Scholar 

  58. L.M. Molina B. Hammer (2004) Phys. Rev. B 69 155424 Occurrence Handle10.1103/PhysRevB.69.155424 Occurrence Handle1:CAS:528:DC%2BD2cXktVKjsLg%3D Occurrence Handle2004PhRvB..69o5424M

    Article  CAS  ADS  Google Scholar 

  59. L.M. Molina M.D. Rasmussen B. Hammer (2004) J. Chem. Phys. 120 7673 Occurrence Handle15267678 Occurrence Handle1:CAS:528:DC%2BD2cXivFOnt7c%3D Occurrence Handle10.1063/1.1687337 Occurrence Handle2004JChPh.120.7673M

    Article  PubMed  CAS  ADS  Google Scholar 

  60. G.C. Bond D.T. Thompson (2000) Gold Bull. 33 41 Occurrence Handle1:CAS:528:DC%2BD3MXmsFKgsw%3D%3D

    CAS  Google Scholar 

  61. L.M. Molina B. Hammer (2005) Appl. Catal. A 291 21 Occurrence Handle1:CAS:528:DC%2BD2MXosVajsr4%3D Occurrence Handle10.1016/j.apcata.2005.01.050

    Article  CAS  Google Scholar 

  62. H. Sakurai T. Akita S. Tsubota M. Kiuchi M. Haruta (2005) Appl. Catal. A 291 179 Occurrence Handle1:CAS:528:DC%2BD2MXosVWqu7s%3D Occurrence Handle10.1016/j.apcata.2005.02.043

    Article  CAS  Google Scholar 

  63. L.M. Liu B. McAllister H.Q. Ye P. Hu (2006) J. Am. Chem. Soc. 128 4017 Occurrence Handle16551110 Occurrence Handle1:CAS:528:DC%2BD28XhvF2is7c%3D Occurrence Handle10.1021/ja056801p

    Article  PubMed  CAS  Google Scholar 

  64. B. Hammer (2006) Top. Catal. 37 3 Occurrence Handle1:CAS:528:DC%2BD28XjslKitro%3D Occurrence Handle10.1007/s11244-006-0004-y

    Article  CAS  Google Scholar 

  65. R.M. Finch N.A. Hodge G.J. Hutchings A. Meagher Q.A. Pankhurst M.R. Siddiqui F.E. Wagner R. Whyman (1999) Phys. Chem. Chem. Phys. 1 485 Occurrence Handle1:CAS:528:DyaK1MXhtV2isbc%3D Occurrence Handle10.1039/a808208a

    Article  CAS  Google Scholar 

  66. Z. Hao L. An H. Wang T. Hu (2000) React. Kinet. Catal. Lett. 70 153 Occurrence Handle1:CAS:528:DC%2BD3cXnvFWjsb4%3D Occurrence Handle10.1023/A:1010383220836

    Article  CAS  Google Scholar 

  67. N.A. Hodge C.J. Kiely R. Whyman M.R.H. Siddiqui G.J. Hutchings Q.A. Pankhurst F.E. Wagner R.R. Rajaram S.E. Golunski (2002) Catal. Today 72 133 Occurrence Handle1:CAS:528:DC%2BD38XisV2jtbk%3D Occurrence Handle10.1016/S0920-5861(01)00487-4

    Article  CAS  Google Scholar 

  68. P. Bera M.S. Hegde (2002) Catal. Lett. 79 75 Occurrence Handle1:CAS:528:DC%2BD38Xksl2htr8%3D Occurrence Handle10.1023/A:1015352223861

    Article  CAS  Google Scholar 

  69. H.H. Kung M.C. Kung C.K. Costello (2003) J. Catal. 216 425 Occurrence Handle1:CAS:528:DC%2BD3sXjvVCnu7k%3D Occurrence Handle10.1016/S0021-9517(02)00111-2

    Article  CAS  Google Scholar 

  70. J. Guzman B.C. Gates (2004) J. Am. Chem. Soc. 126 2672 Occurrence Handle14995163 Occurrence Handle1:CAS:528:DC%2BD2cXht1Wisbk%3D Occurrence Handle10.1021/ja039426e

    Article  PubMed  CAS  Google Scholar 

  71. C.K. Costello J. Guzman J.H. Yang Y.M. Wang M.C. Kung B.C. Gates H.H. Kung (2004) J. Phys. Chem. B 108 12529 Occurrence Handle1:CAS:528:DC%2BD2cXlvFGisbk%3D Occurrence Handle10.1021/jp048643e

    Article  CAS  Google Scholar 

  72. S. Carrettin P. Concepcion A. Corma J.M. Lopez Nieto V.F. Puntes (2004) Angew. Chem. Int. Ed. 43 2538 Occurrence Handle1:CAS:528:DC%2BD2cXkt1ejtrs%3D Occurrence Handle10.1002/anie.200353570

    Article  CAS  Google Scholar 

  73. J.C. Fierro-Gonzalez B.C. Gates (2004) J. Phys. Chem. B 108 16999 Occurrence Handle1:CAS:528:DC%2BD2cXotlals7g%3D Occurrence Handle10.1021/jp046171y

    Article  CAS  Google Scholar 

  74. J.C. Fierro-Gonzalez B.G. Anderson K. Ramesh C.P. Vinod J.W. Niemantsverdriet B.C. Gates (2005) Catal. Lett. 101 265 Occurrence Handle1:CAS:528:DC%2BD2MXks1elu7g%3D Occurrence Handle10.1007/s10562-005-4902-6

    Article  CAS  Google Scholar 

  75. S. Carrettin A. Corma M. Iglesias F. Sanchez (2005) Appl. Catal. A 291 247 Occurrence Handle1:CAS:528:DC%2BD2MXosVajsrg%3D Occurrence Handle10.1016/j.apcata.2005.01.047

    Article  CAS  Google Scholar 

  76. L. Fu N.Q. Wu J.H. Yang F. Qu D.L. Johnson M.C. Kung H.H. Kung V.P. Dravid (2005) J. Phys. Chem. B 109 3704 Occurrence Handle16851411 Occurrence Handle1:CAS:528:DC%2BD2MXhtFegt7s%3D Occurrence Handle10.1021/jp045117e

    Article  PubMed  CAS  Google Scholar 

  77. C. Gonzalez-Arellano A. Corma M. Iglesias F. Sanchez (2006) J. Catal. 238 497 Occurrence Handle1:CAS:528:DC%2BD28Xht1ylsbk%3D Occurrence Handle10.1016/j.jcat.2005.12.015

    Article  CAS  Google Scholar 

  78. A. Comas-Vives C. Gonzalez-Arellano A. Corma M. Iglesias F. Sanchez G. Ujaque (2006) J. Am. Chem. Soc. 128 4756 Occurrence Handle16594712 Occurrence Handle1:CAS:528:DC%2BD28XitlOitLg%3D Occurrence Handle10.1021/ja057998o

    Article  PubMed  CAS  Google Scholar 

  79. P. Concepcion S. Carrettin A. Corma (2006) Appl. Catal. A 307 42 Occurrence Handle1:CAS:528:DC%2BD28XkvFCku7k%3D Occurrence Handle10.1016/j.apcata.2006.03.004

    Article  CAS  Google Scholar 

  80. G.J. Hutchings M.S. Hall A.F. Carley P. Landon B.E. Solsona C.J. Kiely A. Herzing M. Makkee J.A. Moulijn A. Overweg (2006) J. Catal. 242 71 Occurrence Handle1:CAS:528:DC%2BD28XnsFOqsL8%3D Occurrence Handle10.1016/j.jcat.2006.06.001

    Article  CAS  Google Scholar 

  81. S. Chretien H. Metiu (2006) Catal. Lett. 107 143 Occurrence Handle1:CAS:528:DC%2BD28XislWnu7c%3D Occurrence Handle10.1007/s10562-005-0014-6

    Article  CAS  Google Scholar 

  82. A. Baiker J.D. Grunwaldt C.A. Mueller L. Schmid (1998) Chimia 52 517 Occurrence Handle1:CAS:528:DyaK1cXntlGrtrY%3D

    CAS  Google Scholar 

  83. A. Wolf F. Schuth (2002) Appl. Catal. A 226 1 Occurrence Handle1:CAS:528:DC%2BD38XhtFyrur0%3D Occurrence Handle10.1016/S0926-860X(01)00772-4

    Article  CAS  Google Scholar 

  84. A.K. Sinha S. Seelan T. Akita S. Tsubota M. Haruta (2003) Appl. Catal. A 240 243 Occurrence Handle1:CAS:528:DC%2BD3sXptlyltg%3D%3D Occurrence Handle10.1016/S0926-860X(02)00451-9

    Article  CAS  Google Scholar 

  85. C. Aprile A. Abad H. Garcia A. Corma (2005) J. Mater. Chem. 15 4408 Occurrence Handle1:CAS:528:DC%2BD2MXhtFartbbO Occurrence Handle10.1039/b507418e

    Article  CAS  Google Scholar 

  86. T. Bligaard J.K. Nørskov S. Dahl J. Matthiesen C.H. Christensen J. Sehested (2004) J. Catal. 224 206 Occurrence Handle1:CAS:528:DC%2BD2cXjsVejtbw%3D Occurrence Handle10.1016/j.jcat.2004.02.034

    Article  CAS  Google Scholar 

  87. J. Kim E. Samano B.E. Koel (2006) Surf. Sci. 600 4622 Occurrence Handle1:CAS:528:DC%2BD28XhtVWqt7%2FO Occurrence Handle10.1016/j.susc.2006.07.057 Occurrence Handle2006SurSc.600.4622K

    Article  CAS  ADS  Google Scholar 

  88. A. Nilsson L.G.M. Pettersson B. Hammer T. Bligaard C.H. Christensen J.K. Nørskov (2005) Catal. Lett. 100 111 Occurrence Handle1:CAS:528:DC%2BD2MXivVOntLc%3D Occurrence Handle10.1007/s10562-004-3434-9

    Article  CAS  Google Scholar 

  89. S.D. Lin M. Bollinger M.A. Vannice (1993) Catal. Lett. 17 245 Occurrence Handle1:CAS:528:DyaK3sXit1Smtbk%3D Occurrence Handle10.1007/BF00766147

    Article  CAS  Google Scholar 

  90. Y. Yuan K. Asakura H. Wan K. Tsai Y. Iwasawa (1996) Catal. Lett. 42 15 Occurrence Handle1:CAS:528:DyaK28XntFCktLo%3D Occurrence Handle10.1007/BF00814461

    Article  CAS  Google Scholar 

  91. M. Haruta (1997) Catal. Today 36 153 Occurrence Handle1:CAS:528:DyaK2sXitFCrtb0%3D Occurrence Handle10.1016/S0920-5861(96)00208-8

    Article  CAS  Google Scholar 

  92. S.J. Lee A. Gavriilidis (2002) J. Catal. 206 305 Occurrence Handle1:CAS:528:DC%2BD38Xit1yjsbc%3D Occurrence Handle10.1006/jcat.2001.3500

    Article  CAS  Google Scholar 

  93. J.T. Calla M.T. Bore A.K. Datye R.J. Davis (2006) J. Catal. 238 458 Occurrence Handle1:CAS:528:DC%2BD28Xht1ylsb0%3D Occurrence Handle10.1016/j.jcat.2006.01.009

    Article  CAS  Google Scholar 

  94. S.H. Overbury V. Schwartz D.R. Mullins W. Yan S. Dai (2006) J. Catal. 241 56 Occurrence Handle1:CAS:528:DC%2BD28XlvFyltLg%3D Occurrence Handle10.1016/j.jcat.2006.04.018

    Article  CAS  Google Scholar 

  95. E. Wahlstrom N. Lopez R. Schaub P. Thostrup A. Ronnau C. Africh E. Lægsgaard J.K. Nørskov F. Besenbacher (2003) Phys. Rev. Lett. 90 026101–026101/4 Occurrence Handle12570557 Occurrence Handle1:CAS:528:DC%2BD3sXltValtQ%3D%3D Occurrence Handle10.1103/PhysRevLett.90.026101 Occurrence Handle2003PhRvL..90b6101W

    Article  PubMed  CAS  ADS  Google Scholar 

  96. I.N. Remediakis N. Lopez J.K. Nørskov (2005) Angew. Chem. Int. Ed. 44 1824 Occurrence Handle1:CAS:528:DC%2BD2MXislWkur8%3D Occurrence Handle10.1002/anie.200461699

    Article  CAS  Google Scholar 

  97. N. Lopez J.K. Nørskov T.V.W. Janssens A. Carlsson A. Puig-Molina B.S. Clausen J.-D. Grunwaldt (2004) J. Catal. 225 86 Occurrence Handle1:CAS:528:DC%2BD2cXksVantr0%3D Occurrence Handle10.1016/j.jcat.2004.03.036

    Article  CAS  Google Scholar 

  98. Z.P. Liu X.Q. Gong J. Kohanoff C. Sanchez P. Hu (2003) Phys. Rev. Lett. 91 266102–266102/4 Occurrence Handle14754070 Occurrence Handle10.1103/PhysRevLett.91.266102 Occurrence Handle1:CAS:528:DC%2BD2cXnsFCn Occurrence Handle2003PhRvL..91z6102L

    Article  PubMed  CAS  ADS  Google Scholar 

  99. M.A. Bollinger M.A. Vannice (1996) Appl. Catal. B 8 417 Occurrence Handle1:CAS:528:DyaK28XjsVOhsbY%3D Occurrence Handle10.1016/0926-3373(95)00077-1

    Article  CAS  Google Scholar 

  100. J.K. Nørskov T. Bligaard A. Logadottir S. Bahn L.B. Hansen M. Bollinger H. Bengaard B. Hammer Z. Sljivancanin M. Mavrikakis (2002) J. Catal. 209 275 Occurrence Handle10.1006/jcat.2002.3615 Occurrence Handle1:CAS:528:DC%2BD38XltVagtb0%3D

    Article  CAS  Google Scholar 

  101. B. Hammer J.K. Norskov (2000) Adv. Catal. 45 71 Occurrence Handle1:CAS:528:DC%2BD3cXlslajurc%3D Occurrence Handle10.1016/S0360-0564(02)45013-4

    Article  CAS  Google Scholar 

  102. J. Kim E. Samano B.E. Koel (2006) J. Phys. Chem. B 110 17512 Occurrence Handle16942092 Occurrence Handle1:CAS:528:DC%2BD28XotFCrurw%3D Occurrence Handle10.1021/jp061685d

    Article  PubMed  CAS  Google Scholar 

  103. C. Ruggiero P. Hollins (1996) J. Chem. Soc. Farad. Trans. 92 4829 Occurrence Handle1:CAS:528:DyaK2sXktVaktQ%3D%3D Occurrence Handle10.1039/ft9969204829

    Article  CAS  Google Scholar 

  104. J.M. Gottfried K.J. Schmidt S.L.M. Schroeder K. Christmann (2003) Surf. Sci. 536 206 Occurrence Handle1:CAS:528:DC%2BD3sXkt1Kis7c%3D Occurrence Handle10.1016/S0039-6028(03)00595-8

    Article  CAS  Google Scholar 

  105. D.C. Meier V. Bukhtiyarov D.W. Goodman (2003) J. Phys. Chem. B 107 12668 Occurrence Handle1:CAS:528:DC%2BD3sXotlOktr8%3D Occurrence Handle10.1021/jp030499u

    Article  CAS  Google Scholar 

  106. J.D. Stiehl T.S. Kim S.M. McClure C.B. Mullins (2005) J. Phys. Chem. B 109 6316 Occurrence Handle16851703 Occurrence Handle1:CAS:528:DC%2BD2MXit1Cltbs%3D Occurrence Handle10.1021/jp044553y

    Article  PubMed  CAS  Google Scholar 

  107. B.K. Min X. Deng D. Pinnaduwage R. Schalek C.M. Friend (2005) Phys. Rev. B 72 121410 Occurrence Handle10.1103/PhysRevB.72.121410 Occurrence Handle1:CAS:528:DC%2BD2MXhtFajsbbI Occurrence Handle2005PhRvB..72l1410M

    Article  CAS  ADS  Google Scholar 

  108. A. Carlsson A. Puig-Molina T.V.W. Janssens (2006) J. Phys. Chem. B 110 5286 Occurrence Handle16539459 Occurrence Handle1:CAS:528:DC%2BD28XhvVCjtbg%3D Occurrence Handle10.1021/jp0569537

    Article  PubMed  CAS  Google Scholar 

  109. R. Hardeveld Particlevan F. Hartog (1969) Surf. Sci. 15 189 Occurrence Handle10.1016/0039-6028(69)90148-4

    Article  Google Scholar 

  110. B. Yoon H. Häkkinen U. Landman (2003) J. Phys. Chem. A 107 4066 Occurrence Handle1:CAS:528:DC%2BD3sXjtVWnsL0%3D Occurrence Handle10.1021/jp027596s

    Article  CAS  Google Scholar 

  111. X. Wu L. Senapati S.K. Nayak A. Selloni M. Hajaligol (2002) J. Chem. Phys. 117 4010 Occurrence Handle1:CAS:528:DC%2BD38XmtVCmsbo%3D Occurrence Handle10.1063/1.1483067 Occurrence Handle2002JChPh.117.4010W

    Article  CAS  ADS  Google Scholar 

  112. G. Mills M.S. Gordon H. Metiu (2002) Chem. Phys. Lett. 359 493 Occurrence Handle1:CAS:528:DC%2BD38Xlt1GgsLc%3D Occurrence Handle10.1016/S0009-2614(02)00746-7

    Article  CAS  Google Scholar 

  113. J.M. Gottfried K.J. Schmidt S.L.M. Schroeder K. Christmann (2002) Surf. Sci. 511 65 Occurrence Handle1:CAS:528:DC%2BD38XksVelt7o%3D Occurrence Handle10.1016/S0039-6028(02)01555-8

    Article  CAS  Google Scholar 

  114. T. Bar T.V. Bocarme ParticleDe B.E. Nieuwenhuys N. Kruse (2001) Catal. Lett. 74 127 Occurrence Handle1:CAS:528:DC%2BD3MXmsFyqs7s%3D Occurrence Handle10.1023/A:1016685130974

    Article  CAS  Google Scholar 

  115. J.M. Gottfried K. Christmann (2004) Surf. Sci. 566–568 1112

    Google Scholar 

  116. J.D. Stiehl T.S. Kim C.T. Reeves R.J. Meyer C.B. Mullins (2004) J. Phys. Chem. B 108 7917 Occurrence Handle1:CAS:528:DC%2BD2cXktVamtL4%3D Occurrence Handle10.1021/jp0496102

    Article  CAS  Google Scholar 

  117. J.-D. Grunwaldt C. Kiener C. Wögerbauer A.J. Baiker (1999) J. Catal. 181 223 Occurrence Handle1:CAS:528:DyaK1MXpsVyjtw%3D%3D Occurrence Handle10.1006/jcat.1998.2298

    Article  CAS  Google Scholar 

  118. M. Comotti W.C. Li B. Spliethoff F. Schüth (2006) J. Am. Chem. Soc. 128 917 Occurrence Handle16417382 Occurrence Handle1:CAS:528:DC%2BD2MXhtlCgsrzO Occurrence Handle10.1021/ja0561441

    Article  PubMed  CAS  Google Scholar 

  119. S.C. Parker A.W. Grant V.A. Bondzie C.T. Campbell (1999) Surf. Sci. 441 10 Occurrence Handle1:CAS:528:DyaK1MXns1artr4%3D Occurrence Handle10.1016/S0039-6028(99)00753-0

    Article  CAS  Google Scholar 

  120. L. Zhang F. Cosandey R. Persaud T.E. Madey (1999) Surf. Sci. 439 73 Occurrence Handle1:CAS:528:DyaK1MXmslCgsLY%3D Occurrence Handle10.1016/S0039-6028(99)00734-7

    Article  CAS  Google Scholar 

  121. J.T. Calla R.J. Davis (2006) J. Catal. 241 407 Occurrence Handle1:CAS:528:DC%2BD28Xmslahurk%3D Occurrence Handle10.1016/j.jcat.2006.05.017

    Article  CAS  Google Scholar 

  122. M. Maciejewski P. Fabrizioli J.D. Grunwaldt O.S. Becker A. Baiker (2001) Phys. Chem. Chem. Phys. 3 3846 Occurrence Handle1:CAS:528:DC%2BD3MXmtVehsLg%3D Occurrence Handle10.1039/b101184g

    Article  CAS  Google Scholar 

  123. W. Yan S. Brown Z. Pan S.M. Mahurin S.H. Overbury S. Dai (2006) Angew. Chem. Int. Ed. 45 3614 Occurrence Handle1:CAS:528:DC%2BD28Xls1GitLw%3D Occurrence Handle10.1002/anie.200503808

    Article  CAS  Google Scholar 

  124. G. Ertl S.B. Lee M. Weiss (1982) Surf. Sci. 114 527 Occurrence Handle1:CAS:528:DyaL38XhtlSntbs%3D Occurrence Handle10.1016/0039-6028(82)90703-8

    Article  CAS  Google Scholar 

  125. J.K. Nørskov S. Holloway N.D. Lang (1984) Surf. Sci. 137 65 Occurrence Handle10.1016/0039-6028(84)90676-9

    Article  Google Scholar 

  126. S.R. Bare D.R. Strongin G.A. Somorjai (1986) J. Phys. Chem. 90 4726 Occurrence Handle1:CAS:528:DyaL28XlsVSmur8%3D Occurrence Handle10.1021/j100411a003

    Article  CAS  Google Scholar 

  127. J.J. Mortensen B. Hammer J.K. Nørskov (1998) Phys. Rev. Lett. 80 4333 Occurrence Handle1:CAS:528:DyaK1cXislOisLY%3D Occurrence Handle10.1103/PhysRevLett.80.4333 Occurrence Handle1998PhRvL..80.4333M

    Article  CAS  ADS  Google Scholar 

  128. R.J.H. Grisel B.E. Nieuwenhuys (2001) J. Catal. 199 48 Occurrence Handle1:CAS:528:DC%2BD3MXit1aiur0%3D Occurrence Handle10.1006/jcat.2000.3121

    Article  CAS  Google Scholar 

  129. R.J.H. Grisel C.J. Weststrate A. Goossens M.W.J. Craje A.M. Kraan Particlevan der B.E. Nieuwenhuys (2002) Catal. Today 72 123 Occurrence Handle1:CAS:528:DC%2BD38XisV2jtbg%3D Occurrence Handle10.1016/S0920-5861(01)00486-2

    Article  CAS  Google Scholar 

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  1. Haldor Topsøe A/S, Nymøllevej 55, DK-2800, Lyngby, Denmark

    Ton V. W. Janssens & Bjerne S. Clausen

  2. Department of Physics, NanoDTU, Center for Atomic-scale Materials Physics, Technical University of Denmark, DK-2800, Lyngby, Denmark

    Britt Hvolbæk, Thomas Bligaard & Jens K. Nørskov

  3. Department of Chemistry, NanoDTU, Center for Sustainable and Green Chemistry, Technical University of Denmark, DK-2800, Lyngby, Denmark

    Hanne Falsig & Claus H. Christensen

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  1. Ton V. W. Janssens
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Janssens, T.V.W., Clausen, B.S., Hvolbæk, B. et al. Insights into the reactivity of supported Au nanoparticles: combining theory and experiments. Top Catal 44, 15–26 (2007). https://doi.org/10.1007/s11244-007-0335-3

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