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Hydrothermal synthesis, crystal structure, and photoluminescence of novel lanthanide metal organic frameworks constructed from 1,4-benzene-dicarboxylic acid and 1,2,4,5-benzenetetracarboxylic acid as ligands

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Abstract

By using 1,4-benzene-dicarboxylic acid and 1,2,4,5-benzenetetracarboxylic acid as mixed-linkers, three novel 3D lanthanide coordination polymers, [Ln(BDC)0.5(BTEC)0.5(H2O)] (Ln = Eu (1) and Gd (2)) and [Tb(BDC)0.5(BTEC)0.5(H2O)] (3) (H2BDC = 1,4-benzene-dicarboxylic acid, H4BTEC = 1,2,4,5-benzenetetracarboxylic acid) were synthesized via hydrothermal reaction. The X-ray single crystal analyses reveal that the three coordination polymers present two types of different crystal cell parameters and hereby exhibited two kinds of different metal–organic frameworks, although they have the similar chemical formula [Ln(BDC)0.5(BTEC)0.5(H2O)]. Of these complexes, complexes 1 and 2 are isomorphous, crystallizing in monoclinic, space group P21/n. While 3 is a 3D eight-coordinated terbium complex with triclinic crystal system and P-1 space group. The occurrence of the different structures of these complexes under the similar preparation method may be related to the lanthanide contraction effect. Additional, the thermogravimetric analyses and photoluminescent properties for complexes 1 and 3 were discussed in detail.

Graphical Abstract

Three novel coordination polymers, [Ln(BDC)0.5(BTEC)0.5(H2O)] (Ln = Eu (1) and Gd (2)) and [Tb(BDC)0.5(BTEC)0.5(H2O)] (3) (H2BDC = 1,4-benzene-dicarboxylic acid, H4BTEC = 1,2,4,5-benzenetetracarboxylic acid) have been firstly synthesized hydrothermally. Complexes 1 and 2 are isomorphous, crystallizing in monoclinic, space group P21/n. While 3 is a novel eight-coordinated Tb(III) complex with triclinic crystal system and P-1 space group.

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Acknowledgments

This work was supported by the grants of the National Natural Science Foundation of China (Grant No. 21071071 and 10804015), the Education Foundation of Dalian city in China (Grant No. 2009J21DW004) for financial assistance and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, PR China (Grant No. 2010-15).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Jian-Ling Wang, Ke-Ling Hou & Yong-Heng Xing

  2. College of Life Science, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Feng-Ying Bai

  3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, People’s Republic of China

    Zhan Shi

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  1. Jian-Ling Wang
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Correspondence to Yong-Heng Xing.

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Wang, JL., Hou, KL., Bai, FY. et al. Hydrothermal synthesis, crystal structure, and photoluminescence of novel lanthanide metal organic frameworks constructed from 1,4-benzene-dicarboxylic acid and 1,2,4,5-benzenetetracarboxylic acid as ligands. Struct Chem 23, 275–285 (2012). https://doi.org/10.1007/s11224-011-9870-4

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