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A novel layered supramolecular compound containing 2D network of eight-member water clusters and terephthalato extended-bridged

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Abstract

A novel layered supramolecular compound [Ni(L)(TPHA)]·8H2O, containing two-dimensional (2D) water clusters and terephthalato-bridged ligand, where L = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9] octadecane, TPHA = terephthalate dianion, has been synthesized and structurally characterized by spectroscopy and X-ray crystallography. The complex is neutral, in which the nickel(II) ions are bridged by the TPHA to form a one-dimensional (1D) infinite chain structure, and containing the eight-member water cluster. The presence of octameric water clusters have effectively increased the 1D coordination polymer to a three-dimensional layered structure. Every water cluster is connected strongly by a O–H···O hydrogen bond (range of the bonds between 2.724 and 3.056 Å). The complex crystallizes in monoclinic, space group P21/c with a = 9.788(3), b = 13.030(4), c = 11.646(4) Å, and β = 104.551(5)°.

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Acknowledgment

This project was supported by the SRT Foundation of Tianjin University of Commerce, P.R. China (No. 2007120).

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Authors and Affiliations

  1. Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, People’s Republic of China

    Peng Yang, Xi Chen, Shi Ren & Shu-Lin Ma

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  1. Peng Yang
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  2. Xi Chen
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  3. Shi Ren
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  4. Shu-Lin Ma
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Correspondence to Shu-Lin Ma.

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Yang, P., Chen, X., Ren, S. et al. A novel layered supramolecular compound containing 2D network of eight-member water clusters and terephthalato extended-bridged. Struct Chem 19, 291–295 (2008). https://doi.org/10.1007/s11224-008-9285-z

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  • DOI: https://doi.org/10.1007/s11224-008-9285-z

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