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Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster

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Abstract

Two new complexes, [Eu2(NIPH)2(H2O)14](HNIPH)2(H2O)7 (1) [Co2(abtc)(phen)4(H2O)]·12(H2O) (2) (H2NIPH = 5-nitroisophthalic acid, H4abtc = 3,3′,5,5′-azobenzenetetracarboxylic acid, phen = 1,10-phenanthroline, DMF = N,N′-dimethylformamide) have been synthesized and characterized by infrared spectrum, thermal gravimetric analysis, X-ray single crystal diffraction and photoluminescence properties. Complex 1 upon slow evaporation at room temperature gave a 0-D structure, and seven independent water molecules and their equivalent held together by hydrogen bonds with an ordered proton arrangement form a 1-D hydrogen-bonded water tape. An unusual water tape notated T10(0)A0 is observed in 2. A 1-D water tape by connecting five-ten-five membered water rings through hydrogen bonds. Multiple hydrogen bonds and π–π stacking interactions play important roles in the formation of the 3-D networks. Fascinatingly, these lattice water molecules display unprecedented water cluster and play important roles in the stabilizing the whole network.

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Acknowledgments

This work was supported by the NSF of Guangxi Province (No. 2012GXNSFAA053031), Guangxi Department of Education (201203YB071), the Innovation Project of Guangxi University for Nationalities (No. gxun-chx2013096) and the open fund of Key Laboratory of Guangxi Key laboratory of Chemistry and Engineering of Forest Products (No. GXFC 13-08).

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  1. College of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning, 530006, People’s Republic of China

    Shu Long Wang, Ling Yu Zhang, Fen Jiang & Qin Huang

  2. Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Nanning, 530006, People’s Republic of China

    Qin Huang

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Wang, S.L., Zhang, L.Y., Jiang, F. et al. Synthesis, Structures and Properties of Two New Coordination Polymers with Unprecedented Water Cluster. J Clust Sci 26, 959–972 (2015). https://doi.org/10.1007/s10876-014-0788-z

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