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Supramolecular Aggregation of Tetrameric and Homododecameric Water Clusters in a 1D Cobalt(II) Coordination Polymer Containing 1,2,4,5-Benzenetetracarboxylate

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Abstract

A ternary mixed ligand Co(II) coordination polymer, namely, {[Co(L)(btec)0.5(H2O)]·3H2O} n , (L = 1,4-bis(thiabendazole)butane, H4btec = 1,2,4,5-benzenetetracarboxylic acid) has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction analysis. The coordination polymer features a 1D wave-like chain, which is further extended into a 3D supramolecular framework via O–H⋯O hydrogen bonding interactions. It is noteworthy, the chair-shaped homododecamers and quasirectangle teteramers assemble with the 1D loose-string-like water-btec4− chain into a unusual boxing-glove-like 2D water layer. Hirshfeld surface analysis and fingerprint plots show that the coordination polymer is stabilized by O–H⋯O, π⋯π, O–H⋯π, and H⋯H intermolecular interactions. Furthermore, thermal behaviors, luminescence and catalytic properties of the coordination polymer for degradation of methyl orange in a Fenton-like process have been investigated.

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Acknowledgments

The project was supported by the National Natural Science Foundation of China (51474086), Natural Science Foundation-Steel and Iron Foundation of Hebei Province (B2015209299).

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, North China University of Science and Technology, Tangshan Hebei, 063009, People’s Republic of China

    Shao-Yun Hao, Ce Liu, Zeng-Chuan Hao & Guang-Hua Cui

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  1. Shao-Yun Hao
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  2. Ce Liu
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  3. Zeng-Chuan Hao
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  4. Guang-Hua Cui
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Correspondence to Guang-Hua Cui.

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Hao, SY., Liu, C., Hao, ZC. et al. Supramolecular Aggregation of Tetrameric and Homododecameric Water Clusters in a 1D Cobalt(II) Coordination Polymer Containing 1,2,4,5-Benzenetetracarboxylate. J Inorg Organomet Polym 27, 105–113 (2017). https://doi.org/10.1007/s10904-016-0451-2

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