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Electrochemical method for producing globules of ultrasmall rhodium nanoparticles with poly(N-vinylpyrrolidone) bound to the surface of nanocellulose fibers

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Abstract

The study concerns the preparation of Rh nanoparticles (NPs) by room-temperature, methyl viologen (MV2+) mediated electrochemical reduction of RhCl3 in the presence of poly(N-vinylpyrrolidone) (PVP, 40000 Da) and nanocellulose (NC, d = 57±36 nm) at a controlled potential of generation of MV·+ radical cations in aqueous medium. When a theoretical amount of electricity is passed, the mediator is not consumed, while Rh(III) is quantitatively reduced to Rh(0). The reduction results in the Rh@PVP (141–191 nm in size) and Rh@PVP/NC nanocomposites dispersed in the solution bulk. The Rh@PVP/NC nanocomposite represents PVP globules (42±13 nm in size) with encapsulated ultrasmall spherical Rh NPs (1.3±0.4 nm in size) bound to the surface of NC fibers. The Rh nanocomposites exhibited high catalytic activity in the model reaction, viz., reduction of p-nitrophenol with sodium borohydride in aqueous medium. The catalytic activity increased in the presence of cetyltrimethylammonium chloride (CTAC).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    R. R. Fazleeva, G. R. Nasretdinova, Yu. N. Osin, A. T. Gubaidullin & V. V. Yanilkin

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  1. R. R. Fazleeva
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  2. G. R. Nasretdinova
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  3. Yu. N. Osin
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Correspondence to R. R. Fazleeva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1908–1916, October, 2021.

This work was carried out under partial financial support from the Russian Foundation for Basic Research (Project No. 20-03-00007).

This paper does not contain descriptions of studies on animals or humans.

The authors declare no competing interests.

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Fazleeva, R.R., Nasretdinova, G.R., Osin, Y.N. et al. Electrochemical method for producing globules of ultrasmall rhodium nanoparticles with poly(N-vinylpyrrolidone) bound to the surface of nanocellulose fibers. Russ Chem Bull 70, 1908–1916 (2021). https://doi.org/10.1007/s11172-021-3295-z

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