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Chloroacetylenephosphonates in reactions with tetrazolethiones

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Abstract

Chloroacetylenephosphonates react with 1-substituted tetrazole-5-thiones in anhydrous acetonitrile to form fused heterocycles, viz., 3-substituted 6-(dialkoxyphosphoryl)-3H-thiazolo[3,2-d]tetrazol-7-ium chlorides, along with a small amount of compounds having a linear structure, viz., Z-dialkyl {1,2-bis[(1-methyl(phenyl)-1H-tetrazol-5-yl)sulfanyl]ethenyl}phosphonates.

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Correspondence to A. V. Dogadina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0716–0722, March, 2014.

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Dogadina, A.V., Erkhitueva, E.B. & Ionin, B.I. Chloroacetylenephosphonates in reactions with tetrazolethiones. Russ Chem Bull 63, 716–722 (2014). https://doi.org/10.1007/s11172-014-0497-7

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  • DOI: https://doi.org/10.1007/s11172-014-0497-7

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