Abstract
A series of novel photochemically bifunctional compounds was synthesized. Their molecules combine the photochromic spironaphthoxazine fragment with a salicylideneimine fragment containing various substituents. The latter can undergo intramolecular proton transfer in the electron-excited state. Photolysis products of three types, namely, open merocyanine forms having an enol or cis-keto form of the salicylideneimine moiety and a trans-keto form with the closed spiro fragment, were detected using pulse photolysis technique in toluene and methanol solutions. The spectral kinetic characteristics of the photoproducts were studied, and their quantum yields were measured. The effects of substituents in the salicylideneimine fragment and the solvent nature were discussed.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2346–2352, November, 2008.
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Zaichenko, N.L., Levin, P.P., Mardaleishvili, I.R. et al. Synthesis and kinetics of photochemical reactions of novel bifunctional salicylideneiminospironaphthoxazines. Russ Chem Bull 57, 2394–2401 (2008). https://doi.org/10.1007/s11172-008-0341-z
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DOI: https://doi.org/10.1007/s11172-008-0341-z