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Transition metal doped FeOCl activated hydrogen peroxide/persulfate for enhanced degradation of TCH

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Abstract

In the past few decades, the overuse of antibiotics has been a growing concern in the field of medicine. To address this issue, there has been increasing interest in the development of efficient treatment methods. Recently, research has shown that the modification of iron oxychloride with Mn, Co, or Ni can significantly enhance its performance in the degradation of tetracycline hydrochloride. This is attributed to the high similarity between Mn, Co, Ni and Fe, bimetallic systems can be constructed to improve the accelerated cycle of M(II)–M(III) and the activation of hydrogen peroxide, peroxymonosulfate and peroxydisulfate. Additionally, active substances such as SO4−·, ·OH, and 1O2 have been identified in the PS system, while ·OH and 1O2 are active in the H2O2 system. In this study, due to the presence of these active substances, the degradation rate of tetracycline hydrochloride within 10 min in three different systems such as hydrogen peroxide can reach 100%. These findings offer promising prospects for the development of more effective and sustainable treatment methods for antibiotic pollution.

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Acknowledgements

This work was supported from the Collaborative Innovation Foundation of Shanghai Institute of Technology (Grant Number XTCX2022-10 and Grand Number XTCX2023-13).

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Authors and Affiliations

  1. School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Haiquan Road 100, Shanghai, 201418, People’s Republic of China

    Deli Lu, Fengtian Zhu, Zhe Chen, Qidong Yang, Chen Liu, Ying Liu, Yushi Lin & Sheng Han

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  1. Deli Lu
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  2. Fengtian Zhu
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  3. Zhe Chen
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  5. Chen Liu
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Contributions

All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by Deli Lu, Fengtian Zhu, Zhe Chen, Qidong Yan, Chen liu, Ying Liu, Yushi Lin and Sheng Han. The first draft of the manuscript was written by Fengtian Zhu and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Lu, D., Zhu, F., Chen, Z. et al. Transition metal doped FeOCl activated hydrogen peroxide/persulfate for enhanced degradation of TCH. Res Chem Intermed 50, 2187–2198 (2024). https://doi.org/10.1007/s11164-024-05254-0

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