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Performance and mechanism of heterogeneous catalyst prepared from pyrite cinder for tetracycline hydrochloride degradation

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Abstract

Tetracycline hydrochloride, which is commonly present in water bodies, lowers human immunity, affects liver function and poses a significant threat to ecosystems. Heterogeneous Fenton can efficiently and thoroughly remove pollutants. Using pyrite cinder as raw material to prepare catalysts has a guiding significance for the utilization of solid waste and the preparation of catalysts. The vibrating sample magnetometer indicated that the materials had strong magnetic properties. The reaction conditions were as follows: the catalyst dosage was 4 g/L, the H2O2 dosage was 5 ml/L, pH = 7, and the concentration of tetracycline hydrochloride was 100 mg/L. After 120 min of reaction, the degradation rates of tetracycline hydrochloride by Pyc-al and Pyc-pal@Ni reached 91.65% and 93.42%, respectively. The radical quenching experiments determined that the Pyc-pal and Pyc-pal@Ni systems radicals were·OH, ·O2− and h+, and the contributions were h+  > ·O2−  > ·OH. This study proves that pyrite cinder as solid waste can be made into heterogeneous Fenton catalyst with high efficiency and easy magnetic recovery. It provides a green method for the recovery and utilization of solid waste.

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Funding

This work was supported by Science and Technology Innovation Team Project of Hubei Provincial Department of Education (Grant No. T2020002), Wuhan Science and Technology Planning Project (Grant No. 2020020601012274), National Natural Science Foundation of China (Grant No. 41571306) and Hubei Technological Innovation Special Fund (Grant No. 2020ZYYD019). The authors would like to thank Jiang Lang from Shiyanjia Lab (www.shiyanjia.com) for the characterization support.

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Authors and Affiliations

  1. College of Resource and Environmental Engineering, Wuhan University of Science and Technology, Wuhan, 430081, China

    Le Zhang, Dajun Ren, Zhe Zhao, Yulun Xiao, Junlin Zhai, Shuqin Zhang, Xiaoqing Zhang, Xiangyi Gong & Wangsheng Chen

  2. Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources, Wuhan University of Science and Technology, Wuhan, 430081, Hubei, China

    Le Zhang, Dajun Ren, Zhe Zhao, Yulun Xiao, Junlin Zhai, Shuqin Zhang, Xiaoqing Zhang, Xiangyi Gong & Wangsheng Chen

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  1. Le Zhang
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All authors contributed to the study conception and design. Material preparation, data collection and analysis were performed by DR, ZZ and LZ. The first draft of the manuscript was written by LZ and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Dajun Ren.

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Zhang, L., Ren, D., Zhao, Z. et al. Performance and mechanism of heterogeneous catalyst prepared from pyrite cinder for tetracycline hydrochloride degradation. Res Chem Intermed 49, 4561–4584 (2023). https://doi.org/10.1007/s11164-023-05108-1

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