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Supported rhodium with low loading in nanoparticles-catalyzed azidolysis of epoxides: optimization of efficient parameters using response surface methodology

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Abstract

In this study, we examined the catalytic role of low rhodium embedded onto MOF-5 as a hard template, in the ring opening reaction of epoxides with N3− anion as nucleophile. The material was characterized by SEM, TEM, FT-IR, XRD, EDAX, BET, H2-TPR, and AAS techniques. Furthermore, we used BBD and RSM to obtain the optimum reaction conditions, which was 2.25% of Rh loading, 0.05 g amount of the catalyst, and 60 min reaction time at a temperature of 45 °C. The prepared catalyst demonstrated high activity, easy recovery and efficient recyclability with no leaching of Rh in the azidolysis of epoxides.

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Acknowledgements

The authors extend their gratitude to the Mahshahr Branch, Islamic Azad University for its financial support. Also, the authors are grateful to Dr. N. Taheri and Dr. S. J. Saghanezhad for helpful comments.

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Authors and Affiliations

  1. Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

    Azadeh Nemati, Soheil Sayyahi, Vahid Zare-Shahabadi & Hossein Anaraki-Ardakani

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  1. Azadeh Nemati
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  2. Soheil Sayyahi
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  3. Vahid Zare-Shahabadi
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  4. Hossein Anaraki-Ardakani
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Correspondence to Soheil Sayyahi.

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Nemati, A., Sayyahi, S., Zare-Shahabadi, V. et al. Supported rhodium with low loading in nanoparticles-catalyzed azidolysis of epoxides: optimization of efficient parameters using response surface methodology. Res Chem Intermed 46, 3397–3411 (2020). https://doi.org/10.1007/s11164-020-04152-5

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