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A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

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Abstract

Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffers from complicated operation and the difficulty in catalyst recycling. It is highly desirable to develop a heterogeneous catalyst that enables the catalyst recovery without sacrificing the activity and selectivity. There are two strategies to afford such a catalyst for the hydrofromylation: immobilized catalysts on solid support and porous organic ligand (POL)-supported catalysts. In the latter, high concentration of phosphine ligands in the catalyst framework is favorable for the high dispersion of rhodium species and the formation of Rh-P multiple bonds, which endow the catalysts with high activity and stability respectively. Besides, the high linear regioselectivity could be achieved through the copolymerization of vinyl functionalized bidentate ligand (vinyl biphephos) and monodentate ligand (3vPPh3) into the catalyst framework. The newly-emerging POL-supported catalysts have great perspectives in the industrial hydroformylation.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 21273227 and 21403258) and the Strategic Priority Research Program of the Chinese Academy of Science (Grant Nos XDB17020400).

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Authors and Affiliations

  1. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Cunyao Li, Wenlong Wang, Li Yan & Yunjie Ding

  2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

    Yunjie Ding

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  1. Cunyao Li
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  2. Wenlong Wang
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  3. Li Yan
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  4. Yunjie Ding
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Correspondence to Li Yan or Yunjie Ding.

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Li, C., Wang, W., Yan, L. et al. A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts. Front. Chem. Sci. Eng. 12, 113–123 (2018). https://doi.org/10.1007/s11705-017-1672-9

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  • DOI: https://doi.org/10.1007/s11705-017-1672-9

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