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The Oxidation of Four Co-20Ni-xCr-yAl (x = 8,15 wt.%; y = 3,5 wt.%) Alloys Under 1 atm O2 at 800 °C and 900 °C

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Abstract

The oxidation of four Co-20Ni-xCr-yAl (x = 8,15 wt.%; y = 3,5 wt.%) alloys under 1 atm O2 for 24 h was studied at 800 and 900 °C. All the alloys formed complex scales, irregular both in thickness and composition. The formation of external alumina scales was more favored at 800 °C than at 900 °C and for larger chromium and aluminum contents, but was never complete. The simultaneous presence of chromium and aluminum is beneficial for increasing the oxidation resistance of these alloys with respect to ternary Co-20Ni-xCr and Co-20Ni-yAl alloys of similar composition. However, an Al content of 5 wt.% is not yet sufficient to form continuous alumina scales even when coupled with 15 wt.% Cr. The partial substitution of cobalt by nickel has a beneficial effect on the ability of the quaternary Co-20Ni-xCr-yAl alloys to form protective external alumina scales in comparison with the ternary Co-Cr-Al alloys with similar chromium and aluminum contents.

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The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

References

  1. D.J. Young, High Temperature Oxidation and Corrosion of Metals, Second Edition, (Elsevier Corrosion Series, New York, 2016).

  2. G.R. Lai, High-Temperature Corrosion and Materials Applications, (ASM International, 2007).

  3. R. Prescott and M. J. Graham, Oxidation of Metals 38, 233 (1992).

    Article  CAS  Google Scholar 

  4. P. Y. Hou, Journal of the American Ceramic Society 86, 660 (2003).

    Article  CAS  Google Scholar 

  5. F. H. Stott, G. C. Wood, and J. Stringer, Oxidation of Metals 44, 113 (1995).

    Article  CAS  Google Scholar 

  6. N. S. Jacobson, M. A. Kuczmarski, and B. A. Kowalski, Oxidation of Metals 93, 247 (2020).

    Article  CAS  Google Scholar 

  7. G. R. Wallwork and A. Z. Hed, Oxidation of Metals 3, 213 (1971).

    Article  CAS  Google Scholar 

  8. G. R. Wallwork and A. Z. Hed, Oxidation of Metals 3, 243 (1971).

    Article  CAS  Google Scholar 

  9. H. Stott, G. C. Wood, and M. G. Hobby, Oxidation of Metals 3, 103 (1971).

    Article  CAS  Google Scholar 

  10. G. N. Irving, J. Stringer, and D. P. Whittle, Corrosion 33, 56 (1977).

    Article  CAS  Google Scholar 

  11. L. Hu, D. B. Hovis, and A. H. Heuer, Oxidation of Metals 73, 275 (2010).

    Article  CAS  Google Scholar 

  12. A. Ul-Hamid, Corrosion Science 46, 27 (2004).

    Article  CAS  Google Scholar 

  13. T. J. Nijdam, L. P. H. Jeurgens, and W. G. Sloof, Materials at High Temperatures 20, 311 (2003).

    Article  CAS  Google Scholar 

  14. T. J. Nijdam, L. P. H. Jeurgens, and W. G. Sloof, Acta Materialia 53, 1643 (2005).

    Article  CAS  Google Scholar 

  15. I. A. Kvernes and P. Kofstad, Metallurgical Transactions 3, 1511 (1972).

    Article  CAS  Google Scholar 

  16. Y. Niu, X. J. Zhang, Y. Wu, and F. Gesmundo, Corrosion Science 48, 4020 (2006).

    Article  CAS  Google Scholar 

  17. X. J. Zhang, S. Y. Wang, F. Gesmundo, and Y. Niu, Oxidation of Metals 65, 151 (2006).

    Article  CAS  Google Scholar 

  18. S. R. LeVine, Metallurgical Transactions A 99, 1237 (1978).

    Google Scholar 

  19. M. Weiser, Y. M. Eggeler, E. Spiecker, and S. Virtanen, Corrosion Science 135, 78 (2018).

    Article  CAS  Google Scholar 

  20. L. Klein, A. Bauer, S. Neumeier, M. Göken, and S. Virtanen, Corrosion Science 53, 2027 (2011).

    Article  CAS  Google Scholar 

  21. B. Gao, L. Wang, Y. Liu, X. Song, S. Y. Yang, and A. Chiba, Corrosion Science 157, 109 (2019).

    Article  CAS  Google Scholar 

  22. B. H. Yu, Y. P. Li, Y. Nie, and H. Mei, Journal of Alloys and Compounds 765, 1148 (2018).

    Article  CAS  Google Scholar 

  23. F. B. Ismail, V. A. Vorontsov, T. C. Lindley, M. C. Hardy, D. Dye, and B. A. Shollock, Corrosion Science 116, 44 (2017).

    Article  CAS  Google Scholar 

  24. M. Weiser, M. G. Galetz, R. J. Chater, and S. Virtanen, Journal of the Electrochemical Society 167, 021504 (2020).

    Article  CAS  Google Scholar 

  25. M. Seraffon, N. J. Simms, J. Summer, and J. R. Nicholls, Surface and Coatings Technology 206, 1529 (2011).

    Article  CAS  Google Scholar 

  26. M. Seraffon, N. J. Simms, J. Summer, and J. R. Nicholls, Oxidation of Metals 81, 203 (2014).

    Article  CAS  Google Scholar 

  27. H. Lan, P. Y. Hou, Z. G. Yang, Y. D. Zhang, and C. Zhang, Oxidation of Metals 75, 77 (2011).

    Article  CAS  Google Scholar 

  28. L. Yang, Y. Zheng and Z.G. Yang, TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings. 763 (2020).

  29. M. Weiser, M. C. Galetz, H. Eberard-Zschau, C. H. Zenk, S. Neumeier, M. Goken, and S. Virtanen, Corrosion Science 156, 84 (2019).

    Article  CAS  Google Scholar 

  30. C. H. Zenk, S. Neumeier, N. M. Engl, S. G. Fries, O. Dolotko, M. Weiser, S. Virtanen, and M. Goken, Scripta materialia 112, 83 (2016).

    Article  CAS  Google Scholar 

  31. B. D. Bastow, D. P. Whittle, and G. C. Wood, Corrosion Science 16, 57 (1976).

    Article  CAS  Google Scholar 

  32. Y. J. Ren, T. Dai, X. H. Guo, J. Shen, Y. L. Lv, J. Chen, and Y. Niu, Corrosion Science 191, 109719 (2021).

    Article  CAS  Google Scholar 

  33. Y. L. Lv, Y. J. Ren, W. Wang, L. B. Zhou, J. Chen, J. Huang, M. S. Tao, and Y. Niu, Corrosion Science 199, 110140 (2022).

    Article  CAS  Google Scholar 

  34. F. S. Pettit, Transactions of the Metallurgical Society of AIME 239, 1296 (1967).

    CAS  Google Scholar 

  35. G. N. Irving, J. Stringer, and D. P. Whittle, Oxidation of Metals 9, 427 (1975).

    Article  CAS  Google Scholar 

  36. C. S. Giggins and F. S. Pettit, Journal of the Electrochemical Society 118, 1782 (1971).

    Article  CAS  Google Scholar 

  37. G. C. Wood, F. H. Stott, and J. E. Forrest, Materials and Corrosion 28, 395 (1977).

    Article  CAS  Google Scholar 

  38. F. H. Stott, I. G. Wright, T. Hodgkiess, and G. C. Wood, Oxidation of Metals 11, 141 (1977).

    Article  CAS  Google Scholar 

  39. I. G. Wright and G. C. Wood, Oxidation of Metals 11, 163 (1977).

    Article  CAS  Google Scholar 

  40. H. Yu, S. Ukai, S. Hayaschic, and N. Oono, Corrosion Science 118, 49 (2017).

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the NSFC Projects (No.52171066 and No.51771034), Graduate Scientific Research Innovation Project of Hunan Province (No. CX20200871) and Graduate Scientific Research Innovation Project of CSUST (No. CX2020SS66).

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  1. School of Energy and Power Engineering, Changsha University of Science and Technology, Changsha, China

    Y. L. Lv, Y. J. Ren, M. N. Zhou, K. K. Feng, J. Chen & Y. Niu

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  1. Y. L. Lv
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  2. Y. J. Ren
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Lv, Y.L., Ren, Y.J., Zhou, M.N. et al. The Oxidation of Four Co-20Ni-xCr-yAl (x = 8,15 wt.%; y = 3,5 wt.%) Alloys Under 1 atm O2 at 800 °C and 900 °C. Oxid Met 97, 599–627 (2022). https://doi.org/10.1007/s11085-022-10106-6

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