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An advanced reaction model determination methodology in solid-state kinetics based on Arrhenius parameters variation

Part III. Thermal desulfurization kinetic analysis of CuO·CuSO4

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Abstract

Overlapping of parallel or consecutive reactions caused to variation of activation energy and pre-exponential factor and deconvolution of simultaneous reactions rather than fitting the experimental curve by assuming variable kinetic parameters could supply a deeper conception into the mechanism(s) of reaction. The well-known reaction model determination methods are based on the choice of constant Arrhenius parameters and the use of approximations. To solve this limitation, an advanced method of reaction mechanism model determination based on the Arrhenius parameters variation was proposed. This method appears to accurately simulate single step as well as multi-step reactions kinetics. The proposed method was experimentally verified by taking an experimental example of non-isothermal desulfurization kinetics of CuO·CuSO4 in the nanoscale range. Then, the physical meaning of models was effectively interpreted.

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Authors and Affiliations

  1. Department of Mineral Processing Engineering, Shahid Bahonar University of Kerman, Kerman, Iran

    Seyed Hadi Shahcheraghi & Mohammad Ranjbar

  2. Department of Materials Science and Engineering, Shahid Bahonar University of Kerman, Kerman, Iran

    Gholam Reza Khayati

Authors
  1. Seyed Hadi Shahcheraghi
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  2. Gholam Reza Khayati
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  3. Mohammad Ranjbar
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Correspondence to Seyed Hadi Shahcheraghi.

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Shahcheraghi, S.H., Khayati, G.R. & Ranjbar, M. An advanced reaction model determination methodology in solid-state kinetics based on Arrhenius parameters variation. J Therm Anal Calorim 123, 221–229 (2016). https://doi.org/10.1007/s10973-015-4853-0

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  • DOI: https://doi.org/10.1007/s10973-015-4853-0

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