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Preparation and properties of high temperature resistant neutron shielding poly(4-methyl-1-pentene)/boron carbide composite materials

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Abstract

To improve properties of the nuclear reactor secondary neutron shielding material, a novel high temperature resistant shielding material was prepared, in which poly(4-methyl-1-pentene) is blended with polyethylene and polypropylene as matrix materials and boron carbide as filler. Its neutron shielding properties were analyzed by Monte Carlo simulation and tested by Am–Be neutron source. Its thermodynamic properties were tested according to standard methods. Tests show that the new material’s heat distortion temperature is up to 168 ℃, which is much higher than that of polyethylene 45 ℃ and that of polypropylene 85 ℃. The thermal neutron shielding performance of the new material is better than that of polyethylene.

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References

  1. Abdulrahman ST, Ahmad Z, Thomas S et al (2020) Chapter 1—Introduction to neutron-shielding materials. In: Abdulrahman, Thottathil S, Thomas S, Ahmad Z (eds) Micro and nanostructured composite materials for neutron shielding applications. Woodhead Publishing, Sawston, pp 1–23

    Google Scholar 

  2. Wang Z, Liu C, Fang G et al (2021) Vitrification of nuclear contaminated lead–boron polyethylene. J Non Cryst Solids. https://doi.org/10.1016/j.jnoncrysol.2021.120832

    Article  Google Scholar 

  3. Umm-E-Kulsoom GSA, Khurshid MS et al (2020) Investigating the effect of adding CdO nano particles on neutron shielding efficacy of HDPE. Radiat Phys Chem 177:109–145

    Article  Google Scholar 

  4. Uddin Z, Yasin T, Shafiq M et al (2020) On the physical, chemical, and neutron shielding properties of polyethylene/boron carbide composites. Radiat Phys Chem 166:108–450

    Article  Google Scholar 

  5. Tuna T, Eker AA, Kam E (2021) Neutron shielding characteristics of polymer composites with boron carbide. J Korean Phys Soc. https://doi.org/10.1007/s40042-021-00089-z

    Article  Google Scholar 

  6. Guru S, Amritphale SS, Mishra J, Joshi S et al (2019) Multicomponent red mud-polyester composites for neutron shielding application. Mater Chem Phys. https://doi.org/10.1016/j.matchemphys.2018.12.039

    Article  Google Scholar 

  7. Özdemir T, Akbay SK, Uzun H et al (2016) Neutron shielding of EPDM rubber with boric acid: mechanical, thermal properties and neutron absorption tests. Prog Nucl Energy 89:102–109

    Article  Google Scholar 

  8. Mülazim Y, Kızılkaya C, Kahraman MV (2011) Thermal and neutron shielding properties of 10B2O3/polyimide hybrid materials. Polym Bull. https://doi.org/10.1007/s00289-011-0481-4

    Article  Google Scholar 

  9. Soltani Z, Beigzadeh AM, Ziaie F et al (2016) Effect of particle size and percentages of boron carbide on the thermal neutron radiation shielding properties of HDPE/B4C composite: experimental and simulation studies. Radiat Phys Chem 127:182–187

    Article  CAS  Google Scholar 

  10. Shin JW, Lee J-W, Yu S et al (2014) Polyethylene/boron-containing composites for radiation shielding. Thermochim Acta. https://doi.org/10.1016/j.tca.2014.03.039

    Article  Google Scholar 

  11. Baxter L, Herrman K, Panthi R et al (2020) Chapter 3—Thermoplastic micro and nanocomposites for neutron shielding. In: Abdulrahman ST, Thomas S, Ahmad Z (eds) Micro and nanostructured composite materials for neutron shielding applications. Woodhead Publishing, Sawston, pp 53–82

    Chapter  Google Scholar 

  12. Korkut T, Karabulut A, Budak G et al (2010) Investigation of fast neutron shielding characteristics depending on boron percentages of MgB2, NaBH4 and KBH4. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-010-0619-0

    Article  Google Scholar 

  13. Adeli R, Shirmardi SP, Ahmadi SJ (2016) Neutron irradiation tests on B4C/epoxy composite for neutron shielding application and the parameters assay. Radiat Phys Chem 127:140–146

    Article  CAS  Google Scholar 

  14. Cataldo F, Prata M (2019) New composites for neutron radiation shielding. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-019-06526-5

    Article  Google Scholar 

  15. Griffith JH, Rånby BG (1960) Dilatometric measurements on poly(4-methyl-1-pentene) glass and melt transition temperatures, crystallization rates, and unusual density behavior. J Polym Sci. https://doi.org/10.1002/pol.1960.1204414408

    Article  Google Scholar 

  16. Tanigami T, Yamaura K, Matsuzawa S et al (1986) Thermal expansion of crystal lattice of isotactic poly(4-methyl-1-pentene). Polym J 18:35–40

    Article  CAS  Google Scholar 

  17. Jebaseelan Samuel EJ, Mohan S (2004) FTIR and FT Raman spectra and analysis of poly(4-methyl-1-pentene). Spectrochim Acta A 60:19–24

    Article  Google Scholar 

  18. Bu H, Qiu W, Tan Z et al (2015) Study on toughening of poly(4-methyl-1-pentene) with various thermoplastic elastomers. J Thermoplast Compos Mater 28:1334–1342

    Article  CAS  Google Scholar 

  19. Xu LY, Ma AP, Yin B et al (2019) The effect of alkylated graphene oxide on the crystal structure of poly(4-methyl-1-pentene) during uniaxial deformation at high temperature. Polym Compos 40:E493–E500

    Article  CAS  Google Scholar 

  20. Guembou Shouop CJ, Ndontchueng Moyo M, Nguelem Mekongtso EJ et al (2021) 241Am/Be source optimum geometry for DSRS management-based Monte Carlo simulations. AIP Adv 11:115–124

    Article  Google Scholar 

  21. Karimi-Shahri K, Rafat-Motavalli L, Miri-Hakimabad H (2013) Finding a suitable shield for mixed neutron and photon fields based on an Am–Be source. J Radioanal Nucl Chem. https://doi.org/10.1007/s10967-012-2225-9

    Article  Google Scholar 

  22. Kipcak AS, Gurses P, Derun EM et al (2013) Characterization of boron carbide particles and its shielding behavior against neutron radiation. Energy Convers Manag. https://doi.org/10.1016/j.enconman.2012.08.026

    Article  Google Scholar 

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Authors and Affiliations

  1. Naval University of Engineering, Liberation Avenue, Wuhan, 430033, China

    Gu Huang, Junjun Gong, Wenming Xia & Junjun Chen

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  1. Gu Huang
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  2. Junjun Gong
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  3. Wenming Xia
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Correspondence to Wenming Xia.

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Huang, G., Gong, J., Xia, W. et al. Preparation and properties of high temperature resistant neutron shielding poly(4-methyl-1-pentene)/boron carbide composite materials. J Radioanal Nucl Chem 331, 4695–4704 (2022). https://doi.org/10.1007/s10967-022-08552-2

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