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Enhancement of dielectric properties by modulating electroactive \(\varvec{\beta }\)-phase of copper doped nickel oxide nanoparticles incorporated thin film

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Abstract

Polymer nanocomposites (PNCs), exhibiting enhanced physical properties, are emerging as innovative functional materials due to their versatile characteristics suitable for various technological applications. Composite films comprising 0.1% copper (Cu) doped Nickel oxide (NiO) [CNO1 (350)] nanoflakes calcined at 350 °C embedded in Poly (vinylidene fluoride) (PVDF) polymer were prepared using the solution casting method. The influence of CNO1 (350) filler incorporation on the structure and morphology of the composite films was scrutinized through X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FTIR), and Field Emission Scanning Electron Microscopy (FESEM). Results unveiled a direct correlation between CNO1 (350) filler concentration and the crystallinity, β-phase content, and morphology of the composite films, attributed to heterogeneous nucleation. Room temperature electrical measurements indicated dielectric constants reaching more than six times at 40 Hz and a conductivity increase exceeding two orders of magnitude, with a percolation threshold identified around 25wt% of CNO1 (350) filler content. The observed outcomes are elucidated through Maxwell–Wagner–Sillars interfacial polarization occurring at the interface of CNO1 (350) and the insulating polymer matrix. This elucidation involves the development of a conductive network and the establishment of a micro-capacitive structure within the PVDF thin films modified with CNO1 (350).

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Acknowledgements

The first author wishes to thank the Department of Physics, Jadavpur University for the necessary infrastructural facilities. He also gratefully acknowledges the Department of Physics, Bangabasi College, University of Calcutta for their valuable support and necessary co-operation.

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Authors and Affiliations

  1. Department of Physics, Jadavpur University, Kolkata, 700032, India

    Somen Biswas, Indrajit Mondal, Piyali Halder, Souvik Sau, Manisha Kundu & Sukhen Das

  2. Department of Physics, Bangabasi College, Kolkata, 700009, India

    Somen Biswas & Souvik Sau

  3. Department of Physics, Jogamaya Devi College, Kolkata, 700026, India

    Manisha Kundu

  4. Department of Physics, Nabagram Hiralal Paul College, Hooghly, 712246, India

    Dheeraj Mondal

  5. University of Engineering and Management, Kolkata, 700160, India

    Biplab Kumar Paul

  6. Central Glass and Ceramic Research Institute, Kolkata, 700032, India

    Anagha Ghosh

Authors
  1. Somen Biswas
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  2. Indrajit Mondal
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  3. Piyali Halder
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  4. Souvik Sau
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  5. Manisha Kundu
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  6. Dheeraj Mondal
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  7. Anagha Ghosh
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  8. Biplab Kumar Paul
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  9. Sukhen Das
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Correspondence to Biplab Kumar Paul or Sukhen Das.

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Biswas, S., Mondal, I., Halder, P. et al. Enhancement of dielectric properties by modulating electroactive \(\varvec{\beta }\)-phase of copper doped nickel oxide nanoparticles incorporated thin film. J Polym Res 31, 143 (2024). https://doi.org/10.1007/s10965-024-03979-5

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