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High performance fluorinated Bismaleimide-Triazine resin with excellent dielectric properties

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Abstract

A series of high performance fluorinated bismaleimide-triazine (BT) resins were prepared from 2, 2′-Bis(4-cyanatophenyl) propane (CY-1), 2′-Bis[4-(4-maleimidephenoxy) phenyl] hexafluoropropane (6FBMP) and diallyl hexafluorobisphenol A (6FDABPA). The effect of the fluorinated groups on the curing behavior, thermal stability, mechanical and dielectric properties was studied. Dielectric constant of the fluorinated BT resin was 2.89–2.94 and the dielectric loss could reach 0.002–0.004 at 1 MHz, which were dramatically improved compared with the reported cyanate ester resins. The fluorinated BT resins also exhibited excellent thermal stability, with a high glass transition temperature above 220 °C and 5% weight loss thermal decomposition temperature (Td5) exceeding 400 °C. Meanwhile, the impact strength of the fluorinated BT resins could reach 20 kJ/m2 and the flexural strength was 120 MPa. Small dipole, low polarizability, high bond energy of the carbon-fluorine (C-F) bond and symmetrical hexafluoroisopropyl group were the reason for the enhanced properties. This work suggested that the fluorinated BT resins had great potential to be used as the matrix of the advanced structural and functional composites.

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Acknowledgements

The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (No.51403218 & No.51473171 & No.21604090). The authors gratefully thanks the Young Elite Scientist Sponsorship Program by CAST (YESS) and the Youth Innovation Promotion Association of CAS (No. 2017047).

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Authors and Affiliations

  1. Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, People’s Republic of China

    Ying Guo, Fenghua Chen, Zheng Li, Xiang Liu, Heng Zhou & Tong Zhao

  2. South China Advanced Institute for Soft Matter Science and Technology, South China University of Technology, Guangzhou, 510640, People’s Republic of China

    Yue Han

  3. University of Chinese Academy of Sciences, Beijing, 100049, People’s Republic of China

    Zheng Li

Authors
  1. Ying Guo
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  2. Fenghua Chen
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  3. Yue Han
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  4. Zheng Li
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  5. Xiang Liu
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  6. Heng Zhou
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  7. Tong Zhao
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Correspondence to Heng Zhou or Tong Zhao.

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Guo, Y., Chen, F., Han, Y. et al. High performance fluorinated Bismaleimide-Triazine resin with excellent dielectric properties. J Polym Res 25, 27 (2018). https://doi.org/10.1007/s10965-017-1407-0

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  • DOI: https://doi.org/10.1007/s10965-017-1407-0

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